GD—DTPA脊髓造影磁共振扫描技术应用的研究

本文目的,通过将ＧＤ－ＤＴＰＡ直接注入蛛网膜下腔后进行脊髓造影ＭＲ扫描,探索一种新的ＭＲ检查方法,材料方法：对１１例患者进行ＧＤ－ＤＴＰＡ蛛网膜腔直接注射脊髓造影前后ＭＲ扫描,保持扫描序列不变。造影剂量为０．５～１．０ｍｌ,结果：所有患者脊髓造影后即刻扫描显示脑脊液信号反转,Ｔ１Ｗ高信号。Ｔ２Ｗ低信与,结论：小剂量ＧＤ－ＤＴＰＡ直接蛛网膜注射脊髓造影ＭＲ扫描是一种安全可靠的检查方法。对观察脑脊液动     

基于稀疏表示的地面磁共振信号提取方法

在多孔隙含水层中地面磁共振（surface nuclear magnetic resonance,SNMR）信号呈现多弛豫衰减特性,常规盲源分离方法和单指数拟合方法引起信号严重失真和信息缺失等问题.本文提出了基于稀疏表示的随机噪声背景下多弛豫SNMR信号的提取方法.根据SNMR信号的衰减特征,设计了精确刻画SNMR信号且与随机噪声不相关的离散衰减余弦冗余字典.其次,针对多弛豫SNMR信号稀疏度未知的问题,通过设置合理的残差比阈值控制迭代次数,改进了广义正交匹配追踪（generalized orthogonal matching pursuit,gOMP）算法,使得该方法应用于SNMR信号的提取时,具有更好的自适应性和普适性.再次,鉴于SNMR测量数据为多次独立重复采集的结果,提出了基于数据流的SNMR信号提取策略,在提高算法鲁棒性的同时,保证了信号提取结果的唯一性.最后,通过仿真和实测数据证明了基于gOMP算法的稀疏表示方法可以显著地提升多弛豫SNMR信号的提取质量,降低随机噪声对含水层反演结果的影响,提高SNMR探测能力.     

地下核磁共振小尺寸线圈设计和实验

很多国家在进行隧道挖掘、地下矿体开采时,经常会遇到突水涌泥事故.核磁共振方法(Magnetic Resonance Sounding,MRS)作为目前唯一一种直接找水的地球物理技术,在探测诱发灾害的水体方面具有明显的优势.本文首先给出了多匝分离式线圈的MRS信号响应和核函数的计算公式,分析了线圈的匝数、边长和含水层位置对MRS信号响应的影响.分析表明,在限定空间内,利用多匝分离式线圈的设计方法可以提高小尺寸线圈的探测能力.同时,对高匝数线圈给探测系统带来的不利因素进行了分析和改进.最后,为了验证本研究所采用的方法,利用6 m边长的方形线圈和改进型MRS探测系统在中国温州一处在建隧道内的地下场地进行实地探测,探测结果与瞬变电磁方法结果对比表明,6 m边长的方形线圈可以对地下30 m内的含水层进行有效探测.     

天目湖流域丘陵山区典型土地利用类型氮流失特征

天目湖丘陵山区农业综合开发持续推进,大量林地转变为茶园,迫切需要认识茶园扩张对流域氮流失的影响.本研究选取茶园、次生马尾松林和毛竹林开展自然降雨条件下的径流小区实验,分析天目湖丘陵山区典型用地类型径流氮流失规律,为评估丘陵山区综合开发的水环境影响提供实测参数.研究表明:茶园、次生马尾松林和毛竹林地表径流TN浓度分别为11.25、2.83和3.60 mg/L,均以溶解态为主;壤中流TN浓度分别为27.16、3.59和1.06 mg/L,茶园和次生马尾松林均以溶解性无机氮(尤其是硝态氮)为主,毛竹林以溶解性有机氮为主;茶园、次生马尾松林和毛竹林的小区尺度地表径流系数均不到0.03,壤中流是丘陵山区径流的主要来源;茶园开发加剧了丘陵山区的氮素流失,茶园径流TN流失强度高达103.08 kg/(hm²·a),分别是次生马尾松林和毛竹林的7.6和23.2倍,壤中流贡献了流失总量的86.7%~99.7%.防治茶园径流氮流失需重点关注壤中流输出,在减量施肥的基础上,采取坡脚构建毛竹林生态缓冲带/在小流域出口布设塘坝等原位拦截措施,实现流域氮流失综合防控.     

Measuring hydrological connectivity inside a soil by low field nuclear magnetic resonance relaxometry

Hydrological connectivity inside the soil is related to the spatial patterns inside the soil (i.e., the structural connectivity). This, in turn, is directly associated with the physical and the chemical processes at a molecular level (i.e., the functional connectivity). Nuclear magnetic resonance (NMR) relaxometry can be successfully applied to reveal both structural and functional components of soil hydrological connectivity. In the present study, the low field NMR relaxometry was applied on water suspended soils sampled at the upstream‐ and downstream‐end of three different length plots. Also the sediments collected from the storage tanks at the end of each plot were water suspended and monitored by NMR relaxometry. The results from the NMR investigations were elaborated by using a mathematical approach in order to quantify both the functional and structural connectivity components. In particular, following integration of the T₁ distribution curve, an S‐shaped curve was obtained. It revealed two plateaus corresponding to the shortest (low component) and the longest (high component) intervals of relaxation times, respectively. According to relaxometry theory, the two T₁ intervals, associated to the different plateaus, were attributed to micro and macro soil pores, respectively. The two T₁ intervals were used to define a functional connectivity index, while the central part of the S‐shaped distribution was used to define a structural connectivity index. Here we provide the physical meaning of the our mathematical approach, thereby revealing that functional connectivity index increases with plot length, as a result of a selective eroded particle transport. Moreover, the relationship structural connectivity index versus plot length resulted quasi‐independent of grainsize distribution, whereas the values of the structural connectivity index for the sediment samples resulted lower than those obtained for the corresponding soils.     

地震重灾区诱发次生地质灾害风险评价研究

为了揭示地震重灾区与次生地质灾害的关联性,以某地震灾区为例,在分析次生地质灾害类型与危害的基础上,通过计算一次泥石流总量及流量确定其危险度,并引入易损性指数,确定各评价单元次生山地灾害的易损性大小,设置评价指标;结合研究区实际,采用层次分析法构建次生地质灾害风险评价模型,对地震重灾区诱发次生地质灾害风险进行评价。实验以次生地质灾害中的泥石流产生的灾害风险为例进行研究,结果表明,采用本文研究方法可在有效确定地震重灾区诱发次生地质灾害的位置方面具有一定优势,但在纵向地震造成次生地质灾害风险评价方面需进一步进行研究。     

松辽盆地北部深层砂岩成岩作用与孔隙演化

松辽盆地北部深层砂岩成岩作用强,原生孔隙保存差。深层砂岩只有出现大量的次生孔隙,才能具有较好的储集性能。本文通过偏光显微镜、扫描电镜和显微热台等分析方法,研究了松辽盆地深层砂岩岩石类型,成岩作用特征和各成岩阶段砂岩孔隙的演化,表明胶结作用是影响深层砂岩储层物性变差的主要原因,浊沸石胶结物的溶解是深部砂岩储集性能得以改善的主要原因。     

Development and Re‐Evaluation of Tourmaline Reference Materials for In Situ Measurement of Boron δ Values by Secondary Ion Mass Spectrometry

Six tourmaline samples were investigated as potential reference materials (RMs) for boron isotope measurement by secondary ion mass spectrometry (SIMS). The tourmaline samples are chemically homogeneous and cover a compositional range of tourmaline supergroup minerals (primarily Fe, Mg and Li end‐members). Additionally, they have homogeneous boron delta values with intermediate precision values during SIMS analyses of less than 0.6‰ (2s). These samples were compared with four established tourmaline RMs, that is, schorl IAEA‐B‐4 and three Harvard tourmalines (schorl HS#112566, dravite HS#108796 and elbaite HS#98144). They were re‐evaluated for their major element and boron delta values using the same measurement procedure as the new tourmaline samples investigated. A discrepancy of about 1.5‰ in δ¹¹B was found between the previously published reference values for established RMs and the values determined in this study. Significant instrumental mass fractionation (IMF) of up to 8‰ in δ¹¹B was observed for schorl–dravite–elbaite solid solutions during SIMS analysis. Using the new reference values determined in this study, the IMF of the ten tourmaline samples can be modelled by a linear combination of the chemical parameters FeO + MnO, SiO₂ and F. The new tourmaline RMs, together with the four established RMs, extend the boron isotope analysis of tourmaline towards the Mg‐ and Al‐rich compositional range. Consequently, the in situ boron isotope ratio of many natural tourmalines can now be determined with an uncertainty of less than 0.8‰ (2s).     

High‐Precision,High‐Accuracy Oxygen Isotope Measurements of Zircon Reference Materials with the SHRIMP‐SI

Analytical protocols for SHRIMP‐SI oxygen isotope analysis (δ¹⁸O) of a suite of zircon reference materials (RMs) are presented. Data reduction involved a robust estimate of uncertainties associated with the individual spot as well as for groups where the spot data are combined. The repeatability of δ¹⁸O measurements is dependent on both the analytical conditions and the choice of the primary reference material. Under optimised conditions, repeatability was often better than 0.4‰ (2s) allowing sample uncertainties to be obtained to better than 0.2‰ (at 95% confidence limit). Single spot uncertainty combined the within‐spot precision with the scatter associated with repeated measurements of the primary zircon reference material during a measurement session. The uncertainty for individual spots measured under optimised conditions was between 0.3 and 0.4‰ (at 95% confidence). The analytical protocols described were used to assess a variety of zircon RMs that have been used for geochronology and for which laser fluorination oxygen isotope data are available (Temora 2, FC1, R33, QGNG and Ple?ovice), as well as zircons that have been used as RMs for trace element or other types of determination (Mud Tank, Monastery, 91500, AS57, AS3, KIM‐5, OG1, SL13, CZ3 and several other Sri Lankan zircons). Repeated analyses over nine sessions and seven different mounts show agreement within analytical uncertainty for Temora 2, FC1, R33, QGNG, Ple?ovice and 91500, when normalised to Mud Tank. For existing ion microprobe mounts with these materials, an appropriate δ¹⁸O can be determined. However, care should be taken when using zircons from the Duluth Complex (i.e., FC1, AS57 and AS3) as reference materials as our data indicated an excess scatter on δ¹⁸O values associated with low‐U zircon grains.     

应用核磁共振技术分析干盐湖地区地下卤水空间分布特征——以昆特依干盐湖为例

昆特依干盐湖位于柴达木盆地西北部,为特大型综合盐类矿床.大盐滩是昆特依干盐湖内最大的盐滩,地下赋存有一定量的卤水矿床,但该矿床的水文地质条件差,主要卤水矿层含水性弱,开采难度大.核磁共振找水方法作为当今世界上唯一的直接找水地球物理新方法,具有高分辨力、高效率、信息量丰富和解的唯一性等优点,本文运用该方法对昆特依干盐滩地区地下卤水空间分布特征进行研究,通过对核磁共振数据进行处理与反演,结合已有的地质与钻井资料,对测点进行综合地质-地球物理解释,获得以下认识:1)大盐滩0~130 m深度范围内,共存在3个卤水含水层,主要呈扁平状或漏斗状、近似层状展布,W1为晶间潜卤水层,渗透系数较大,颗粒较粗,单位体积含水量为0.4%~2.7%,W2和W3为晶间承压卤水层,渗透系数较小,颗粒较粗,单位体积含水量分别为0.2%~1.1%和0.1%~0.8%;2)大盐滩地区存在两个卤水富集区,分别为研究区西南部沉积盆地中心的Ⅰ号富卤区和盆地东北部的Ⅱ号富卤区;3)根据区域内卤水富集分布以及构造情况,划定大盐滩向斜沉积中心、大盐滩北侧F1~F8及遥F6断裂发育区和冷湖构造带为区域内主要的找矿找水远景区;4)GMR核磁共振系统在干盐滩地区理论探测深度为130 m,该系统不仅可以有效地探测自由水,而且可以依据束缚水的分布解译地下各类含水盐类矿物和含水黏土矿物的存在与分布.