原子吸收光谱同时测定多元素的研究

本文着重从提高原子吸收光谱分析的效率出发,利用等离子体光源和光谱仪以替代目前原子吸收光谱分析所用的空心阴极灯和单色器系统,对多种元素进行同时测定。选用了Ca、Mg、Fe、Mn等四个元素进行实验,结果良好。此外,对这种方法的特点以及在实际工作中的应用等方面也作了简要叙述。     

电感耦合等离子体原子发射光谱法测定硅铁中微量元素

应用电感耦合等离子体发射光谱法对硅铁中微量元素的测定进行了研究，采用基体匹配法消除了大量基体的干扰，选择了最佳激发条件，样品的加标回收率在97％－107％。方法用美国硅铁标样分析验证，测定结果与标准值吻合较好，各元素8次测定的RSD％＜7％。     

The charged particle distribution due to emission in a magnetic field

Charged particles emission in a magnetic field on the basis of Boltzman equation with source term is studied. The work develops the results of Narasimha (1962), where the neutral gas expansion into a vacuum is studied. The different specific cases of emission are given for moving sources. The results may be of use when we study phenomena which happen in plasma close to the Earth and in space, as well as for studies of phenomena which take place due to moving satellites in the ionosphere and in interplanetary or interstellar plasma.     

Conjugate observations of the day-side reconnection electric field: A GEM boundary layer campaign

Data from HF-radars are used to make the first simultaneous conjugate measurements of the day-side reconnection electric field. A period of 4 h around local magnetic noon are studied during a geospace environment modeling (GEM) boundary layer campaign. The interplanetary magnetic field (IMF) was southward whilst the eastward component (By) was variable. The flow patterns derived from the radar data show the expected conjugate asymmetries associated with IMF |By| ≥ 0. High-time resolution data (50 and 100 s) enable the flow of plasma across the open/closed field line boundary (the separatrix) to be studied in greater detail than in previous work. The latitude of the separatrix follows the same general trend in both hemispheres but shows a hemispherical difference of 4°, with the summer cusp at higher latitude, as expected from dipole tilt considerations. However, the short-time scale motion of the separatrix cannot be satisfactorily resolved within the best resolution (300 m s⁻¹) of the experiment. The orientation of the separatrix with respect to magnetic latitude is found to follow the same trend in both hemispheres and qualitatively fits that predicted by a model auroral oval. It shows no correlation with IMF By. However, the degree of tilt in the Northern (summer) Hemisphere is found to be significantly greater than that given by the model oval. The convection pattern data show that the meridian at which throat flow occurs is different in the two hemispheres and is controlled by IMF By, in agreement with empirically derived convection patterns and theoretical models. The day-side reconnection electric field values are largest when the radar’s meridian is in the throat flow or early afternoon flow regions. In the morning or afternoon convection cells, the reconnection electric field tends to zero away from the throat flow region. The reconnection electric field observed in the throat flow region is bursty in nature.     

Spacecraft potential control aboard Equator-S as a test for Cluster-II

The payload of Equator-S was complemented by the potential control device (PCD) to stabilise the electric potential of the spacecraft with respect to the ambient plasma. Low potentials are essential for accurate measurements of the thermal plasma. The design of PCD is inherited from instruments for Geotail and Cluster and utilises liquid metal ion sources generating a beam of indium ions at several keV. The set-up of the instrument and its interaction with the plasma instruments on board is presented. When the instrument was switched on during commissioning, unexpectedly high ignition and operating voltages of some ion emitters were observed. An extensive investigation was initiated and the results, which lead to an improved design for Cluster-II, are summarised. The cause of the abnormal behaviour could be linked to surface contamination of some emitters, which will be monitored and cured by on-board procedures in future. The mission operations on Equator-S were not at all affected, because of the high redundancy built into the instrument so that a sufficient number of perfectly operating emitters were available and were turned on routinely throughout the mission. Observations of the effect of spacecraft potential control on the plasma remained limited to just one event on January 8, 1998, which is analysed in detail. It is concluded that the ion beam lead to the predicted improvement of the particle measurements even outside the low density regions of the magnetosphere where the effect of spacecraft potential control would have been much more pronounced, and that the similar instruments for the four Cluster-II spacecraft to be launched in 2000 will be very important to ensure accurate plasma data from this mission.     

Study of the magnetic turbulence in a corotating interaction region in the interplanetary medium

We study the geometry of magnetic fluctuations in a CIR observed by Pioneer 10 at 5 AU between days 292 and 295 in 1973. We apply the methodology proposed by Bieber et al. to make a comparison of the relative importance of two geometric arrays of vector propagation of the magnetic field fluctuations: slab and two-dimensional (2D). We found that inside the studied CIR this model is not applicable due to the restrictions imposed on it. Our results are consistent with Alfvenic fluctuations propagating close to the radial direction, confirming Mavromichalaki et al.’s findings. A mixture of isotropic and magnetoacoustic waves in the region before the front shock would be consistent with our results, and a mixture of slab/2D and magnetoacoustic waves in a region after the reverse shock. We base the latter conclusions on the theoretical analysis made by Kunstmann. We discuss the reasons why the composite model can not be applied in the CIR studied although the fluctuations inside it are two dimensional.     

Non-magnetic aspect sensitive auroral echoes from the lower E region observed at 50 MHz

Backscatter from E-region irregularities was observed at aspect angles close to 90° (almost parallel to the direction of the magnetic field) using the ALOMAR SOUSY radar at Andoya/Norway. Strong electric fields and increased E-region electron temperatures simultaneously measured with the incoherent scatter facility EISCAT proved that the Farley-Buneman plasma instability was excited. In addition, strong particle precipitation was present as inferred from EISCAT electron densities indicating that the gradient drift instability may have been active, too. Backscatter at such large aspect angles was not expected and has not been observed before. The characteristics of the observed echoes, however, are in many aspects completely different from usual auroral radar results: the Doppler velocities are only of the order of 10 m/s, the half-width of the spectra is around 5 m/s, the echoes originate at altitudes well below 100 km, and they seem to be not aspect-sensitive with respect to the magnetic field direction. We, therefore, conclude that the corresponding irregularities are not caused by the mentioned instabilities and that other mechanism have to be invoked.     

Solar and seasonal dependence of ion frictional heating

Ion frictional heating constitutes one of the principal mechanisms whereby energy, originating in the solar wind, is deposited into the Earth’s ionosphere and ultimately the neutral atmosphere. Common programme observations by the EISCAT UHF radar system, spanning the years 1984 to 1995, provide the basis for a comprehensive statistical study of ion frictional heating, results of which are documented in this and a previous paper by the authors. In the present work, the authors demonstrate the solar and seasonal dependence of the universal time distribution of frictional heating, and explain these results with reference to corresponding dependences of the ion velocity. Although EISCAT observes a significant increase in the occurrence of enhanced ion velocities associated with increased solar activity, the latter characterised according to the prevailing 10.7 cm solar flux, this is not reflected to such an extent in the occurrence of frictional heating. It is suggested that this is a consequence of the decreased neutral atmosphere response times associated with active solar conditions, resulting from the higher ionospheric plasma densities present. Seasonal effects on the diurnal distribution of ion frictional heating are well explained by corresponding variations in ionospheric convection, the latter principally a result of geometrical factors. It is noted that, over the entire dataset, the variations in the unperturbed F-region ion temperature, required to implement the identification criterion for ion heating, are highly correlated with model values of thermospheric temperature.     

INTERBALL-Auroral observations of 0.1–12 keV ion gaps in the diffuse auroral zone

We examine ion flux dropouts detected by INTERBALL-Auroral upon traversal of the auroral zone at altitudes of ≈13 000 up to 20 000 km. These dropouts which we refer to as “gaps”, are frequently observed irrespectively of longitudinal sector and appear characteristic of INTERBALL-Auroral ion spectrograms. Whereas some of these gaps display a nearly monoenergetic character (≈12 keV), others occur at energies of a few hundreds of eV up to several keV. INTERBALL-Auroral data exhibit the former monoenergetic gap variety essentially in the evening sector. As examined in previous studies, these gaps appear related to transition from particle orbits that are connected with the magnetotail plasma source to closed orbits encircling the Earth. The latter gap variety, which spreads over several hundreds of eV to a few keV is often observed in the dayside magnetosphere. It is argued that such gaps are due to magnetospheric residence times well above the ion lifetime. This interpretation is supported by numerical orbit calculations which reveal extremely large (up to several tens of hours) times of flight in a limited energy range as a result of conflicting E × B and gradient-curvature drifts. The characteristic energies obtained numerically depend upon both longitude and latitude and are quite consistent with those measured in-situ.     

Sausage mode instability of thin current sheets as a cause of magnetospheric substorms

Observations have shown that, prior to substorm explosions, thin current sheets are formed in the plasma sheet of the Earth’s magnetotail. This provokes the question, to what extent current-sheet thinning and substorm onsets are physically, maybe even causally, related. To answer this question, one has to understand the plasma stability of thin current sheets. Kinetic effects must be taken into account since particle scales are reached in the course of tail current-sheet thinning. We present the results of theoretical investigations of the stability of thin current sheets and about the most unstable mode of their decay. Our conclusions are based upon a non-local linear dispersion analysis of a cross-magnetic field instability of Harris-type current sheets. We found that a sausage-mode bulk current instability starts after a sheet has thinned down to the ion inertial length. We also present the results of three-dimensional electromagnetic PIC-code simulations carried out for mass ratios up to M_i/m_e = 64. They verify the linearly predicted properties of the sausage mode decay of thin current sheets in the parameter range of interest.