多接收电感耦合等离子体质谱Cu同位素测定中的干扰评估

多接收电感耦合等离子体质谱（MC—ICP—MS）是高精度测定铜同位素的新方法,然而在测定中也可能存在干扰。为此对MC—ICPMS Cu同位素测定中的可能干扰进行了评估。主要包括以下方面的内容：（1）对所用标准物质和试剂进行了纯化,所用标准物质和试剂对Cu同位素的同质异位素干扰可以忽略;（2）运用K和／参数进行了讨论,其中K为样品中的Cu浓度与标准溶液中Cu浓度的比值,f为在一定Cu浓度的标准溶液中干扰信号相对于^63Cu真实信号的比值。理论模拟表明,当K值小于1时,即使在质量为63处的干扰很小,对ε^65 Cu的影响也可能很大;（3）通过对理论模拟结果与实际测定结果的对比,发现对所用的试剂而言质量数为65的干扰可以忽略不计;（4）实际测定结果表明,当样品中Cu的浓度是标样中Cu的浓度的0．5～4倍时,测试获得的样品的ε^65值与其真值在误差范围内一致;（5）对潜在的基质效应重点研究了Fe和Co对Cu同位素测定的影响。实验结果表明,当Fe／Cu〈100,Co／Cu〈7时,Fe,Co不影响Cu同位素比值的测定;（6）10个月的重现性研究结果为ε^65=3．5±1．0（2SD）。该测定值在误差范围内与文献报道的值一致     

由束流不稳定性直接放大电磁波的弱磁化修正

本文在文［３］的基础上，考虑背景电磁波色散方程的弱磁化修正，在１＜ωｐｅ／Ωｅ＜１０的范围内（主委适用于太阳高日冕、行星际空间及星系射电喷流等），计算了由束流不稳定性直接放大正常模和反常模的增长率。增长率随着频率、ωｐｅ／Ωｅ、电磁波传播角以及非热电子入射角等参数的变化规律，和忽略磁场时的结果与文［３］大体相同，但是反常模的增长，则随着ωｐｅ／Ωｅ的增大而受到明显的抑制，因而在本文参数范围内，束流不稳定性所放大的电磁波以正常模为主，可以解释太阳ＩＩＩ型爆发和星系射电喷流的偏振性质。     

Electron-Positron Plasmas Created by Ultra-Intense Laser Pulses Interacting with Solid Targets

We discuss the necessary requirements to create dense electron-positron plasmas in the laboratory and the possibility of using them to investigate certain aspects of various astrophysical phenomena, such as gamma ray burst engines. Earth-based electron-positron plasmas are created during the interaction of ultra-intense laser pulses impinging on a solid density target. The fact that positrons can be generated during this interaction has already been demonstrated by Cowan et al. (2000). However, several questions concerning the number, energy, and dynamics of these positrons have yet to be answered. Through insight gathered from PIC simulations, we postulate that the e⁺e⁻ plasma leaves the creation region in dense jets, with relativistic energies. In order to estimate the number density of the positrons created, we begin by first experimentally measuring the hot electron temperatures and densities of such interactions using a compact electron spectrometer. Once the electron distribution is known, the positron creation rate, Γ, can be estimated. This same experimental diagnostic can also, with minor modification, measure the energy distribution of positrons. Initial estimates are that, with proper target and laser configurations, we could potentially create one of the densest arraignments of positrons ever assembled on earth. This experimental configuration would only last for a few femtoseconds, but would eventually evolve into astrophysically relevant pure electron-positron jets, possibly relevant to e⁺e⁻ outflow from black holes.     

束－等离子体不稳定性直接放大电磁波及其对太阳Ⅲ型爆的解释

弱磁化相对论电子束注入等离子体时，由非共振波粒相互作用激发的束－等离子体不稳定性可以直接放大电磁波，计算结果表明：在偏离共振条件的区域，电磁波仍可在较宽的频率范围被放大，并在每个共振峰下形成平台结构。随着谐波数的增高，增长率峰值逐渐变小，峰宽也变窄。本文还分析了电磁波的增长率随背景参数ω＿（ｐｅ）／Ω＿ｅ及高能电子的入射方向和辐射方向的变化规律，在典型的日冕条件下，此类不稳定性所放大的电磁波的增长率大小、带宽、方向性、偏振及谐波等性质，可以用来解释太阳Ⅲ型射电爆发现象，本文的研究亦可用来解释其他天体等离子体辐射。     

Sedimentary provenance in the central Ribeira belt based on laser-ablation ICPMSPb/Pb zircon ages

²⁰⁷Pb/²⁰⁶Pb ages from 420 zircons from 9 upper amphibolite and granulite facies quartzites of the post-1.8 Ga metasedimentary cover from the Occidental and Oriental terranes from the Neoproterozoic central Ribeira belt, in eastern Brazil, are discussed. Ages from the Occidental terrane show that Proterozoic ages predominate with a modal class at 2.1–2.2 Ga and that Archean ages are less common and lie within the 2.5–3.6 Ga range. A wider dispersion on Proterozoic ages down to 1.1 Ga and youngest Neoproterozoic ages (550–700 Ma) were also observed and could be related to the Brasiliano/PanAfrican metamorphic events. The data show that detrital sediments of the Occidental terrane were derived predominantly from erosion of a 1.8–2.2 Ga Paleoproterozoic terrane with a small proportion of a 2.6–3.6 Ga Archean crust. Ages from the Oriental terrane are greatly dispersed, but show a significant proportion of ages between 1.7 and 2.1 Ga, although the great majority are between 0.5 and 1.6 Ga. Only 3 out of 144 grains yield Archean ages, between 2.5 and 2.9 Ga. Based on the greatest errors observed on the data from the Oriental Terrane (100–300 Ma), and a continuum of obtained ages between 2072 Ma (Paleoproterozoic) and 517 Ma (Cambrian), the more plausible interpretation is that the dispersion of ages results from partial resetting of the U–Pb system by Brasiliano metamorphism in Proterozoic–Archean zircons, although a Mesoproterozoic source could not be discarded.     

日食电离层效应

本文分析了1987年9月23日日环食期间,我国14个电离层站和1988年3月18日日全食期间两个站的垂测仪和偏振仪记录,并综合50年代以来历次日食电离层效应的观测结果,证实:1.E层和F₁层光食效应明显,F₂层动力学效应显著;2.f₀F₂存在日食日值大于、小于或等于控制日值三种典型情况;3.TEC食变曲线有凹陷和不凹陷两种典型情况,甚至出现日食日值大于控制日值的异常现象. 本文对F₂层和外电离层的动力学特征作了定性讨论,认为:空间等离子体温度急剧下降和沿场扩散是F₂层和外电离层日食效应的最主要因素;而磁赤道上空等离子体的沿场扩散、“喷泉”效应,热层风和全（环）食带方位是影响位于磁赤道异常区各电离层站日食电离层效应的主要因素.     

Large-scale structure of magnetospheric plasma

Recent investigations of magnetospheric plasma structure are summarized under the broad categories of empirical models, transport across boundaries, formation, and dynamics of the plasma sheet. This report reviews work in these areas during the period 1991 to 1993. Fully three-dimensional empirical models and simulations have become important contributors to our understanding of the magnetospheric system. Some new structural concepts have appeared in the literature: the entry boundary and geopause, the plasma sheet region 1 vortices, the low-energy layer, the adiabaticity boundary or wall region, and a region in the tail to which we refer as the injection port. Traditional structural concepts have also been the subject of recent study, notably the plasmapause, the magnetopause, and the plasma sheet. Significant progress has been made in understanding the nature of plasma sheet formation and dynamics, but the acceleration of electrons to high energy remains somewhat mysterious.     

Elimination of Interferences in the Determination of Palladium,Platinum and Rhodium Mass Fractions in Moss Samples using ICP‐MS/MS

Moss samples (Pleurozium schreberi) exposed to traffic‐related emission of Pd, Pt and Rh were analysed in this study. Successful elimination of interferences was achieved in the determination of Pd, Pt and Rh mass fractions in these samples using inductively coupled plasma‐tandem mass spectrometry (ICP‐MS/MS). Based on the results, a reliable determination of Pd, Pt and Rh mass fractions in microwave‐digested moss samples was obtained using ammonia (10% NH₃ in He) in the collision/reaction cell when ¹⁰³Rh was measured either on‐mass (103→103) or with mass‐shift (103→171) and mass‐shifts for ¹⁰⁸Pd (108→159) and ¹⁹⁵Pt (195→229) were used. The ICP‐MS/MS procedure was validated using BCR‐723 (road dust) as a reference material. In addition, a good agreement between the ICP‐MS/MS results and the results obtained with cloud point extraction and quadrupole ICP‐MS was observed for the moss samples.     

岩石矿物中锆的测定方法研究

测定岩石类样品中的Zr含量,酸溶经常结果偏低,碱溶通常较难获得较低的检出限。本文选取了不同岩性的岩石类国家标准物质GBW07104、GBW07106、GBW07107、GBW07114、GBW07835、GBW07836、GBW07837作为实验样品,分别采用酸溶后复溶、Na2O2碱熔、赶硅后Na2CO3和Na2B4O7三种前处理方法,对电感耦合等离子体质谱仪进行参数优化后上机测定,结果表明:对样品赶硅后加入少量Na2CO3和Na2B4O7混合试剂高温熔融处理岩石样品后,锆的测量值准确度高,而且获得了最低的检出限,同时缩短了方法流程,操作快捷。该方法更适用于各类岩石样品锆的测定。     

两个大洋多金属结核标准物质中27种元素的等离子体质谱法测定

从样品制备、仪器操作参数最佳化、内标补偿等几方面着手,利用两个标准物质(GSPN-2,GSPN-3)发展了大洋多金属结核中27种元素的等离子体质谱(ICP-MS)测定方法.这27种元素包括Ba,Ce,Co,Cu,Dy,Er,Eu,Gd,Ho,La,Li,Lu,Mo,Nd,Pr,Sb,Sc,Sm,Tb,Th,Tm,U,V,W,Y,Yb和Zn.各元素测定值与保证值相当吻合.对GSPN-2和GSPN-3,Ba,Sb,Sc,Y,Zn等5种元素可用外标校准法准确测定,其平均回收率(n=3)在91.4%～106.9%之间;可用内标(103Rh)校准法准确测定其他22种元素,其平均回收率(n=3)在89.4%～110.2%之间;各元素3次测定的相对标准偏差(RSD)为0.0%～11.0%.