一株海绵共附生真菌Pleosporaceae sp.中甾体类化合物及其生物活性

在生物活性测定指导下,综合运用硅胶柱层析、凝胶柱层析以及半制备HPLC等方法,从南海海绵Xestospongiatestudinaria来源的一株共附生真菌Pleosporaceae sp.发酵液的乙酸乙酯提取物中分离鉴定出5个甾体类化物,通过NMR,MS等波谱技术鉴定其结构分别为:(22E,24R)-5α,8α-epidioxy-ergosta-6,22-dien-3β-ol(1),(22E,24R)-5α,8α-epidioxy-ergosta-6,9,22-trien-3β-ol(2),(22E)-ergosta-5,7,22-trien-3β-ol(3),ergosta-6α-hydroxy-4,22-dien-3-one(4),(22E)-5α-cholesta-7,22-diene-3β,5α,6β-triol(5)。这些化合物均为首次从Pleosporaceae属真菌中分离获得。化合物1,4和5具有较强的卤虫Ar-temia salina致死活性,化合物1还显示强的抗藤壶Balanus amphitrite附着活性,其EC50为0.85μg/mL。     

德州市冬季大气挥发性有机物污染特征及其对臭氧和二次有机气溶胶生成的贡献

利用气相色谱-质谱仪/火焰离子检测器（Online-GC-MS/FID）对2017年冬季山东德州大气中99种挥发性有机物（VOCs）进行连续测量,研究了VOCs浓度和组分特征、日变化趋势、来源及其对臭氧（O₃）、二次有机气溶胶（SOA）生成的贡献.结果表明,德州大气VOCs平均体积分数为（47.74±33.11）×10^-9,烷烃占比最大,为40.66%.总VOCs及其组分表现出早晚体积分数高、中午体积分数低的日变化规律.德州大气中丙烷、丙烯、苯及甲苯和二氯甲烷分别受到液化石油气挥发、生物质燃烧、机动车排放和溶剂使用等人为源的影响.反向轨迹模型分析发现,北方内陆气团对德州VOCs体积分数具有一定贡献.烷烃、烯烃、芳香烃的臭氧生成潜势分别为（34.87±33.60）、（120.48±118.76）和（59.77±94.14）μg/m³,乙烯、丙烯、甲苯和间/对二甲苯的贡献较大.芳香烃氧化主导了SOA生成,其贡献率为93.7%,甲苯、间/对二甲苯、苯对SOA生成的贡献最大.为解决大气复合污染问题、实现臭氧和PM_2.5协同控制,德州应重点控制甲苯、间/对二甲苯等芳香烃的排放.     

Influences of Different PBL Schemes on Secondary Eyewall Formation and Eyewall Replacement Cycle in Simulated Typhoon Sinlaku (2008)

The effects of different planetary boundary layer (PBL) processes on the secondary eyewall formation (SEF) and eyewall replacement cycle (ERC) in Typhoon Sinlaku (2008) are investigated by using the Weather Research and Forecasting (WRF) model with six different PBL schemes. The SEF and ERC have been successfully simulated with all the six PBL schemes and the mechanism for the SEF and ERC proposed in our previous study has been reconfirmed. It is demonstrated that both the intensification of the storm and the inward-moving outer spiral rainband contribute to the SEF. After the SEF, the associated diabatic heating enhances the secondary eyewall further, and the transfer of moist air from outer region to the primary eyewall is cut off by the secondary eyewall. In such a way, the primary eyewall dies and an ERC completes. It is found that some simulated features of the SEF and ERC, such as the time and location of the SEF and duration of the ERC, do vary from one simulation to another. In order to describe the features of the SEF and ERC quantitatively, a concentric eyewall index (CEI) is defined and a threshold of the CEI is suggested to determine the onset of the secondary eyewall. The differences in the simulated SEF and ERC are discussed and some possible causes are suggested. In addition, based on the CEI threshold and the conservation law of angular momentum, a formula to predict the location of SEF is also proposed and applied to all the six simulations. The success and failure of the formula are then discussed.     

2017年2月下旬浙江省一次冷锋引起的大风天气过程分析

利用常规地面气象观测资料和NCEP再分析资料,对2017年2月20—21日浙江省中西部地区的一次冷空气大风天气过程进行分析。结果表明：西伯利亚冷高压与东亚大槽共同作用形成的强气压梯度是此次大风天气过程的重要成因;高空槽槽后动量下传是此次区域性大风超出一般冷锋大风强度的关键因素;200 hPa高空西风急流入流区的辐合下沉运动与冷锋前的上升运动叠加形成的次级环流是此次大风天气出现的增强条件。     

Approximate Analytic Solutions of the Averaged Three-Body Problem at First-Order Resonance with Large Oblateness of the Central Planet

For the general spatial planetary three-body problem at first-order mean motion resonance under the large oblateness of the central planet, the analytic solutions of the averaged motion are obtained with the help of the Weierstrass functions accurate to the third-degree terms in the satellites' eccentricities and inclinations. The behavior of solutions is investigated on the phase plane.This revised version was published online in October 2005 with corrections to the Cover Date.     

MARKET TRADE IN DECENTRALIZED DEVELOPMENT: THE CASE OF CAJAMARCA,PERU *

Decentralized development views market trade and market towns as part of a comprehensive strategy to divert economic development away from major metropolitan areas. Seventy-one traders were surveyed in the central market of Cajamarca, Peru in 1981. Most are women earning minimal incomes, primarily because of price controls and expensive credit. Stimulating market trade as it is currently organized seems unlikely to assist migrants in secondary towns or to stimulate agricultural development in their hinterlands.     

A symplectic mapping model for the 3/4 exterior

We present a symplectic mapping model to study the evolution of a small body at the 3/4 exterior resonance with Neptune, for planar and for three dimensional motion. The mapping is based on the averaged Hamiltonian close to this resonance and is constructed in such a way that the topology of its phase space is similar to that of the Poincaré map of the elliptic restricted three-body problem. Using this model we study the evolution of a small object near the 3/4 resonance. Both chaotic and regular motions are found, and it is shown that the initial phase of the object plays an important role on the appearance of chaos. In the planar case, objects that are phase-protected from close encounters with Neptune have regular orbits even at eccentricities up to 0.44. On the other hand objects that are not phase protected show chaotic behaviour even at low eccentricities. The introduction of the inclination to our model affects the stable areas around the 3/4 mean motion resonance, which now become thinner and thinner and finally at is=10° the whole resonant region becomes chaotic. This may justify the absence of a large population of objects at this resonance.     

Dynamical causes of asymmetry in the arrangement of gaps in the asteroid belt

The centers of the gaps observed in the asteroid belt are displaced toward Jupiter from their positions that correspond to the exact commensurability between the mean motions of an asteroid and Jupiter. Using the current theory of stability and nonlinear oscillations of Hamiltonian systems, we point out the dynamical causes of this asymmetry. Our analysis is performed in terms of the plane circular restricted three-body problem. The orbits that correspond to Poincaré periodic solutions of the first kind are taken as unperturbed asteroid orbits.     

近地小行星轨道演化的研究

主要阐述近年来在近地小行星轨道演化研究工作中所获得的一些基本结果，即合理的力学模型和相应的有效算法，并以实际预报算例（近地小行星与地球的交会状态）与有关权威性的结果作了比较，证实这些研究结果确实是可信的。在给出的力学模型中，考虑了所有可能影响近地小行星运动的力学因素，包括各大天体和较大的主带小行星的引力作用、有关天体的扁率影响以及源于太阳引力的后牛顿效应。而在计算方法中，合理地处理了变步长问题和月球位置量这种相对而言的快变化问题，使得数值求解一个高维方程组时，对各天体而言，可采用同一步长进行 积分，避免了求解过程中的复杂性。     

ESR dating of optically bleached quartz grains from Plio-Pleistocene to Holocene coastal dune deposits (Wilderness-Knysna area,South Africa): a comparison with luminescence

Five Plio-Pleistocene to Holocene aeolian quartz samples from the coastal dune deposits of the Wilderness-Knysna area (South Africa) previously dated by OSL were selected for ESR dating. Samples were processed following the Multiple Centre approach and using the Multiple Aliquot Additive dose method. Aluminium (Al) and Titanium (Ti) signals were systematically measured in all samples.Our study shows that ESR results obtained for Middle Pleistocene to Holocene samples may be strongly impacted by (i) the presence of a significant high frequency noise in the ESR spectra acquired for the Ti signals and (ii) the choice of the fitting function employed. In particular, if not taken into account, very noisy spectra can lead to a significant overestimation of the true ESR intensity measured for the Ti–H signal. These sources of uncertainty are however not sufficient to remove the ESR age overestimations. Consequently, our results indicate that the Al and Ti ESR signals of these quartz samples have not been fully reset during their aeolian transport.While this work contributes to improve our understanding of the ESR method applied to quartz grains, and especially of the potential and limitations of the Ti signals, it also provides additional baseline data to illustrate the existing variability among quartz samples of different origins or sedimentary context. Our results are consistent with previous studies by confirming that the Ti–H signal shows the best potential for the evaluation of low dose values (<100 Gy for these samples), whereas it becomes inappropriate for the higher dose range, and the Ti–Li–H (option D sensu Duval and Guilarte, 2015) should be used instead.Beyond the methodological outcome, this ESR dating study also provides a useful addition to the existing chronology of the aeolian deposits in this region. In particular, new (and possibly) finite numerical age results were obtained for the two oldest samples, constraining the aeolianite landward barrier dune and the coversand formations to the MIS 10-8 and Pliocene, respectively.