高压密闭消解-电感耦合等离子体光谱和质谱联合测定海洋地质样品中52种元素

An improved analytical method to determine the content of 52 major, minor and trace elements in marine geological samples, using a HF-HCl-HNO_3 acid system with a high-pressure closed digestion method(HPCD), is studied by an inductively coupled plasma optical emission spectrometry(ICP-OES) and an inductively coupled plasma mass spectrometry(ICP-MS). The operating parameters of the instruments are optimized, and the optimal analytical parameters are determined. The influences of optical spectrum and mass spectrum interferences, digestion methods and acid systems on the analytical results are investigated. The optimal spectral lines and isotopes are chosen, and internal standard element of rhodium is selected to compensate for matrix effects and analytical signals drifting. Compared with the methods of an electric heating plate digestion and a microwave digestion, a high-pressure closed digestion method is optimized with less acid, complete digestion,less damage for digestion process. The marine geological samples are dissolved completely by a HF-HCl-HNO_3 system, the relative error(RE) for the analytical results are all less than 6.0%. The method detection limits are 2–40μg/g by the ICP-OES, and 6–80 ng/g by ICP-MS. The methods are used to determine the marine sediment reference materials(GBW07309, GBW07311, GBW07313), rock reference materials(GBW07103, GBW07104,GBW07105), and cobalt-rich crust reference materials(GBW07337, GBW07338, GBW07339), the obtained analytical results are in agreement with the certified values, and both of the relative standard deviation(RSD) and the relative error(RE) are less than 6.0%. The analytical method meets the requirements for determining 52 elements contents of bulk marine geological samples.     

Deep massive sulphide exploration using 2D and 3D geoelectrical and induced polarization data in Skellefte mining district,northern Sweden

Geoelectrical and induced polarization data from measurements along three profiles and from one 3D survey are acquired and processed in the central Skellefte District, northern Sweden. The data were collected during two field campaigns in 2009 and 2010 in order to delineate the structures related to volcanogenic massive sulphide deposits and to model lithological contacts down to a maximum depth of 1.5 km. The 2009 data were inverted previously, and their joint interpretation with potential field data indicated several anomalous zones. The 2010 data not only provide additional information from greater depths compared with the 2009 data but also cover a larger surface area. Several high‐chargeability low‐resistivity zones, interpreted as possible massive sulphide mineralization and associated hydrothermal alteration, are revealed. The 3D survey data provide a detailed high‐resolution image of the top ～450 m of the upper crust around the Maurliden East, North, and Central deposits. Several anomalies are interpreted as new potential prospects in the Maurliden area, which are mainly concentrated in the central conductive zone. In addition, the contact relationship between the major geological units, e.g., the contact between the Skellefte Group and the Jörn Intrusive Complex, is better understood with the help of 2010 deep‐resistivity/chargeability data. The bottommost part of the Vargfors basin is imaged using the 2010 geoelectrical and induced polarization data down to ～1‐km depth.     

Point‐spread functions for interferometric imaging

Interferometric redatuming is a data‐driven method to transform seismic responses with sources at one level and receivers at a deeper level into virtual reflection data with both sources and receivers at the deeper level. Although this method has traditionally been applied by cross‐correlation, accurate redatuming through a heterogeneous overburden requires solving a multidimensional deconvolution problem. Input data can be obtained either by direct observation (for instance in a horizontal borehole), by modelling or by a novel iterative scheme that is currently being developed. The output of interferometric redatuming can be used for imaging below the redatuming level, resulting in a so‐called interferometric image. Internal multiples from above the redatuming level are eliminated during this process. In the past, we introduced point‐spread functions for interferometric redatuming by cross‐correlation. These point‐spread functions quantify distortions in the redatumed data, caused by internal multiple reflections in the overburden. In this paper, we define point‐spread functions for interferometric imaging to quantify these distortions in the image domain. These point‐spread functions are similar to conventional resolution functions for seismic migration but they contain additional information on the internal multiples in the overburden and they are partly data‐driven. We show how these point‐spread functions can be visualized to diagnose image defocusing and artefacts. Finally, we illustrate how point‐spread functions can also be defined for interferometric imaging with passive noise sources in the subsurface or with simultaneous‐source acquisition at the surface.     

激光雷达(LiDAR):获取高精度古地震探槽信息的一种新技术

激光雷达技术是近几十年新发展起来的一种测量技术,已被广泛应用于工程测量、文物保护及地形测量等方面,近几年来活动构造的研究中也已逐步引入。作为活动构造研究的最基础的古地震研究一直还采用传统的地质素描技术进行探槽信息获取,数码照相技术的引入虽然解决了一些问题,但由于照相技术本身的限制,很难克服获取信息的变形和扭曲。激光雷达扫描系统的高信息量、高精度、便捷、安全和易操作等性能,为古地震研究开辟了获取数据信息的新手段和新技术。     

基于单程波偏移算子的地表相关多次波成像

在常规地震资料处理中,多次反射波被视为噪声并从地震数据中去除,以免在之后的地震资料解释中造成误解.而事实上,多次波也是地震信号,是照明波场的一部分,能够对地下构造成像的精度做出贡献.本文分析了多次波在传统单程波叠前深度偏移中产生构造假象的机制和表现,为实现基于单程波偏移算子的多次波成像,修改了单程波叠前深度偏移的边界条件,即将输入的震源波场用包含多次波的记录来替代,输入的记录波场用预测出的表层相关多次波来替代,实现了基于单程波偏移算子的地表相关多次波成像,并从理论上给出了其成像依据.通过基于二范式最小能量差原则求取的匹配因子,将多次波成像结果与一次波成像结果进行匹配叠加,应用多次波成像来弥补一次波成像的不足.简单模型验证了基于单程波偏移算子的多次波成像方法的有效性,最后对Sigsbee2B模型进行了一次波与多次波联合成像试算,盐边界高陡构造成像质量得到了明显改善.     

Spectral Reflectance Analysis of the Caribbean Sea

Reflectance spectral curves were analysed by a derivative method. Derivative reflectance spectra revealed concealed peaks of both reflectance and absorption curves of Caribbean seawater and elements contained within it. Reflectance curves showed a predominant blue colour (400–500 nm) characteristic of Caribbean oligotrophic waters, conspicuous peaks result from the optical properties of chlorophyll a and seawater. Reflectance curves had a similar spectral response. This paper analyses reflectance spectra of surface seawater at 31 stations in the Caribbean Sea during the summer of 2001.     

Subsurface offset behaviour in velocity analysis with extended reflectivity images

Migration velocity analysis with the constant‐density acoustic wave equation can be accomplished by the focusing of extended migration images, obtained by introducing a subsurface shift in the imaging condition. A reflector in a wrong velocity model will show up as a curve in the extended image. In the correct model, it should collapse to a point. The usual approach to obtain a focused image involves a cost functional that penalizes energy in the extended image at non‐zero shift. Its minimization by a gradient‐based method should then produce the correct velocity model. Here, asymptotic analysis and numerical examples show that this method may be too sensitive to amplitude peaks at large shifts at the wrong depth and to artefacts. A more robust alternative is proposed that can be interpreted as a generalization of stack power and maximizes the energy at zero‐subsurface shift. A real‐data example is included.     

基于声学全波形反演的油气藏地震成像方法

岩性油气藏在我国天然气勘探开发中占有非常重要的位置,其分布区域的成像是合理布设井位,提高钻井成功率的关键之一.本文首先基于地下介质的声学近似和波场回传理论,利用频率域单程声波方程延拓计算地震波场,进行全波形反演,获得地层密度和体积模量的定量成像,并依据油气藏物性特征和流体饱和多孔介质岩石物理模型,简要讨论了孔隙度和饱和度与密度及体积模量的关系,明确了地震油气藏成像新概念.在此基础上,定义了基于流体体积模量和孔隙度的成像函数,进行油气藏成像.理论模型计算表明该方法是可行的.通过对西部地区某气田二维地震数据处理,实现了致密砂岩气藏成像,钻井结果证实了气藏区域成像位置的准确性和方法的有效性.     

多排螺旋CT对结核性腹膜炎与癌性腹膜炎的鉴别诊断

目的：探讨结核性腹膜炎（TBP）及癌性腹膜炎（CP）的多排螺旋CT（MSCT）表现,为两者的诊断及鉴别提供依据。方法：搜集2010年9月～2011年9月的24例TBP和47例CP患者的CT影像资料,全部病例经手术和病理进行确诊,采用χ2检验比较各种CT征象在两种病变中的发生率,结合病理变化、临床症状进行分析。结果：TBP组及CP组患者大量腹水,所占比例差异有统计学意义（41.7%、72.3%,χ2=9.695,P〈0.05）。TBP组以壁层腹膜均匀光滑增厚、肠系膜污垢样改变为主,CP组壁层腹膜以不规则、结节、块样增厚为主。结论：以壁层腹膜改变为基础,综合大网膜、肠系膜、腹水及淋巴结改变CT征象进行对两种病变的诊断及鉴别诊断具有重要意义。     

膝关节痛风性关节炎的CT与MRI分析

目的：探讨膝关节痛风性关节炎的CT和MRI影像特征。方法：回顾分析经手术病理证实的21例膝关节痛风性关节炎的CT和MRI表现,其中12例CT,14例MRI。结果：所有病例均能发现痛风结节,CT显示45个,MRI显示48个,痛风结节位于肌腱和韧带共58个,滑膜或关节腔内15个,骨内11个,其他软组织9个。形态呈条块状31个,结节状31个,线状4个,不规则形27个。骨质破坏CT共发现21处,MRI发现24处,位于骨边缘共30处;MRI显示5处骨质破坏周围骨髓水肿。痛风结节在T1WI均呈低至中等信号;T2WI上39个呈混杂信号,6个呈高信号,3个呈低信号。在5例均行CT及MRI检查膝关节比较中：CT显示痛风结节21个,MRI显示痛风结节18个;CT和MRI在显示骨质破坏的部位均为12处,MRI显示骨髓水肿4处;MRI显示软骨异常共5处。结论：膝关节痛风性关节炎在影像上有一定的特征性,CT更容易发现痛风结节,而MRI更合适于评估软组织情况及炎性改变,综合分析两种影像资料有助于准确诊断痛风性关节炎。