海水中三价与六价铬高效液相色谱-三重四级杆电感耦合等离子体质谱法(HPLC-TQ-ICP-MS)的联用测定

基于高效液相色谱(HPLC)与三重四级杆电感耦合等离子体质谱(TQ-ICP-MS)联用技术,构建海水中三价铬与六价铬在线分离与测定的检测方法。采用TQ-ICP-MS碰撞反应池(KED)技术消除³⁵Cl¹⁶O¹H⁺、⁴⁰Ar¹²C对⁵²Cr同位素测定可能存在的质谱干扰。选用Dionex IonPac AG 7 (4 mm×50 mm10μm)阴离子交换柱为分析柱,对流动相浓度及pH值进行优化,结果表明,当流动相浓度为0.08 mol/L NH₄NO₃、0.6 mmol/L EDTA,pH值7.5,流速1.0 mL/min时,仅需80 s就可以完成三价铬和六价铬的理想分离与测定。对络合剂EDTA的络合浓度、pH、温度及时间进行了深入研究,结果显示,当EDTA浓度为10 mmol/L、络合pH值7.5、络合温度50°C、络合时间2 h时,三价铬可以最大程度的被EDTA络合。在0.1～50.0μg/...     

顺序等离子体光谱法测定钢中钨、铬、钼、钴

采取顺序等离子体光谱技术测定高速工具钢中的主要合金元素Ｗ,Ｍｏ,Ｃｒ和Ｃｏ。用扫描光谱法研究了分析线的选择和干扰情况,建立了准确、快速,同时测定主要合金元素的方法。     

A self-similar solution for spherically symmetric gravitational collapse

A model of gas-dynamical flow during gravitational collapse is analyzed mathematically by assuming its spherical symmetry and self-similarity. A shock wave diverging from the center emerges in this model. The physical requirements imposed on the post-shock flow at the center for the specified parameters at infinity unambiguously determine the shock front and the flow behind it.     

Estimating biomass of phytoplankton in the Jiaozhou Bay I. Phytoplankton biomass estimated from cell volume and plasma volume

I~IOXPhytoplankton is the doAnnant primary producer O'f the pelagic realm, converting inorganicmaterials (e. g., nitrate, phosphate) into new organic compounds (e. g., proteins, lipids) by theprocess of photosynthesis and thereby starting the marine food chain (Lalli and Parsons, 1993).Historically, phytoplankton abundance has primarily been measured and expressed as cellnumbers based on enumeration of the phytoplankton in an aliquot of the sample. Such measurements have established four ba…     

Large-scale transport of plasma in the Earth's plasma sheet: comparative analysis for adiabatic and non-adiabatic cases

A system of multi-fluid MHD-equations is used to compare adiabatic and non-adiabatic transport of the energetic particles in the magnetospheric plasma sheet. A “slow-flow” approximation is considered to study large-scale transport of the anisotropic plasma consisting of energetic electrons and protons. Non-adiabatic transport of the energetic plasma is caused by scattering of the particles in the presence of both wave turbulence and arbitrary time-varying electric fields penetrating from the solar wind into the magnetosphere. The plasma components are devided into particle populations defined by their given initial effective values of the magnetic moment per particle. The spatial scales are also given to estimate the non-uniformity of the geomagnetic field along the chosen mean path of a particle. The latters are used to integrate approximately the system of MHD-equations along each of these paths. The behaviour of the magnetic moment mentioned above and of the parameter which characterizes the pitch-angle distribution of the particles are studied self-consistently in dependence on the intensity of non-adiabatic scattering of the particles. It is shown that, in the inner magnetosphere, this scattering influences the particles in the same manner as pitch-angle diffusion does. It reduces the pitch-angle anisotropy in the plasa. The state of the plasma may be unstable in the current sheet of the magnetotail. If the initial state of the plasma does not correspond to the equilibrium one, then, in this case, scattering influences the particles so as to remove the plasma further from the equilibrium state. The coefficient of the particle diffusion across the geomagnetic field lines is evaluated. This is done by employing the Langevin approach to take the stochastic electric forces acting on the energetic particles in the turbulent plasma into account. The behaviour of the energy density of electrostatic fluctuations in the magnetosphere is estimated.     

Some ideas concerning the problem of anomalous polar E region heating due to Farley-Buneman turbulence

The energetics of the excitation of the Farley-Buneman instability is considered, which is recently observed in the auroral and equatorial E regions of the Earth's ionosphere at altitudes between 100 km and 120 km. In the magnetic field of the Earth the Farley-Buneman instability is excited under the condition of a strong enough external electric field in the case of ion-neutral collisions with frequencies much larger than the ion gyrofrequency and electron-neutral collisions with frequencies much below the electron gyrofrequency. It is shown that the linear increase of the wave amplitudes is caused by a small disbalance between the processes of nonlinear energy pumping into the wave from an external electric field and the energy loss because of the collisions of the electrons and ions with the neutral particles. During the nonlinear energy pumping energy of the external electric field is transferred into a nonlinear current of second order, which is connected with the oscillating motion of the electrons in the wave. The oscillating electron motion takes place perpendicular to wave propagation. From the estimations follows that the energy pumped into a Farley-Buneman wave during one period of pulsation is much larger than the wave energy itself. A new and simply to understand derivation of the anomalous diffusion coefficient is presented, related to the study of the behaviour of a test wave with frequency much above the frequencies of the Farley-Buneman turbulence in developed stage can cause an additional macroscopic nonlinear Pedersen current directed along the external electric field. It is found that the nonlinear Pedersen current can reach the order of the usual Pedersen current and should contribute to the effective heating of the ionospheric plasma.     

空间尘埃等离子体中的重力波特性

建立尘埃等离子体中重力波的基本方程,推导尘埃等离子体中重力波的色散关系,分析地球极区中间层顶处尘埃等离子体层中的重力波特性,研究了重力波在电子密度垂直分层的尘埃等离子体中的反射. 结果表明尘埃等离子体改变了通常大气中的重力内波的色散关系,限制了小水平波数重力内波的传播,改变了波的能量特性,减小了重力波在不均匀大气中垂直向上传播时振幅的增长;在尘埃等离子体中传播时重力波可被电子密度垂直分层的结构反射而导致波能量的集中, 它产生的湍动所导致的空间电子密度的不均匀性分布是极区上空PMSEs的可能机制.     

1997年11月2日微波尖峰源背景参数的诊断

利用北京天文台高时间和高频率分辨率的射电频谱仪对射电尖峰的测量,可以对背景等离子体参数进行的自洽诊断（ 磁场,密度,温度,波矢,及非热电子的性质） 。该诊断基于电子回旋脉塞不稳定性和回旋共振吸收。最后从诊断结果和太阳日冕典型参数的比较以确定尖峰辐射的谐波数。     

WIND observations of coherent electrostatic waves in the solar wind

The time domain sampler (TDS) experiment on WIND measures electric and magnetic wave forms with a sampling rate which reaches 120 000 points per second. We analyse here observations made in the solar wind near the Lagrange point L1. In the range of frequencies above the proton plasma frequency f_pi and smaller than or of the order of the electron plasma frequency f_pe, TDS observed three kinds of electrostatic (e.s.) waves: coherent wave packets of Langmuir waves with frequencies f ≃ f_pe, coherent wave packets with frequencies in the ion acoustic range f_pi ≥ f ≥ f_pe, and more or less isolated non-sinusoidal spikes lasting less than 1 ms. We confirm that the observed frequency of the low frequency (LF) ion acoustic wave packets is dominated by the Doppler effect: the wavelengths are short, 10 to 50 electron Debye lengths λ_D. The electric field in the isolated electrostatic structures (IES) and in the LF wave packets is more or less aligned with the solar wind magnetic field. Across the IES, which have a spatial width of the order of ≃25_D, there is a small but finite electric potential drop, implying an average electric field generally directed away from the Sun. The IES wave forms, which have not been previously reported in the solar wind, are similar, although with a smaller amplitude, to the weak double layers observed in the auroral regions, and to the electrostatic solitary waves observed in other regions in the magnetosphere. We have also studied the solar wind conditions which favour the occurrence of the three kinds of waves: all these e.s. waves are observed more or less continuously in the whole solar wind (except in the densest regions where a parasite prevents the TDS observations). The type (wave packet or IES) of the observed LF waves is mainly determined by the proton temperature and by the direction of the magnetic field, which themselves depend on the latitude of WIND with respect to the heliospheric current sheet.     

EDI convection measurements at 5–6 RE in the post-midnight region

We present the first triangulation measurements of electric fields with the electron drift instrument (EDI) on Equator-S. We show results from five high-data-rate passes of the satellite through the near-midnight equatorial region, at geocentric distances of approximately 5–6 R_E, during geomagnetically quiet conditions. In a co-rotating frame of reference, the measured electric fields have magnitudes of a few tenths of mV/m, with the E × B drift generally directed sunward but with large variations. Temporal variations of the electric field on time scales of several seconds to minutes are large compared to the average magnitude. Comparisons of the “DC” baseline of the EDI-measured electric fields with the mapped Weimer ionospheric model and the Rowland and Wygant CRRES measurements yield reasonable agreement.