Sorption of carbon dioxide–methane mixtures

The paper reports the results of experiments concerning the sorption/desorption processes, observed under laboratory conditions, in two types of coal extracted from operational coal-mines in Poland, using CH₄ and CO₂ to observe their relative inter-reaction with the coal samples when introduced in varying proportions and conditions. Numerous studies concerning the sorption/desorption phenomena have described the operational mechanisms and the relationship of mine gases to the organically-created coal-body in mines. The differences in the behaviour of certain gases is twofold: firstly the essentially different characteristics of CO₂ and CH₄, and secondly the structure of the coal-bed itself: its degree of metamorphism and content of macerals. From the results yielded, it was observed that the divergence of the isotherms of sorption of CH₄ and other gases in comparison with the isotherms of sorption of CO₂ and a CO₂/CH₄ mixture differed and that the curve on the sorption isotherm was more clearly distinct after the introduction of CO₂ molecules to the system: coal with a higher degree of metamorphism—CH₄, which is closely related to the rigidity of the structure according to the level of metamorphism. Since coals with higher carbon content exhibit lower molecular bonding than low-carbonised coals, the characteristic feature of the bonds in the first case is their mobility. Knowledge of the physical and chemical properties of hard coals, as well as their interaction with mining gases, is of great use in solving problems concerned with the extraction of methane from mines or its storage in goafs.     

On Tension Failure of 2-D Rock Specimens and Associated Acoustic Emission

Summary To understand the failure mechanism of quasi-brittle materials like rock under tensile stress, observations on the failure process of granite and marble plate specimens under tension are summarized and presented. Micro- and macro-failure properties of rock plates under uniaxial tension have been characterized by using an acoustic emission technique. Acoustic emission signals associated with micro-fractures are captured to locate the sources. An algorithm based on arrival time difference is developed for this purpose. The results reveal clearly the failure processes of rock which include initiation, nucleation and propagation of micro-fractures when the axial stress is close to the peak strength of rock. It is believed that the difference in heterogeneity between granite and marble specimens leads to different fracture shapes and different behaviors of associated acoustic emissions. Numerical simulation of acoustic emissions for two-dimensional tensile test is also carried out. The simulated characteristics are in good agreement with the experimental results.     

The Stonyford Volcanic Complex: a Forearc Seamount in the Northern California Coast Ranges

Jurassic age volcanic rocks of the Stonyford volcanic complex(SFVC) comprise three distinct petrological groups based ontheir whole-rock geochemistry: (1) oceanic tholeiites; (2) transitionalalkali basalts and glasses; (3) high-Al, low-Ti tholeiites.Major and trace element, and Sr–Nd–Pb isotopic dataindicate that the oceanic tholeiites formed as low-degree partialmelts of normal mid-ocean ridge basalt (N-MORB)-source asthenospheresimilar in isotope composition to the East Pacific Rise today;the alkalic lavas were derived from an enriched source similarto that of E-MORB. The high-Al, low-Ti lavas resemble second-stagemelts of a depleted MORB-source asthenosphere that formed bymelting spinel lherzolite at low pressures. Trace element systematicsof the high-Al, low-Ti basalts show the influence of an enrichedcomponent, which overprints generally depleted trace elementcharacteristics. Tectonic discrimination diagrams show thatthe oceanic tholeiite and alkali suites are similar to present-daybasalts generated at mid-oceanic ridges. The high-Al, low-Tisuite resembles primitive arc basalts with an enriched, alkalibasalt-like overprint. Isotopic data show the influence of recycledcomponents in all three suites. The SFVC was constructed ona substrate of normal Coast Range ophiolite in an extensionalforearc setting. The close juxtaposition of the MORB-like olivinetholeiites with alkali and high-Al, low-Ti basalts suggestsderivation from a hybrid mantle source region that includedMORB-source asthenosphere, enriched oceanic asthenosphere, andthe depleted supra-subduction zone mantle wedge. We proposethat the SFVC formed in response to collision of a mid-oceanridge spreading center with the Coast Range ophiolite subductionzone. Formation of a slab window beneath the forearc duringcollision allowed the influx of ridge-derived magmas or themantle source of these magmas. Continued melting of the previouslydepleted mantle wedge above the now defunct subduction zoneproduced strongly depleted high-Al, low-Ti basalts that werepartially fertilized with enriched, alkali basalt-type meltsand slab-derived fluids. KEY WORDS: CRO; oceanic basalts; California     

Systematic Variation of Sr-, Nd- and Pb-Isotopes with Time in Lavas of Mauritius, Reunion Hotspot

We report Sr-, Nd- and Pb-isotopic compositions for the lavasof Mauritius, the second youngest volcanic island in the Réunionhotspot. The lavas of the Older Series (7·8–5·5Ma) have identical isotopic compositions (⁸⁷Sr/⁸⁶Sr = 0·70411to 0·70422,¹⁴³Nd/¹⁴⁴Nd = 0·512865 to 0·512854,and ²⁰⁶Pb/²⁰⁴Pb = 19·016 to 19·041) to those ofRéunion, where the center of volcanic activity is currentlylocated. The lavas of the Intermediate Series (3·5–1·9Ma) and Younger Series (0·70–0·17 Ma) areshifted to lower Sr-isotopic compositions (0·70364–0·70394,with ¹⁴³Nd/¹⁴⁴Nd = 0·512813 to 0·512948 and ²⁰⁶Pb/²⁰⁴Pb= 18·794 to 18·984). The Intermediate Series lavashave similar trace-element characteristics (e.g. Zr–Nb,Ba–Y) to those of Rodrigues, in both cases requiring theinvolvement of an enriched mantle-like component in the mantlesource. During the volcanic history of Mauritius, the magmaslost the principal isotopic characteristics of the Réunionhotspot with time, and became gradually imprinted with the isotopicsignature of a shallower mantle source that produced the CentralIndian Ridge basalts. KEY WORDS: hotspot; isotopes; Mauritius; Réunion; trace element     

Exhumation Paths of High-Pressure-Low-Temperature Metamorphic Rocks from the Lycian Nappes and the Menderes Massif (SW Turkey): a Multi-Equilibrium Approach

The Menderes Massif and the overlying Lycian Nappes occupy anextensive area of SW Turkey where high-pressure–low-temperaturemetamorphic rocks occur. Precise retrograde P–T pathsreflecting the tectonic mechanisms responsible for the exhumationof these high-pressure–low-temperature rocks can be constrainedwith multi-equilibrium P–T estimates relying on localequilibria. Whereas a simple isothermal decompression is documentedfor the exhumation of high-pressure parageneses from the southernMenderes Massif, various P–T paths are observed in theoverlying Karaova Formation of the Lycian Nappes. In the uppermostlevels of this unit, far from the contact with the MenderesMassif, all P–T estimates depict cooling decompressionpaths. These high-pressure cooling paths are associated withtop-to-the-NNE movements related to the Akçakaya shearzone, located at the top of the Karaova Formation. This zoneof strain localization is a local intra-nappe contact that wasactive in the early stages of exhumation of the high-pressurerocks. In contrast, at the base of the Karaova Formation, alongthe contact with the Menderes Massif, P–T calculationsshow decompressional heating exhumation paths. These paths areassociated with severe deformation characterized by top-to-the-eastshearing related to a major shear zone (the Gerit shear zone)that reflects late exhumation of high-pressure parageneses underwarmer conditions. KEY WORDS: exhumation; high-pressure–low-temperature metamorphism; multi-equilibrium P–T estimates; Lycian Nappes; Menderes Massif     

Pan-African Tectonism in the Western Maud Belt: P-T-t Path for High-grade Gneisses in the H.U. Sverdrupfjella, East Antarctica

Extensive high-grade polydeformed metamorphic provinces surroundingArchaean cratonic nuclei in the East Antarctic Shield recordtwo tectono-thermal episodes in late Mesoproterozoic and lateNeoproterozoic–Cambrian times. In Western Dronning MaudLand, the high-grade Mesoproterozoic Maud Belt is juxtaposedagainst the Archaean Grunehogna Province and has traditionallybeen interpreted as a Grenvillian mobile belt that was thermallyoverprinted during the Early Palaeozoic. Integration of newU–Pb sensitive high-resolution ion microprobe and conventionalsingle zircon and monazite age data, and Ar–Ar data onhornblende and biotite, with thermobarometric calculations onrocks from the H.U. Sverdrupfjella, northern Maud Belt, resultedin a more complex P–T–t evolution than previouslyassumed. A c. 540 Ma monazite, hosted by an upper ampibolite-faciesmineral assemblage defining a regionally dominant top-to-NWshear fabric, provides strong evidence for the penetrative deformationin the area being of Pan-African age and not of Grenvillianage as previously reported. Relics of an eclogite-facies garnet–omphaciteassemblage within strain-protected mafic boudins indicate thatthe peak metamorphic conditions recorded by most rocks in thearea (T = 687–758°C, P = 9·4–11·3kbar) were attained subsequent to decompression from P >12·9 kbar. By analogy with limited U–Pb singlezircon age data and on circumstantial textural grounds, thisearlier eclogite-facies metamorphism is ascribed to subductionand accretion around 565 Ma. Post-peak metamorphic K-metasomatismunder amphibolite-facies conditions is ascribed to the intrusionof post-orogenic granite at c. 480 Ma. The recognition of extensivePan-African tectonism in the Maud Belt casts doubts on previousRodinia reconstructions, in which this belt takes a pivotalposition between East Antarctica, the Kalahari Craton and Laurentia.Evidence of late Mesoproterozoic high-grade metamorphism duringthe formation of the Maud Belt exists in the form of c. 1035Ma zircon overgrowths that are probably related to relics ofgranulite-facies metamorphism recorded from other parts of theMaud Belt. The polymetamorphic rocks are largely derived froma c. 1140 Ma volcanic arc and 1072 ± 10 Ma granite. KEY WORDS: Maud Belt; Pan-African orogeny; geochronology; P–T–t path, East Antarctica     

Origin of Grandite Garnet in Calc-Silicate Granulites: Mineral-Fluid Equilibria and Petrogenetic Grids

The role of clinopyroxene in producing grandite garnet is evaluatedusing data from an ultrahigh-temperature metamorphosed calc-silicategranulite occurrence in the Eastern Ghats Belt, India. ‘Peak’pressure–temperature conditions of metamorphism were previouslyconstrained from associated high Mg–Al granulites as c.0·9 GPa, >950°C, and the rocks were near-isobaricallycooled to c. 750°C. Grandite garnet of variable compositionwas produced by a number of reactions involving phases suchas clinopyroxene, scapolite, plagioclase, wollastonite and calcite,in closely spaced domains. Compositional heterogeneity is preservedeven on a microscale. This precludes pervasive fluid fluxingduring either the peak or the retrograde stage of metamorphism,and is further corroborated by computation of fluid–rockratios. With the help of detailed textural and mineral compositionalstudies leading to formulation of balanced reactions, and usingan internally consistent thermodynamic dataset and relevantactivity–composition relationships, new petrogenetic gridsare developed involving clinopyroxene in the system CaO–Al₂O₃–FeO–SiO₂–CO₂–O₂in T–aCO₂–fO₂ space to demonstrate the importanceof these factors in the formation of grandite garnet. Two singularcompositions in garnet-producing reactions in this system arededuced, which explain apparently anomalous textural relations.The possible role of an esseneite component in clinopyroxenein the production of grandite garnet is evaluated. It is concludedthat temperature and fO₂ are the most crucial variables controllinggarnet composition in calc-silicate granulites. fO₂, however,behaves as a dependent variable of CO₂ in the fluid phase. Externalfluid fluxing of any composition is not necessary to producechemical heterogeneity of garnet solid solution. KEY WORDS: grandite garnet; role of clinopyroxene; internal buffering; oxidation–decarbonation equilibria     

Post-Collisional Transition from Subduction- to Intraplate-type Magmatism in the Westernmost Mediterranean: Evidence for Continental-Edge Delamination of Subcontinental Lithosphere

Post-collisional magmatism in the southern Iberian and northwesternAfrican continental margins contains important clues for theunderstanding of a possible causal connection between movementsin the Earth's upper mantle, the uplift of continental lithosphereand the origin of circum-Mediterranean igneous activity. Systematicgeochemical and geochronological studies (major and trace element,Sr–Nd–Pb-isotope analysis and laser ⁴⁰Ar/³⁹Ar-agedating) on igneous rocks provide constraints for understandingthe post-collisional history of the southern Iberian and northwesternAfrican continental margins. Two groups of magmatic rocks canbe distinguished: (1) an Upper Miocene to Lower Pliocene (8·2–4·8Ma), Si–K-rich group including high-K (calc-alkaline)and shoshonitic series rocks; (2) an Upper Miocene to Pleistocene(6·3–0·65 Ma), Si-poor, Na-rich group includingbasanites and alkali basalts to hawaiites and tephrites. Maficsamples from the Si–K-rich group generally show geochemicalaffinities with volcanic rocks from active subduction zones(e.g. Izu–Bonin and Aeolian island arcs), whereas maficsamples from the Si-poor, Na-rich group are geochemically similarto lavas found in intraplate volcanic settings derived fromsub-lithospheric mantle sources (e.g. Canary Islands). The transitionfrom Si-rich (subduction-related) to Si-poor (intraplate-type)magmatism between 6·3 Ma (first alkali basalt) and 4·8Ma (latest shoshonite) can be observed both on a regional scaleand in individual volcanic systems. Si–K-rich and Si-poorigneous rocks from the continental margins of southern Iberiaand northwestern Africa are, respectively, proposed to havebeen derived from metasomatized subcontinental lithosphere andsub-lithospheric mantle that was contaminated with plume material.A three-dimensional geodynamic model for the westernmost Mediterraneanis presented in which subduction of oceanic lithosphere is inferredto have caused continental-edge delamination of subcontinentallithosphere associated with upwelling of plume-contaminatedsub-lithospheric mantle and lithospheric uplift. This processmay operate worldwide in areas where subduction-related andintraplate-type magmatism are spatially and temporally associated. KEY WORDS: post-collisional magmatism; Mediterranean-style back-arc basins; subduction; delamination; uplift of marine gateways