黑色页岩风化过程中元素的活动性及参照系的选取初探--以湖南省麻田、桃花江剖面为例

系统考察了湖南省麻田和桃花江两个不同发育程度的下寒武统黑色页岩风化剖面,并提出了元素在理想剖面中的分布模式(概念模型);通过对比分析这两个剖面中元素的分布特征与理想分布模式的关系,并结合元素相关性研究、等质量图解的判别分析、微量元素的赋存状态及地球化学性质的探讨,认为在黑色页岩风化过程中,Ti为不活动元素,可作为参照系来计算其它元素的相对迁移性,Nb、Ta的活动性较小,Zr与Hf之间存在着共迁移现象;研究表明化学风化程度是影响元素活动性的重要因素.     

区域性网络定位服务应用技术探讨

通过建立区域连续运行卫星基准站网络系统,建立一种新型定位测量与服务模式,取代现有传统标志式控制点位保存、管理与应用模式,实现虚拟化的、现代网络定位服务,并介绍了不同的测绘精度需求的作业与应用模式。     

Vision-based system of AUV for an underwater pipeline tracker

This paper describes a new framework for detection and tracking of underwater pipeline,which includes software system and hardware system.It is designed for vision system of AUV based on monocular CCD camera.First,the real-time data flow from image capture card is pre-processed and pipeline features are extracted for navigation.The region saturation degree is advanced to remove false edge point group after Sobel operation.An appropriate way is proposed to clear the disturbance around the peak point in the process of Hough transform.Second,the continuity of pipeline layout is taken into account to improve the efficiency of line extraction.Once the line information has been obtained,the reference zone is predicted by Kalman filter.It denotes the possible appearance position of the pipeline in the image.Kalman filter is used to estimate this position in next frame so that the information of pipeline of each frame can be known in advance.Results obtained on real optic vision data in tank experiment are displayed and discussed.They show that the proposed system can detect and track the underwater pipeline online,and is effective and feasible.     

Estimation of potential evapotranspiration over the Yellow River basin: reference crop evaporation or Shuttleworth–Wallace?

Potential evapotranspiration (PET) is a key input to hydrological models. Its estimation has often been via the Penman–Monteith (P–M) equation, most recently in the form of an estimate of reference evapotranspiration (RET) as recommended by FAO‐56. In this paper the Shuttleworth–Wallace (S–W) model is implemented to estimate PET directly in a form that recognizes vegetation diversity and temporal change without reference to experimental measurements and without calibration. The threshold values of vegetation parameters are drawn from the literature based on the International Geosphere–Biosphere Programme land cover classification. The spatial and temporal variation of the LAI of vegetation is derived from the composite NOAA‐AVHRR normalized difference vegetation index (NDVI) using a method based on the SiB2 model, and the Climate Research Unit database is used to provide the required meteorological data. All these data inputs are publicly and globally available. Consequently, the implementation of the S–W model developed in this study is applicable at the global scale, an essential requirement if it is to be applied in data‐poor or ungauged large basins. A comparison is made between the FAO‐56 method and the S–W model when applied to the Yellow River basin for the whole of the last century. The resulting estimates of RET and PET and their association with vegetation types and leaf area index (LAI) are examined over the whole basin both annual and monthly and at six specific points. The effect of NDVI on the PET estimate is further evaluated by replacing the monthly NDVI product with the 10‐day product. Multiple regression relationships between monthly PET, RET, LAI, and climatic variables are explored for categories of vegetation types. The estimated RET is a good climatic index that adequately reflects the temporal change and spatial distribution of climate over the basin, but the PET estimated using the S–W model not only reflects the changes in climate, but also the vegetation distribution and the development of vegetation in response to climate. Although good statistical relationships can be established between PET, RET and/or climatic variables, applying these relationships likely will result in large errors because of the strong non‐linearity and scatter between the PET and the LAI of vegetation. It is concluded that use of the implementation of the S–W model described in this study results in a physically sound estimate of PET that accounts for changing land surface conditions. Copyright © 2006 John Wiley & Sons, Ltd.     

内蒙古高原中东部地区137Cs背景值的确定方法(英文)

In isotope 137 Cs tracing studies, it is a premise to determine suitable 137 Cs reference inventory(CRI) plots and the CRI values. Owing to the heterogeneous spatial distribution of 137 Cs deposition in the ground and diverse, or even irregular, operations in sampling and testing procedures, CRI determination is usually faced with many difficulties and uncertainties. In addition, more difficulties occur in an investigation of a large-scale region because of time constraints and measurement cost limitations. In this study, traditional CRI acquiring methods were summarized first, and then a new complex scheme was established, involving seven core steps and coupling the model estimate and sample measurement. The above CRI determination methodology was implemented in the central-eastern Inner Mongolia Plateau. The case study results showed that the CRI in the dark chestnut soil sub-region, located in the east and south of Xing'an City, exhibited 2447 Bq·m–2; the CRI in the aeolian sandy soil sub-region, positioned in the south central Tongliao City and central Chifeng City, showed 2430 Bq·m–2; the CRI in the sandy chernozem soil sub-region, situated in the northwestern Chifeng City, presented 2384 Bq·m–2; and the CRI in the chestnut soil sub-region, in the southern Xilin Gol City, was 2368 Bq·m–2. The newly proposed CRI determination scheme was proved effective, and the determined CRI plots and CRI values were convincing. The methodology offered a framework for 137 Cs tracing studies in large-scale regions or long-distance transects.     

国际标准物质数据库COMAR及有证标准物质

有证标准物质（CRMs）是具有准确量值的测量标准,在分析方法研究和评价、定性和定量分析、矿产勘查、仲裁检验、质量监督检验等领域发挥着重要的作用。20世纪80年代成立的国际标准物质数据库（COMAR）是目前国际上最大的CRMs数据库,收录来自25个成员国274个生产机构提供的CRMs数量超过10200种。本文从CRMs的数量、分类、发展变化等角度全面评述了国际数据库COMAR,阐述了欧盟组织、美国、中国、日本、澳大利亚等成员国的标准物质研究情况。英、美、法、德等国家的标准物质研究开展较早,研究水平高,处于世界领先地位;中国、日本等亚洲国家标准物质的发展虽起步晚,但发展迅速,已成为向COMAR提供CRMs最多的两个国家,分别为1194种和1456种（截至2013年8月）。COMAR建立以来,工业、有色金属和物理特性三大传统应用领域的CRMs占COMA数据库总CRMs的份额一直较大,比例始终保持50%以上,其中工业领域的CRMs数量最多,占19%;有机、生物与临床类CRMs所占份额最少,仅为7%和3%。随着社会需求的增加,生物与临床、生活质量领域标准物质成为未来标准物质发展的热点方向。本文指出,未来标准物质的发展将由过去的钢铁、有色金属、物理特性等传统领域逐渐转向食品安全、环境保护、气候变化、临床医学、制药产业、生物能源等新兴领域,标准物质的研究制备、定值及不确定度将面临新的技术挑战。     

Simultaneous Determination of Fluorine,Chlorine, Bromine and Iodine in Six Geochemical Reference Materials Using Pyrohydrolysis,Ion Chromatography and Inductively Coupled Plasma‐Mass Spectrometry

Concentrations of halogens (fluorine, chlorine, bromine and iodine) were determined in six geochemical reference materials (BHVO‐2, GS‐N, JG‐1, JR‐1, JB‐1b, JB‐2). Halogens were first extracted from powdered samples using a pyrohydrolysis technique, then hydrolysis solutions were analysed by ion chromatography for F and Cl and inductively coupled plasma‐mass spectrometry for Br and I. The detection limits in solutions were 100 μg l^?1 for both F and Cl and 10 ng l^?1 for Br and I. Considering the extraction procedure, performed on a maximum of 500 mg of sample and producing 100 ml of pyrohydrolysis solution, detection limits in rock samples were 20 mg kg^?1 for F and Cl and 2 μg kg^?1 for Br and I. The mean analytical errors on the studied composition ranges were estimated at 10 mg kg^?1 for F and Cl, 100 μg kg^?1 for Br and 25 μg kg^?1 for I. The concentration values, based on repeated (generally > 10) sample analysis, were in good agreement generally with published values and narrowed the mean dispersion around mean values. Large dispersions are discussed in terms of samples heterogeneity and contaminations during sample preparation. Basaltic RMs were found to be more suitable for studies of halogen compositions than differentiated rock material, especially granites – the powders of which were heterogeneous in halogens at the 500 mg level.     

一种复杂轮廓线的真三维TIN算法

针对多层轮廓线三维重构问题,研究了真三维复杂轮廓线的空间分布特征,通过引入参考基准面概念,提出了一种顾及局部平展特性的真三维TIN生成算法。该方法在递增生成表面过程中,利用了加权最小三角化方法,动态建立参考基准面,将三角面片自身形态和局部邻接轮廓点的相对空间关系有机地结合起来,避免了面片的遮掩重叠和自相交,使得重建表面和原始表面的拓扑差异最小。选取三维地震量测的多层反射波剖面数据进行了实验,并对不同算法得到的实验结果进行了分析比较,得出实验结论:本文算法快速可靠,重建出来的三维表面过渡光滑、自然,更接近实际的表面形态。该方法对于石油、地质勘探三维地质构造形态辅助解译具有现实的应用意义。     

GGR Critical Review of Analytical Developments in 2004–2005

In 2005 Geostandards and Geoanalytical Research embarked upon a new initiative for its readers. Key researchers in various fields of geoanalytical technique development and their application were identified and invited to provide reviews pertinent to their expertise. As noted in the first of these publications "…instead of revisiting the historical context or decades of development in each analytical technique, the goal here has been to capture a snapshot of "hot topics" across a range of fields as represented in the… literature" (Hergt et al . 2005). Rather than prepare an annual review, a decision was taken earlier this year to provide a biennial summary of progress and accomplishments, in this case for the years 2004–2005. The principal techniques employed in Earth and environmental sciences are covered here, and include laser ablation and multicollector ICP-MS, ICP-AES, thermal ionisation and secondary ion mass spectrometry, as well as neutron activation analysis, X-ray fluorescence and atomic absorption spectrometry. A comprehensive review of the development of reference materials, often essential to these techniques, is also provided. The contributions assembled serve both to keep readers informed of advances they may be unfamiliar with, but also as a means of showcasing examples of the breadth and depth of work being conducted in these fields.