Isotopic evidence of TSR origin for natural gas bearing high H<Subscript>2</Subscript>S contents within the Feixianguan Formation of the northeastern Sichuan Basin,southwestern China

The northeastern area of Sichuan Basin, southwestern China, is the area with the maximal reserve of natural gas containing higher hydrogen sulphide (H₂S) that has been found among the petroliferous basins of China, with the proven and controlled gas reserve of more than 200 billion cubic meters. These gas pools, with higher H₂S contents averaging 9%, some 17%, are mainly distributed on structural belts of Dukouhe, Tieshanpo, Luojiazhai, Puguang, etc., while the oolitic-shoal dolomite of the Triassic Feixianguan Fm. (T₁f) is the reservoir. Although many scholars regard the plentiful accumulation of H₂S within the deep carbonate reservoir as the result of Thermochemical Sulfate Reduction (TSR), however, the process of TSR as well as its residual geological and geochemical evidence is still not quite clear. Based on the carbon isotopic analysis of carbonate strata and secondary calcite, etc., together with the analysis of sulfur isotopes within H₂S, sulphur, gypsum, iron pyrites, etc., as well as other aspects including the natural gas composition, carbon isotopes of hydrocarbons reservoir petrology, etc., it has been proved that the above natural gas is a product of TSR. The H₂S, sulphur and calcite result from the participation of TSR reactions by hydrocarbon gas. During the process for hydrocarbons being consumed due to TSR, the carbons within the hydrocarbon gas participate in the reactions and finally are transferred into the secondary calcite, and become the carbon source of secondary calcite, consequently causing the carbon isotopes of the secondary calcite to be lower (−18.2‰). As for both the intermediate product of TSR, i.e. sulfur, and its final products, i.e. H₂S and iron pyrites, their sulfur elements are all sourced from the sulfate within the Feixianguan Fm. During the fractional processes of sulfur isotopes, the bond energy leads to the ³²S being released firstly, and the earlier it is released, the lower δ ³⁴S values for the generated sulphide (H₂S) or sulfur will be. However, for the anhydrite that participates in reactions, the higher the reaction degree, the more ³²S is released, while the less ³²S remains and the more δ ³⁴S is increased. The testing results have proved the process of the dynamic fractionation of sulfur isotopes.     

海洋粘土沉积物的组成及其增白试验

为了海洋粘土的开发应用,利用FTIR和XRD衍射对其进行了矿物成分分析。结果表明,海洋粘土样品中粘土矿物含量较高,其主要矿物组成为伊/蒙混层和伊利石并含有少量其它矿物,同时证实样品中有磁铁矿和赤铁矿存在。粘土沉积物的化学成分分析显示,粘土中Fe2O3质量分数较高,约为7%。采用酸溶氢气还原法对东太平洋的粘土样品进行了化学增白试验,并探讨了酸种类及其浓度、药剂用量、反应时间、煅烧温度等因素对除铁增白效果的影响,优选出最佳除铁增白方案,使海洋粘土的白度由原来的23.8%提高到73.1%。另外,对增白前后样品的粒度、比表面积和分散性的测试表明,在增白的同时样品的活性也得到了提高。     

山区地形效应对微波辐射特征与土壤水分反演的影响—以青藏高原地区为例

采用星载微波辐射计AMSR-E的低频C波段(6.925GHz),改进了山区微波辐射传输方程,以中国青藏高原地区为例,研究山区可能产生的多种地形效应对微波辐射特征以及土壤水分反演的影响。结果表明,地形效应使得垂直极化亮温最多衰减达到16K,水平极化的亮温最大增强了18K,土壤水分在地形的影响下将被高估超过最大允许误差4%。最后,利用地形效应模拟模型计算的山区地表有效发射率,为山区土壤水分的反演提出了可行的地形校正方法。     

山东大张矽卡岩型铁矿床中铁的富集机制 ——来自流体包裹体和氢、氧同位素的证据

大张铁矿是鲁西地区近年来新发现的一个重要的矽卡岩型矿床.矿体主要赋存于石英二长闪长岩与奥陶系马家沟组灰岩接触带及其附近.根据脉体穿插关系和交代蚀变特征,将大张矽卡岩型铁矿床成矿过程划分为矽卡岩阶段、氧化物阶段、硫化物阶段和碳酸盐阶段.通过对透辉石、绿帘石、石英和方解石等透明矿物显微观察发现,大张铁矿中流体包裹体类型主要...     

气象卫星资料在估测热带气旋强度方向的应用进展

在常规观测资料稀少的热带洋面上,气象卫星是监测热带气旋的主要工具.基于可见光和红外的Dvorak技术通过一系列经验规则,将热带气旋在卫星云图中表现出来的云系结构特征及特定的参数同其发展强度联系起来,但它无法得到气旋内部辐射信息.相对而言,波长较长的微波能穿透热带气旋中高层云系,反映出与热带气旋强度相关的暖核辐射信息.介绍了国内外利用Dvorak技术和星载微波技术估测热带气旋强度的研究进展,指出它们在应用中存在的优势和不足,同时展望了该领域在未来的发展方向.     

水脉泽寄主星系的倾角分析

迄今已经在104个河外星系中检测到水脉泽辐射.同其它没有检测到水脉泽的星系相比,水脉泽星系可能隐含着某种或某些特殊性质.收集了到当前为止(截止2008.09)发表的所有水脉泽星系以及相关的观测资料.计算得到了这些源的星系盘的倾角,并分析讨论了这些水脉泽源星系盘和脉泽盘的倾角可能存在的相关.统计发现只有大约10%的盘脉泽源的星系盘侧面对着我们的视线.然而VLBI对6个盘脉泽源高空间分辨率的成图观测显示那些旋转脉泽盘都是近似侧向的,脉泽盘的倾角都大于80°.对大多数水盘脉泽星系而言,他们的星系盘和脉泽盘方向不一致,这可能间接支持盘脉泽仅仅同星系核相关.为了探讨遮蔽物质的由来和水脉泽辐射的放大机制,对整个水脉泽样本的脉泽光度,X射线吸收气体柱密度和寄主星系倾角的可能相关进行了分析.结果显示高密度的遮蔽物质主要来自于星系核区,而水脉泽辐射的放大更可能发生在围绕核的尘埃盘(～100Pc)或更小尺度的核盘上.     

青海玉树东莫扎抓铅锌矿床地质特征及碳氢氧同位素地球化学研究

东莫扎抓铅锌矿床位于青藏高原羌塘地体东北缘,是"三江"北段铅锌铜银多金属成矿带中的典型代表,对该矿床地质特征和成因类型的研究有助于理解区域铅锌铜银多金属成矿规律,对区域找矿具有重要意义.笔者通过详细的矿区地质考察、系统的矿石光薄片显微镜下鉴定和矿石中方解石的碳、氢、氧同位素分析测试,概述了东莫扎抓铅锌矿床的地质特征和成矿流体的碳、氢、氧同位素组成特征.东莫扎抓铅锌矿床矿体呈似层状展布,产状严格受到矿区逆冲断层的控制,赋矿围岩为上三叠统结扎群波里拉组灰岩和下一中二叠统开心岭群尕迪考组灰岩,发育强白云石化和弱硅化,矿物组合简单,主要为闪锌矿+方铅矿+黄铁矿+白云石+方解石+重晶石,矿石结构以皮壳状、草莓状等胶状结构和他形粒状结构为主,矿石构造为浸染状、角砾状、团块状和脉状.矿石中方解石的δ~(13)C_(V-PDB)值、δ~(18)O_(V-SMOW)值分别为δD_(V-SMOW)值分别为-1.8‰～+3.3‰、+6.1‰～+24.6‰和-137‰～-53‰,计算得到成矿流体的δ~(18)O_(流体)值为-0.5‰～+13.8‰.研究结果表明,东莫扎抓铅锌矿床的成矿流体主要来自盆地封存热卤水和大气降水,金属物质可能由区域流体在长距离迁移过程中通过与碳酸盐岩地层相互作用,以及淋滤含矿地层底部的火山岩而得来,成矿过程中伴随着碳酸盐岩的溶解作用,可能存在有机质的参与.据此,笔者将东莫扎抓矿床归为发育在碰撞造山带中受逆冲推覆断裂构造控制的类MVT铅锌矿床,并初步建立了东莫扎抓铅锌矿床的构造控矿模型.     

安徽淮北煤矿富水区被动式超低频电磁探测结果解析

被动式超低频电磁法是一种在地表直接接收来自地下3～3000Hz频段的天然超低频电磁信号,通过对接收信号的处理和解释实现对地下的岩性界面、构造、资源和能源进行探测,拥有巨大开发潜力的地球物理勘探新方法.首先简述了富水区的被动式超低频电磁探测机理,其次结合安徽省淮北市煤矿富水区的探测实例来说明该方法的适用性和局限性.在数据处理上采用曲线叠加平均、平滑和特征深度标定的方法,同时采用了测深曲线和视电阻率等值断面进行地质解释.解释结果和已知钻孔资料对比发现,无论在测深曲线上,还是在断面图上,富水区均具有明显的特征.     

Low post-Cenomanian denudation depths across the Brazilian Northeast: Implications for long-term landscape evolution at a transform continental margin

The Brazilian Northeast affords good opportunities for obtaining reliable timings and rates of landscape evolution based on stratigraphic correlations across a vast region. The landscape formed in the context of an episodically fluctuating but continuously falling base level since the Cenomanian. After formation of the transform passive margin in Aptian times, landscape development was further driven by a swell-like uplift with its crest situated  300 km from the coastline. The seaward flank of this swell or broad monocline between the interior Araripe and coastal Potiguar basins was eroded, and currently forms a deeply embayed plain bordered by a semi-circular, north-facing erosional escarpment. The post-Cenomanian uplift caused an inversion of the Cretaceous basins and generated a landscape in which the most elevated landforms correspond either to resistant Mesozoic sedimentary caprock, or to eroded stumps of syn-rift Cretaceous footwall uplands. Denudation in the last 90 My never exceeded mean rates of 10 m·My^− 1 and exhumed a number of Cretaceous stratigraphic unconformities. As a result, some topographic surfaces at low elevations are effectively Mesozoic land surfaces that became re-exposed in Cenozoic times. The Neogene Barreiras Formation forms a continuous and mostly clastic apron near the coast. It testifies to the last peak of erosion in the hinterland and coincided with the onset of more arid climates at  13 Ma or earlier. The semi-circular escarpment is not directly related to the initial breakup rift flanks, which had been mostly eroded before the end of the Mesozoic, but the cause and exact timing of post-Cenomanian crustal upwarping are poorly constrained. It could perhaps have been a flexural response of the low-rigidity lithosphere to sediment loads on the margin, and thus a slowly ongoing process since the late Cretaceous. Uplift could instead be the consequence of a more discrete dynamic event related either to Oligocene magmatism in the region, or to continental-scale far-field stresses determined by Andean convergence.     

湘中邵阳凹陷二叠系龙潭组页岩含气性特征与气体成因

针对湘中地区邵阳凹陷二叠系龙潭组页岩气资源评价,部署了页岩气调查井2015H-D3井,通过现场解析气等相关样品测试定量分析了页岩含气性特征及其影响因素,并借助气体稳定碳、氢同位素对气体成因进行了初步探讨.结果显示:钻深从150m处开始出现气显,随深度增加,解析气含量呈现先逐渐增大后减小的趋势,300～425m为最高含气层段,累计厚度达125m,现场解析气含量全部大于0.5m^3/t,最高为2.35m^3/t,平均1m^3/t,证实龙潭组具良好页岩气资源潜力.当埋深大于300m时,解析气含量受有机碳含量控制,而埋深小于300m时,解析气含量并不简单受控于有机碳含量,而是受到保存条件的严重制约.气体碳、氢同位素测试显示δ13C1介于-29.87‰～-36.82‰,平均为-34.52‰,δ¹³C_2介于-29.45‰～-31.02‰,平均为-30.09‰,δD1介于-131.20‰～-178.40‰,平均为-167.40‰.气体成因分析揭示龙潭组页岩气属热成因中的油型气类型.基于沉积现象判断龙潭组为海陆过渡相环境,与氢同位素判断结果基本吻合,但目前还无法确定具体判定区间.