非离子聚合物稳定水敏岩层的应用研究

水敏岩层机械破碎出露的新鲜岩面遇水侵蚀产生软化或泥化现象,致使孔(槽)壁变形量增大而失稳。实验表明,低聚合度、非离子型、结晶性好的高分子聚合物无固相稳定液,能以较快的竞争吸附速度在岩石的内、外表面产生渗析胶结和吸附胶结,并在不可逆的作用力下成膜,因而能抑制由水引起的岩石软化、泥化和崩解,可用以解决使用各类泥浆自由水滤失量大且泥皮易脱落而造成的孔(槽)壁坍塌问题。      

成庄矿区构造特征及应力场分析

本文对成庄矿区褶皱、断层及3号煤层的构造特征进行了总结论述.通过对矿区节理的统计、配套和分期,对该区燕山期以来的主应力方位、期次进行了划分,将主应力划分为3期,同时将成庄矿区含煤地层形成以后的构造演化划分为三个阶段:早期应力阶段奠定成庄矿区煤田构造基本格架;中期应力阶段对成庄矿区造成的影响很小;晚期应力阶段完成了矿区内煤田构造基本格局.     

Calculated Phase Relations in the System NCKFMASH (Na2O-CaO-K2O-FeO-MgO-Al2O3-SiO2-H2O) for High-Pressure Metapelites

Petrogenetic grids in the system NCKFMASH (Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O)and the subsystems NCKMASH and NCKFASH calculated with the softwareTHERMOCALC 3.1 are presented for the P–T range 7–30kbar and 450–680°C, for assemblages involving garnet,chloritoid, biotite, carpholite, talc, chlorite, kyanite, staurolite,paragonite, glaucophane, jadeite, omphacite, diopsidic pyroxene,plagioclase, zoisite and lawsonite, with phengite, quartz/coesiteand H₂O in excess. These grids, together with calculated compatibilitydiagrams and P–T and T–X_Ca and P–X_Ca pseudosectionsfor different bulk-rock compositions, show that incorporationof Ca into the NKFMASH system leads to many of the NKFMASH invariantequilibria moving to lower pressure and/or lower temperature,which results, in most cases, in the stability of jadeite andgarnet being enlarged, but in the reduction of stability ofglaucophane, plagioclase and AFM phases. The effect of Ca onthe stability of paragonite is dependent on mineral assemblageat different P–T conditions. The calculated NCKFMASH diagramsare powerful in delineating the phase equilibria and P–Tconditions of natural pelitic assemblages. Moreover, contoursof the calculated phengite Si isopleths in P–T and P–X_Capseudosections confirm that phengite barometry in NCKFMASH isstrongly dependent on mineral assemblage. KEY WORDS: phase relations; metapelites; NCKFMASH; THERMOCALC; phengite geobarometry     

发现天然产高压相矿物的微矿物学途径

迄今人们已经在陨石中发现了11种高压相矿物,它们是地幔过渡带和下地幔的主要矿物相,其中有8种是最近5年来随着研究工作的深入和微矿物学 技术的不断发展而连续发现的。1995年在寺巷口陨石中发现了属于地幔过渡带的林伍德石、 瓦茨利石、镁铁榴石、镁方铁矿和磷酸盐A相,随后又参与了陨石中其它新高压同质多像矿 物的发现和研究。在工作中使用了多种近代微矿物学技术,特别是激光拉曼探针和原位X射线显微分析技术在鉴定中起了关键作用。     

多年冻土区桩基温度场研究

为了解决多年冻土区桥梁桩基浇筑混凝土对冻土层地温的影响,把握后续工程施工,需要对多年冻土区桩基温度场进行认真分析与研究。结合冻土桩的特点,根据冻融循环条件下土体热量迁移的基本规律,基于多孔介质和热力学理论,建立了多年冻土区桩基温度场控制方程。该控制方程不仅包括了热传导和相变潜热对温度分布的影响,而且考虑了混凝土水化热的释放规律,并将研究成果与的西藏某大直径灌注桩温度场现场试验结果进行对比分析。结果表明：所建立的冻土区桩基温度场控制方程计算结果与实测结果吻合较好。在此基础上,应用该模型作数值分析,着重分析了不同深度处桩侧土层温度随时间变化规律和混凝土浇注后不同时期温度沿桩径方向的变化规律,于解决西部多年冻土地区公路运营安全和行车性能,准确掌握多年冻土地区已建桥涵和新建桥涵基础稳定性,具有非常重要的理论和实际意义。     

High-Pressure Behavior of Copper Carbonate: Data from Malachite

Abstract: In-situ high-pressure energy dispersive X-ray diffraction experiments of malachite have been performed using diamond anvil cell and synchrotron radiation. The highest recorded pressure is up to 17.4 GPa. The experimental results reveal that malachite experienced two phase transitions at 0.7 and 7.8 GPa, and the last one is reversible.     

Influence of ferric iron on phase equilibria in greenschist facies assemblages: the hematite‐rich metasedimentary rocks from the Monti Pisani (Northern Apennines)

We have investigated the effects of different Fe₂O₃ bulk contents on the calculated phase equilibria of low‐T/intermediate‐P metasedimentary rocks. Thermodynamic modelling within the MnO–Na₂O–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–O (MnNKFMASHTO) chemical system of chloritoid‐bearing hematite‐rich metasedimentary rocks from the Variscan basement of the Pisani Mountains (Northern Apennines, Italy) fails to reproduce the observed mineral compositions when the bulk Fe₂O₃ is determined through titration. The mismatch between observed and computed mineral compositions and assemblage is resolved by tuning the effective ferric iron content by P–XFe₂O₃ diagrams, obtaining equilibration conditions of 475 °C and 9–10 kbar related to a post‐compressional phase of the Alpine collision. The introduction of ferric iron affects the stability of the main rock‐forming silicates that often yield important thermobaric information. In Fe₂O₃‐rich compositions, garnet‐ and carpholite‐in curves shift towards higher temperatures with respect to the Fe₂O₃‐free systems. The presence of a ferric‐iron oxide (hematite) prevents the formation of biotite in the mineral assemblage even at temperatures approaching 550 °C. The use of P–T–XFe₂O₃ phase diagrams may also provide P–T information in common greenschist facies metasedimentary rocks.     

The structural role of Ti in aluminosilicate liquids in the glass transition range: insights from heat capacity and shear viscosity measurements

The shear viscosities and 1 bar heat capacities of glasses and melts along the 67mol% silica isopleth in the system SiO₂-Al₂O₃-Na₂O-TiO₂ have been determined in the temperature ranges 780-1140 K and 305-1090 K respectively. Anomalous behaviour of both these properties is observed for compositions rich in TiO₂ and/or Al₂O₃, an observation attributed to liquid-liquid phase separation followed by anatase crystallization. For samples which do not show anomalous behaviour, it is found that the partial molar heat capacity of the TiO₂ component previously determined in Al-free compositions reproduces our heat capacities to within 1.3%. Viscosity data show that addition of TiO₂ tends to increase viscosity and melt fragility at constant temperature. Furthermore, heat capacity and viscosity data may be combined within the framework of the Adam-Gibbs theory to extract values of the configurational entropy of the liquids and qualitative estimates of the variation of the average energy barrier to viscous flow. Configurational entropy at 900K is inferred to decrease upon addition of TiO₂, in contrast to previous results from Al-free systems. The compositional limit separating normal from anomalous behaviour, as well as the data for homogenous melts have been used to constrain the structural role of Ti in these samples. Our data are consistent with a majority of Ti in five-fold coordination associated with a titanyl bond, in agreement with previous spectroscopic studies. Furthermore, we find no evidence for a Ti-Al interaction in our samples, and we are led to the conclusion that Al and Ti are incompletely mixed, a hypothesis consistent with the observed reduction of configurational entropy upon addition of TiO₂, suggesting an important role of medium range order in controlling the variations in thermodynamic properties.     

主应力轴循环旋转下高密实粉土稳定性影响研究

为研究主应力轴循环旋转对粉土性状影响,对长江入海口高密实饱和粉土进行了主应力轴180°转幅的循环旋转试验。试验发现,等向固结的高密实粉土在恒定动剪应力比的主应力轴循环旋转下能发生孔压达到初始围压水平的液化破坏,但液化前孔压开展会因动应力水平的不同而呈现以渐变相态点和激变相态点区分的3阶段变化形式,或仅以激变相态点区分的两阶段变化形式。试样应变开展则始终呈现由崩塌点区分的两阶段变化形式,且孔压激变相态点与应变崩塌点同步反映了土体结构崩塌状态,崩塌状态时主应变差双向幅值限制在0.2%～0.4%这一较小范围内。试样进行主应力轴旋转达到崩塌时的应力状态与频率无显著关系,可由 - 空间中一条准不稳定状态线归一化。而以崩塌状态为终点进行归一化的主应力轴循环旋转下孔压振次曲线,可用修正的Seed公式进行较好拟合     

基于球体层状介质模型的大地电磁正演

目前大地电磁测深法的一维正演理论,是基于平面波垂直入射水平层状介质的假设模型。但由于地球是一个球体,因此有必要研究基于球状介质模型的大地电磁正演理论。这里详细推导了基于球体层状介质模型的大地电磁正演公式,计算了若干理论模型。通过同基于水平层状介质模型的大地电磁正演结果对比,验证了正演公式的正确性。同时,指出当探测周期增加到上万秒时,阻抗相位会增大;而当探测周期增加到数十万秒时,视电阻率会减小。