激光探针等离子体质谱同时测定锆石微区铀—铅年龄及微量元素

建立了一种利用激光探针等离子体质谱技术同时原位测定锆石Ｐｂ－Ｐｂ及Ｐｂ－Ｕ年龄和２５个微量元素的快速分析方法。Ｐ的检出限为１４μｇ／ｇ,Ｓｃ的检出限为３μｇ／ｇ,Ｒｂ、Ｎｂ、Ｂａ稀土元素Ｎｄ、Ｇｄ、Ｄｙ、Ｅｒ及Ｙｂ的检出限为０．１￣０．３μｇ／ｇ,Ｐｂ的检出限０．５μｇ／ｇ,其它稀土元素及Ｓｒ、ｙ、Ｈｆ、Ｔａ、Ｔｈ和Ｕ的检出限为１０￣９０ｎｇ／ｇ。方法对绝大多数微量元素的相对标准偏差为５￣１５％;     

浮游植物生物量研究 Ⅰ.浮游植物生物量细胞体积转化法

在海洋生态动力学研究过程中,采用浮游植物细胞数量来估算浮游植物丰度可以说是不够精确的,因为不同种的浮游植物细胞大小差别很大,只有浮游植物的生物量才能正确反映海洋生态系中的能量分布.本文以拟合浮游植物细胞相似体积方法,基于胶州湾生态动力学研究所获资料,计算了87种中国近海常见浮游植物的细胞体积、鲜重、碳含量、氮含量.     

南沙海域海底浅层第四系地震地层结构与地质意义

科技进步使得地震采集数据量及其精度实现质的飞跃,南沙海域的地震调查,采用国际先进水平的等离子震源,获得地震剖面精度优于3 m局部甚至可在1 m之内,为科学研究、工程、浅层资源、地质灾害预警等研究奠定基础.在南沙第四系识别出了七个地震反射界面,确定500 ms至海底沉积区间内地震层序与三期海平面升降并与冰期、间冰期对应,典型地震剖面展示第四纪至少有三套完整的具有三角洲顶积层、前积层、底积层的地震相证据,与全球的第四纪海平面的变化一致.精细的浅层地震结构表明：南沙的地质现象丰富,浅层断层非常发育,下切河谷、泥石流、滑坡等地质遗迹的形成的地震相清晰,是地质活动频繁的地区.     

地球磁尾等离子体片磁洞的统计分析

本文利用THEMIS卫星的磁场数据和等离子体观测数据,统计分析地球磁尾等离子体片区域线性磁洞的发生率、时空尺度、分布特征、和发生率与地磁AE指数的相关性.分析结果表明磁尾等离子体片区域的磁洞的时间尺度为几秒到几十秒,空间尺度小于当地的质子回旋半径.通过磁洞在空间的位置分布和卫星数据在空间的数据采样分布的对比,我们发现线性磁洞在等离子体片内经常发生,然而在磁尾等离子体片中的发生率要小于太阳风中磁洞的发生率.本文最后统计分析了磁洞发生和AE指数的相关性,结果表明磁洞可能与地磁活动有关系.     

直流弧光放电等离子体CVD金刚石薄膜中的晶体类型与特征

采用自主研制的直流弧光放电等离子体CVD设备,以甲烷和氢气为气源,在YG6硬质合金基体上制备出主显晶面为（100）、（111）以及纳米晶粒的金刚石薄膜涂层。SEM观测其晶体类型主要为立方体、八面体、立方八面体,其中以立方八面体为主。随着碳源气体浓度的增加,金刚石晶体的形态会呈现从八面体一立方八面体一立方体顺序转变的趋势;而薄膜的表面形貌呈现从主显（111）晶面-（111）与（100）晶面混杂-主显（100）晶面顺序转变的特征。此外,CVD金刚石薄膜中还存在有许多类似接触孪晶、贯穿孪晶、复合孪晶,以及球形或聚晶晶粒形态的晶体,并且多数孪晶属于类似（111）复合孪晶结构。     

Adiabatic indices in a convecting anisotropic plasma

Adiabatic indices for a non-dissipative anisotropic convecting plasma are analyzed, and general expressions for the effective adiabatic index and the partial adiabatic indices parallel (γ_∥) and perpendicular (γ_⟂) to the magnetic field are obtained. It is shown that, in the general case, the value of the effective adiabatic index is not an universal constant and depends on the plasma temperature anisotropy and on the properties of the plasma motion. The values of γ_⟂ and γ_∥ are shown to be independent of the plasma parameters being completely determined by the characteristics of the plasma flow.     

高压密闭消解-电感耦合等离子体光谱和质谱联合测定海洋地质样品中52种元素

An improved analytical method to determine the content of 52 major, minor and trace elements in marine geological samples, using a HF-HCl-HNO_3 acid system with a high-pressure closed digestion method(HPCD), is studied by an inductively coupled plasma optical emission spectrometry(ICP-OES) and an inductively coupled plasma mass spectrometry(ICP-MS). The operating parameters of the instruments are optimized, and the optimal analytical parameters are determined. The influences of optical spectrum and mass spectrum interferences, digestion methods and acid systems on the analytical results are investigated. The optimal spectral lines and isotopes are chosen, and internal standard element of rhodium is selected to compensate for matrix effects and analytical signals drifting. Compared with the methods of an electric heating plate digestion and a microwave digestion, a high-pressure closed digestion method is optimized with less acid, complete digestion,less damage for digestion process. The marine geological samples are dissolved completely by a HF-HCl-HNO_3 system, the relative error(RE) for the analytical results are all less than 6.0%. The method detection limits are 2–40μg/g by the ICP-OES, and 6–80 ng/g by ICP-MS. The methods are used to determine the marine sediment reference materials(GBW07309, GBW07311, GBW07313), rock reference materials(GBW07103, GBW07104,GBW07105), and cobalt-rich crust reference materials(GBW07337, GBW07338, GBW07339), the obtained analytical results are in agreement with the certified values, and both of the relative standard deviation(RSD) and the relative error(RE) are less than 6.0%. The analytical method meets the requirements for determining 52 elements contents of bulk marine geological samples.     

Lofted charged dust distribution above the Moon surface

We developed kinetic theory for the charging processes of small dust grains near the lunar surface due to interaction with the anisotropic solar wind plasma. Once charged, these dust grains, which are exposed to the electric field in the sheath region near the lunar surface, could loft and distribute around such heights off the surface where they reach equilibrium with the local gravitational force. Analytical solutions were derived for the charging time, grain floating potential, and grain charge, characterizing the charging processes of small dust grains in a two-component and in a multi-component solar wind plasma, and further highlighting the unique features presented by the high streaming plasma velocity. We have also formulated a novel kinetic theory of sheath formation around an absorbing planar surface immersed in the anisotropic solar wind plasma in the case of a negligible photoelectric effect and presented solutions for the sheath structure. In this study we combined the results from these analyses and provided estimates for the size distribution function of dust that is expected to be lofted in regions dominated by the solar wind plasma, such as near the terminator and in nearby shadowed craters. Corresponding to the two dominant streaming velocity peaks of 300 and 800 km/s, mean dust diameters of 500 and 350 nm, respectively, are expected to be found at equilibrium at heights of relevance to exploration operations, e.g., around 1.5 m height off the lunar surface. In shadowed craters near the terminator region, where isotropic plasma should be dominating, we estimate mean lofted dust diameter of 800 nm around the same 1.5 m height off the lunar surface. The generally applicable solutions could be used to readily calculate the expected lofted size distribution near the lunar surface as a function of plasma parameters, dust grain composition, and other parameters of interest.     

Scaling law of the reduced magnetic helicity in fast streams

The reduced magnetic helicity is a quantity related to the handedness of the magnetic field fluctuations. In the present paper we study the scaling law of the reduced magnetic helicity in fast streams in the solar wind by using high-resolution magnetic field data by the Ulysses spacecraft. We show that at high frequencies both the left-hand and the right-hand helicity survives, implying that there is no predominance of a single sign. In addition, the scaling law of the magnetic helicity exhibits a strong dependence on the data set analyzed and we do not observe any universal behavior.     

Excitation of ion waves by charged dust beams in ionospheric aerosol release experiments

Ion waves excited by charged dust beams streaming across or along the geomagnetic field in the ionosphere may be generated by plasma instabilities during aerosol release experiments. The injection speed of the dust and gas is comparable to or larger than the ion thermal speed in the background plasma. The dust grains can get charged by plasma collection from the ambient ionosphere, and can thus act as a charged beam that excites instabilities in the background plasma. The theory is applied to relatively early time scales of the order of in the dust-gas cloud expansion, with wave frequencies that are larger than the ion gyrofrequency, and collisions with neutrals are included.