淄博市区大气颗粒物重金属元素分布特征及其来源分析

为科学认识淄博市区大气颗粒物污染状况,探讨颗粒物的污染水平和元素在颗粒物中的分布与分配特征,对颗粒物中元素的来源进行分析。于2015年冬季和夏季期间分别布设45个和16个采样点采集悬浮颗粒物（TSP）、PM₁₀及PM_2.5样品,分析了颗粒物和18种元素（或化合物）的质量浓度。结果表明：1）大气颗粒物中冬季TSP、PM₁₀及PM_2.5的质量浓度均值高于夏季;PM₁₀和PM_2.5质量浓度均超过国家标准,其中冬季PM_2.5质量浓度是标准限值的1.96倍。2）不同粒径的颗粒物中元素质量分数差别显著,As、Cd、Cr、Cu、Ni、Pb、Zn等多数重金属元素主要富集在PM_2.5中,且PM_2.5约占PM₁₀的65%（冬季）和73%（夏季）。3）颗粒物PM_2.5中Al₂O₃、CaO、Fe₂O₃、K₂O、MgO等氧化物主要受土壤扬尘控制;As、Cd、Hg、Pb、Se、Zn等元素主要源于人为污染;Se的富集因子最高,反映了PM_2.5污染主要来源于燃煤;Co、Cu、Ni、Na₂O受土壤扬尘和人类活动的共同作用,而Cr具有混合污染的特点。     

伊通软土的次固结特性

为了合理计算软土地基的沉降量,对软土的次固结特性及影响因素进行研究。采用分级加荷的方法,对伊通软土进行了压缩固结试验。结果表明：伊通软土的应变速率和时间双对数曲线具有相关性;随着固结压力的增大,次固结系数C_a先迅速增大至最小值的3倍,达到峰值后逐步减小至峰值的15%,达到稳定;次固结系数C_a与压缩指数C_c具有一定的线性相关性,C_a/C_c值在0.030~0.043之间;次固结系数C_a随时间的增加呈对数下降趋势,随着时间的增长,C_a下降,最终其最小值达到最大值的72.3%。本文的研究结果可以对伊通地区软土地基的变形与沉降预测提供一定的参考。     

15 ka以来罗斯海陆架岩心沉积学记录及古海洋学意义

本文对取自罗斯海陆架的JB04岩心沉积物进行AMS14C测年、粒度、有机碳等测试,结合沉积物粒度组分因子分析,研究该岩心的沉积学记录,探讨其古海洋学意义。结果显示:JB04岩心沉积物的底部年龄为15 ka;沉积物粒度组分因子分析提取出3个环境敏感粒级,分别代表正常冰海沉积、低能海洋沉积和高能海洋沉积;综合沉积物岩相及沉积物组成特征,可以将岩心分为4段,从底部到顶部依次为主要受冰盖刮蚀影响的冰盖下沉积、属低能海洋环境的冰架下沉积、属高能海洋环境的冰架前缘沉积和主要受冰山影响的季节性海冰区沉积。该岩心的沉积地质记录及其古海洋学研究对全面认识罗斯海的海洋环境演变具有重要的意义。     

基于综合环境因子的协同克里金法分析茎柔鱼资源丰度空间分布

茎柔鱼是我国重要的远洋捕捞对象之一,研究其资源丰度空间分布问题,有助于更好地理解茎柔鱼的生态习性,并提高我国鱿钓渔船的生产效率。本文利用上海海洋大学鱿钓技术组提供的2003-2012年6-9月秘鲁外海茎柔鱼捕捞数据,结合海表面温度（SST）,海表面高度（SSH）,海表面盐度（SSS）和叶绿素浓度（Chl a）进行协同克里金插值预测其资源丰度的空间分布。为了解决协同克里金插值中4个环境因子的权重问题,本文将4个环境因子进行归一化处理,利用主成分分析方法将其整合为单一综合环境因子,以此作为协变量。将综合环境因子与单位捕捞努力量渔获量（CPUE）进行相关性检验后进行协同克里金插值,根据平均误差（ME）,均方根误差（RMSE）和标准化均方根（RMSSE）对插值结果评价,探讨此种方法的可行性。研究结果认为:（1）主成分分析方法获得的6-9月份的综合环境因子均与CPUE具有显著相关性;（2）6-7月份ME分别为0.002 6和0.002 5,预测准确性很高,平均预测结果稍高于实际观测值;而8-9月份的ME分别为-0.007 8和-0.000 2,预测准确性较高,平均预测结果稍低于实际观测值。6月份的RMSE估值精度最高,8月份的估值精度最低。6-7月份的RMSSE值小于1,说明都高估了预测的不确定性,8-9月份的RMSSE值大于1,说明都低估了预测的不确定性,则在6-9月份中的预测精度和准确性上会有一定程度的偏差。从ME、RMSE和RMSSE三者综合来看,6-9月的预测值具有一定的可靠性。     

Diagenesis and reservoir quality of sandstones with ancient “deep” incursion of meteoric freshwater——An example in the Nanpu Sag,Bohai Bay Basin,East China

An example of diagenesis and reservoir quality of buried sandstones with ancient incursion of meteoric freshwater is presented in this study. The interpretation is based on information including porosity and permeability, petrography, stable isotopic composition of authigenic minerals, homogenization temperatures (T_h) of aqueous fluid inclusions (AFIs), and pore water chemistry. These sandstones, closely beneath or far from the regional unconformity formed during the late Paleogene period, are located in the thick Shahejie Formation in the Gaoliu area of Nanpu Sag, Bohai Bay Basin, East China. Early-diagenetic calcite cements were leached to form intergranular secondary pores without precipitation of late-diagenetic calcite cements in most sandstones. Feldspars were leached to form abundant intragranular secondary pores, but with small amounts of concomitant secondary minerals including authigenic quartz and kaolinite. The mass imbalance between the amount of leached minerals and associated secondary minerals suggests that mineral leaching reactions occurred most likely in an open geochemical system, and diagenetic petrography textures suggest that advective flow dominated the transfer of solutes from leached feldspars and calcites. Low salinity and ion concentrations of present pore waters, and extensive water rock interactions suggest significant incursion of meteoric freshwater flux in the sandstones. Distances of the sandstones to the regional unconformity can reach up to 1800 m, while with significant uplift in the Gaoliu area, the burial depth of such sandstones (below sea level) can be less than 800–1000 m during the uplift and initial reburial stage. Significant uplift during the Oligocene period provided substantial hydraulic drive and widely developed faults served as favorable conduits for downward penetration of meteoric freshwater from the earth's surface (unconformity) to these sandstone beds. Extensive feldspar leaching has been occurring since the uplift period. Coupled high T_h (95∼115 °C) of AFI and low δ¹⁸O_(SMOW) values (+17∼+20‰) within the quartz overgrowths show that quartz cementation occurred in the presence of diagenetic modified meteoric freshwater with δ¹⁸O_(SMOW) values of −7∼−2‰, indicating that authigenic quartz only have been formed during the late reburial stage when meteoric fresh water penetration slowed down. Secondary pores in thin sections and tested porosity suggest that meteoric freshwater leaching of feldspars and calcite minerals generated approximately 7–10% enhanced secondary porosity in these sandstones. Meteoric freshwater leaching reactions cannot be ignored in similar sandstones that located deep beneath the unconformity, with great uplift moving these sandstones above or close to sea level and with faults connecting the earth's surface with the sandstone beds.     

海底管道出露悬空环境风险的定量评价研究

海底管道是海洋油气输送的主要方式,其运行状况直接关系到海上油气田的安全和海洋生态环境的质量。本文先以海底管道出露悬空作为故障树的顶事件,分析出海洋环境中各项基本事件,构建针对海洋环境的海底管道故障树模型;再以灰色模糊识别为理论基础,量化对海底管道安全有影响的海洋环境因素,并以层次分析法对每个风险因素进行分级赋权,确定评价指标范围和权重,进而构建海洋环境条件的海底管道风险评价体系。利用该体系对平湖油气田海底管道4个区段进行环境风险评价,避免了将整段管道一同评价导致的信息均等化,评价结果不能真实反映风险等级高的区段的情况;评价结果与管道2014~2016年现场检测数据对比,两者均显示P2分区中海底管道的风险等级较高,说明了该模型具有一定的合理性和实用性。     

Performance investigation of a two-raft-type wave energy converter with hydraulic power take-off unit

Raft-type wave energy converter (WEC) is a multi-mode wave energy conversion device, using the relative pitch motion to drive its hydraulic power take-off (PTO) units for capturing energy from the ocean waves. The hydraulic PTO unit as its energy conversion module plays a significant role in storing large qualities of energy and making the output power smooth. However, most of the previous investigations on the raft-type WECs treat the hydraulic PTO unit as a linear PTO unit and do not consider the dynamics of the hydraulic circuit and components in their investigations. This paper is related to a two-raft-type WEC consisting of two hinged rafts and a hydraulic PTO unit. The aim of this paper is to make an understanding of the dynamics of the hydraulic PTO unit and how these affect the performance of the two-raft-type WEC. Therefore, a combined hydrodynamic and hydraulic PTO unit model is proposed to investigate and optimize the performance of the two-raft-type WEC; and based on the simulation of the combined model, the relationships between the optimal power capture ability, the optimal magnitude of the hydraulic PTO force and the wave states are numerically revealed. Results show that an approximately square wave type hydraulic PTO force is produced by the hydraulic PTO unit, which causes the performance of the two-raft-type WEC not to be sinusoidal and the energy capturing manner different from that of the device using a linear PTO unit; moreover, there is an optimal magnitude of the hydraulic PTO force for obtaining an optimal power capture ability, which can be achieved by adjusting the parameters of the hydraulic PTO unit; in regular waves, the optimal power capture ability as well as the optimal magnitude of the hydraulic PTO force normalized by the wave height presents little relationship with the wave height, mainly depends on the wave period; in irregular waves, the trends of the optimal power capture ability and the normalized optimal magnitude of the hydraulic PTO force against the peak wave periods at different significant wave heights are generally identical and show a good correlation. All means that the hydraulic PTO unit of the two-raft-type WEC can be tuned to the wave states, and these would provide a valuable guidance for the optimal design of its hydraulic PTO unit.     

环境因子对菲在黄河口沉积物上吸附的影响

为研究多环芳烃从河口到近海的环境归趋行为与生态风险,考察了沉积物质量浓度、溶解性有机质、温度、盐度4种典型环境因子对菲在黄河口沉积物上吸附的影响,比较了黄河口与近海两种沉积物对菲的吸附性能。研究结果表明,沉积物质量浓度越低,单位质量颗粒物的菲吸附量越高;共存的溶解性有机质对菲的吸附具有增促作用,且腐殖酸比黄腐酸的作用更显著;温度的升高不利于菲的吸附,而盐度的增加有利于菲的吸附。菲在沉积物上的吸附是分配作用与表面吸附两种行为的耦合,其中黄河口沉积物以表面吸附为主,而近海沉积物以分配作用为主。近海沉积物菲吸附量显著高于黄河口沉积物菲吸附量。基于此,菲从河口到近海的迁移过程中,更易于在沉积物表面发生吸附沉降,从而可能降低水相中的生态危害,但对近海底栖生物具有潜在的健康生态风险。     

Field study of set-up effect in open-ended PHC pipe piles

Large-scale field tests were conducted to study set-up effect in open-ended prestressed high-strength concrete pipe piles jacked into stratified soil. Four open-ended prestressed high-strength concrete pipe piles with 13 and 18 m in embedment depth were fully instrumented with fiber Bragg grating sensors and installed. Several restrike dynamic tests were performed on each test pile, with the time interval from 21.5 to 284 hours after installation. Static loading tests (SLTs) were later performed on each test pile at 408 hours after installation to substantiate the dynamic tests. Changes with time in pile bearing capacity and in the shaft and toe resistances were studied based on the results of the pile tests. The development of shaft resistance set-up in different layers was studied in particular. It was found that set-up effect in the shaft resistance is significant and the toe resistance increment was minor. The overall set-up factor of total bearing capacity was found to range from 0.09 to 0.53, and the set-up effect of friction pile is much larger than the end bearing pile. More significant set-up in shaft resistance was observed in fill and alluvium layer. The dimensionless set-up factor A for shaft resistance in marine deposits ranges from 0.5 to 1.43, and it contributes the most to the shaft resistance as the shaft resistance in marine deposits is higher.     

珠江口海域春季富营养化现状与影响分析

随着珠江三角洲经济圈的迅速发展,珠江口海域环境污染日趋严重,于2014年春季对珠江口邻近海域进行环境现状调查,并通过因子分析法和聚类分析法就珠江口调查海域管辖城市和邻近区域的环境现状对珠江口海域环境污染的贡献率进行排序和分类.结果表明:珠江口调查海域营养盐污染较为严重,无机氮含量范围为0.213~1.963 mg/dm~3,平均值为0.888 mg/dm~3;活性磷酸盐含量范围为0.009~0.063 mg/dm~3,平均值为0.033 mg/dm~3.无机氮和活性磷酸盐在珠江口上游和中游均超过海水水质第四类标准,珠江口下游无机氮含量符合海水水质第四类标准,活性磷酸盐含量符合海水水质第二类标准.无机氮以硝氮为主,氨氮次之,亚硝氮含量最低.珠江口调查海域DIN/P变化范围为8.5~168.0,平均值为31.8;富营养化指数E变化范围为0.3~45.1,平均值为8.2,富营养化较为严重.来自广州、东莞、佛山、中山的四大口门排入的污染物对珠江口海域环境影响最大,其次是深圳西部海域沿岸和前海湾、深圳湾排入的污染物,最后是珠海、澳门和香港带入的污染物.从珠江口邻近海域环境现状对珠江口海域环境影响进行较为深入地分析和探讨,为珠江口海域环境的治理和修复提供一些意见和建议.