蒙脱石提纯研究进展

总结了蒙脱石的各种提纯方法及其试验原理和提纯分离效果。主要涉及重力选矿、水力分析、絮凝法、离心分离和化学提纯。对电泳法提纯作了简介。研究证实，与蒙脱石粒度相近的方石英和石英微粒等杂质很难去除。氢氧化钠溶蚀法会对蒙脱石、石英和方石英同时产生溶蚀，引入新的物相杂质。     

高密度空间采样地震数据特点分析

中国陆相沉积盆地的地质结构复杂,储层岩性的多变,需要有高精度的勘探方法。高密度空间采样是提高地震勘探精度的一项新技术。本文简要说明了点激发和点接收技术,分析高密度空间采样的野外工作方法,介绍了Gijs j．o．Vermeer提出的对称采样原理,从波场连续性的角度探讨了高密度空间采样技术。重点分析高密度空间采样数据的特点, 即:高密集的初至波有利于近地表结构的调查,可提高静校正的精度;小偏移距、小点距接收增加了浅层的有效覆盖次数,提高浅层反射的成像精度; 对规则噪声可实现无假频采样,室内的噪声分析和噪声压制的精度随着提高;高密度采集使波场连续性增强,使得各种数学变换的精度提高,有利于不同波场的分离。最后指出高密度空间采样地震勘探技术的难点在于室内数据处理,针对海量数据的分析和处理方法还需要进行深入细致的研究工作。     

岩石中铅和锌的分离与测定

以KHSO4作为沉淀济加入到小体积(1 mL)试液中,以K2SO4.PbSO4复盐形式沉淀分离Pb,用NaAc-HAc溶液热提取Pb,1 mg Pb的平均回收率为100.66%;滤液再蒸至1 mL小体积,NaCl-NaOH小体积两次沉淀分离Fe、Ti、Mn等干扰元素,存在于滤液中的Zn平均回收率为100.5%。分离所得的含Pb2 和Zn2 的溶液用EDTA分别进行滴定,测定下限由0.5%降至0.01%;测定结果与极谱法、原子吸收法相一致;方法的精密度(RSD,n=10)试验Pb为2.6%,Zn为1.4%。     

基于小波包变换的面波分离技术研究

依据面波视速度的分布范围,提出一种新的叠前面波分离技术,即把地震波场分成不受面波影响的波场和受面波影响的波场,然后利用小波包变换对受面波影响的波场进行时频分析,通过分解与重构,从中提取有效波,再将其与不受面波影响的波场合并,就可得到面波分离后的地震波场。该方法在成功分离面波的同时,可使有效波的能量(尤其是其低频能量)不受损失,既有效地保持信号的频宽不变,又提高了记录的信噪比。实际资料的处理结果表明:此方法在叠前面波分离方面具有有良好的效果。     

Extraction of rhyolitic component of Vedde microtephra from minerogenic lake sediments

A technique is described for the extraction of rhyolitic microtephra from inorganic Lateglacial lake sediments. This technique was successfully applied by Lowe and Turney (1996) and is an adaption of the method described by Pilcher & Hall (1992) for application to Holocene peat deposits. It uses a density separation procedure to concentrate any microtephra component in lake sediments and was applied to the investigation of a lake sediment succession from a small basin in NE Scotland. Using this approach is was possible to define quantitatively for the first time the presence of the Vedde Ash tephra layer on the British Isles.     

贵金属资源的应用及开发

将贵金属的应用,资源分布,生产和贵金属的分析化学结合在一起进行了综述,由于贵金属资源的短缺性及考虑可持续发展战略,特别介绍了贵金属资源的二次回收问题,并对其将来的发展作了一定的评价和展望。     

A Spectrum-Independent Procedure for Correcting Eddy Fluxes Measured with Separated Sensors

We investigate flux underestimates in eddy correlation measurements that are caused by horizontal separation of the sensors. A common eddy correlation setup consists of a sonic anemometer and a humidity sensor which, because of its bulk, must be placed some distance away from the sonic path, leading to a flux loss (of latent heat). Utilizing an additional fast temperature sensor placed near the humidity sensor, we develop a procedure for correcting for this loss. The procedure simultaneously corrects the sensible heat flux for the difference between true temperature and sonic temperature. Our correction procedure, which does not depend on the shape of the cospectrum, is then compared to the widely-used procedure following Moore (1986), which assumes a cospectral model ('Kansas Model). Both correction methods are applied to data collected within the internal boundary layer over a rice paddy, downwind of arid land. Under conditions of good fetch, they were found to agree well. Under poor fetch conditions, the model-based correction tended to be too small, while the spectrum-independent combined correction was robust. The latter is thus recommended for situations where the cospectral shape can be expected to deviate from the 'Kansas shape.     

On the galactic motion

A certain potential function is studied as a possible model for the galactic potential. Some solutions are obtained. Also the numerical study of some of the orbits and their stability is carried out.     

Salinograph trends as indicators of the recession characteristics of stream components

Compared to hydrograph recession analysis, which is widely applied in engineering hydrology, the quantitative assessment of stream salinity with time (i.e. the salinograph) has received significantly less attention. In particular, while in many previous hydrological studies an inverse relationship between hydrograph and salinograph responses is apparent, the concept of salinity accession (the inversely related salinity counterpart to hydrograph recession) has not been introduced nor quantitatively evaluated in previous literature. In this study, we conduct a mathematical analysis of salinograph accession, and determine new quantitative relationships between salinity accession and hydrograph recession parameters. An equation is formulated that reproduces the general trend in salinity accession. A salinity accession parameter k_c is then introduced and is shown to be the ratio of direct runoff to total stream flow recession parameters: k_r/k. The groundwater recession parameter k_g was estimated using a simple and rapid method that uses both salinograph and hydrograph data. Salinity accession type‐curves illustrate that under certain conditions, the relative steepness of individual salinographs is dependent upon the ratio of groundwater salinity to direct runoff salinity: C_g/C_r. The salinity accession algorithms are applied to two contrasting field settings: Scott Creek, South Australia and Sandy Creek, northern Queensland, Australia. It was found that k_g > k during periods of obvious stream flow recession, for the events analysed. Salinograph accession behaviour was fairly similar for both sites, despite contrasting environments. Using assumed end‐member salinities for groundwater and direct runoff based upon field observations, the behaviour of k_c from the Scott Creek site was approximately reproduced by varying the initial groundwater to runoff flow ratio: Q_g0/Q_r0, within reasonable parameter ranges. The use of salinograph information when used in addition to standard hydrograph analyses provided useful information on recession characteristics of stream components. Copyright © 2008 John Wiley & Sons, Ltd.     

Impact of wildfire on source water contributions in Devil Creek,CA: evidence from end‐member mixing analysis

A geochemical and end‐member mixing analysis (EMMA) is undertaken in Devil Canyon catchment, located in southern California, to further understanding of watershed behaviour and source water contributions after an acute and extensive wildfire. Physical and chemical transformations in post‐fire watersheds are known to increase overland flow and decrease infiltration, mainly due to formation of a hydrophobic layer at, or near, the soil surface. However, less is known about subsurface flow response in burned watersheds. The current study incorporates EMMA to evaluate and quantify source water contributions before, and after, a catchment affected by wildfires in southern California during the fall of 2003. Pre‐ and post‐fire stream water data were available at several sampling sites within the catchment, allowing the identification of contributing water sources at varying spatial scales. Proposed end‐member observations (groundwater, overland flow, shallow subsurface flow) were also collected to constrain and develop the catchment mixing model. Post‐fire source water changes are more evident in the smaller and faster responding sub‐basin (interior sampling point). Early post‐fire storm events are dominated by overland flow with no significant soil water or groundwater flow contribution. Inter‐storm streamwater in this smaller basin shows an increase in groundwater and a decrease in soil water. In the larger, baseflow‐dominated system, source water components appear less affected by fire. A slight increase in lateral flow is observed with only a slight decrease in baseflow. Changes in the post‐fire flow regimes affect nutrient loading and chemical response of the basin. Relatively rapid recovery of the chaparral ecosystem is evidenced, with active re‐growth and evapotranspiration evidenced by the fourth post‐fire rainy season. Copyright © 2008 John Wiley & Sons, Ltd.