Urban Atmospheric Chemistry During the PUMA Campaign 2: Radical Budgets for OH,HO<Subscript>2</Subscript> and RO<Subscript>2</Subscript>

A detailed photochemical box model was used to investigate the key reaction pathways between OH, HO₂ and RO₂ radicals during the summer and winter PUMA field campaigns in the urban city-centre of Birmingham in the UK. The model employed the most recent version of the Master Chemical Mechanism and was constrained to 15-minute average measurements of long-lived species determined in situ at the site. The results showed that in the summer, OH initiation was dominated by the reactions of ozone with alkenes, nitrous acid (HONO) photolysis and the reaction of excited oxygen atoms atoms with water. In the winter, ozone+alkene reactions were the primary initiation route, with a minor contribution from HONO photolysis. Photolysis of aldehydes was the main initiation route for HO₂, in both summer and winter. RO₂ initiation was dominated by the photolysis of aldehydes in the summer with a smaller contribution from ozone+alkenes, a situation that was reversed in the winter. At night, ozone+alkene reactions were the main radical source. Termination, under all conditions, primarily involved reactions with NO (OH) and NO₂ (OH and RCO₃). These results demonstrate the importance of ozone+alkene reactions in urban atmospheres, particularly when photolysis reactions were less important during winter and at nighttime. The implications for urban atmospheric chemistry are discussed.     

Ca-H-Al exchanges and aluminium mobility in two Chinese acidic forest soils: a batch experiment

Exchange reactions between Ca²⁺, H⁺ and Al species and their effects on the aluminium mobility in two Chinese acidic forest soils were studied. The study was based on a batch experiment using extractant solutions with different base cation (calcium) concentrations and pH. The experimental data showed that increased Ca²⁺ concentrations increased the release of soil hydrogen—and aluminium ions, especially from the more acid soil. In agreement with a cation exchange process, the treatment with Ca²⁺ extracts gave significantly decreased soil aluminium saturation (AlS) and increased calcium saturation (CaS) on the ion exchanger. Geochemical calculation using AlCHEMI program showed that activities of Al³⁺ in the extracts were all strongly under-saturated with respect to any gibbsite mineral in the studied pH region (i.e. below 4.1). There were instead apparently two different mechanisms controlling the activities of Al³⁺ in extracts. At pH between about 4.1 and 3.7, the Al³⁺ activity did not change significantly with pH. This is especially the case in the more acid soil. Apparently there are no sizeable pools available to release Al in this pH region. At pH below 3.7 (induced by higher Ca²⁺concentration) the activity of Al³⁺ increased with H⁺ though not in a pattern that complies with a gibbsite solubility control. An increase of base cation deposition would therefore mainly enhance the release of hydrogen ions between pH 4.1 and 3.7 and aluminium ions below pH 3.7 from Chinese mature acidic soils. This will cause an increased acidity of soil water in the short term and a decrease in the soil acidity in the long term. More attention should be paid to this fact in Chinese acid rain studies and control options.     

2020年前我国核能发展的策略和目标研究

本文提出了我国核电发展的 4项策略 ,明确了近中远兼顾的 3个层次的发展目标及相关的重点工程。     

Nuclear modification factor for quarkonium production in high energy proton-nucleus collisions within the parton saturation approach

In this work, we analyze nuclear effects in the inclusive production of quarkonium in proton-nucleus collisions at high energy regime. A theoretical framework that includes initial state effects like nuclear shadowing and gluon density saturation is considered. Numerical results for nuclear modification factor, $R_{pA}(y)$, as a function of meson rapidity in proton-nucleus collisions are presented. The parameter-free predictions are compared to the available data from the Large Hadron Collider. Discussion on the main theoretical uncertainties is made, with emphasis on the phenomenological models for the nuclear saturation scale.     

影响靖宇地区温带气旋的统计分析

核电站因它不排放如二氧化碳这样的温室气体,核电对降低能源部门的碳密集作出了贡献,因此愈益受到人们的重视.在对核电站地区的天气、气候环境进行分析的基础上,对影响靖宇核电站地区的温带气旋作了研究.结果表明:1949-2007年期间影响靖宇地区的温带气旋计111个;受温带气旋影响的年数有41年(约2/3).影响靖宇地区且产生强降雨的温带气旋,主要发生在6、7、8月这3个月,并且一半以上出现在7月.影响靖宇地区的温带气旋大部分是东北气旋,占总数的65%;蒙古气旋与华北气旋次之.此外,对造成严重影响的温带气旋的个例也从天气学角度进行了分析.     

The Origin of the Element Eu in Extremely Metal-poor Halo Stars

The fast neutron capture process (the r-process) occurs in the neutron-rich circumstance. However its concrete physical environment is not very clear. With recent progress in observations, many extremely metal-poor halo stars have been discovered. They have two characteristics: one is the overabundance of fast neutron elements with the relative abundance consistent with that of the sun; the other is that fast neutron element contents in stars at the same metal abundance have a very large dispersion. This provides a particular way to study the origin of the r-process. Simulation was used to study the galaxy's evolution process and the resulting dispersion of fast neutron nuclide contents in stars. The model of galaxy evolution obtained in this way not only contains spontaneous star formation in the gas region, but also includes the star formation excited by the supernova explosion. It is shown from our results that the supernovae at the low mass end should be the place producing the fast neutron nuclides. In addition, it is also shown that the non-uniformity of the galaxy evolution caused by the supernova explosion is not enough to explain the observed dispersion of fast neutron element contents in halo stars. This problem should be further studied.     

Study of the dependence of the star formation rate in the nuclear regions of 39 Kazarian galaxies on their integral parameters

A statistical study of the dependence of the star formation rate in the nuclear regions of 39 Kazarian galaxies on the integral parameters of these galaxies is carried out on the basis of spectra from SDSS DR6. The value of SFR/kpc² for our sample lies in the range 0.013÷2.04M _⨀ year⁻¹kpc⁻² (with the maximum value of 2.04 corresponding to the Kaz 98 (merger)). It is found that the surface density of the rate of star formation correlates positively with the bar structure parameter and EW(Hα), and that, for spiral galaxies of early morphological types, SFR/kpc² is greater than for the later types. It is shown that the color B-R for the galaxies and the color (u − g) _nucl for the nuclear region correlate positively with the total absorption A(Hα) in the Ha line for the nuclear region. The average value of A(Hα) for our samples is found to be A(Hα)=1.3±0.09 magnitudes. Translated from Astrofizika, Vol. 52, No. 2, pp. 211–224 (May 2009).     

Interplay between equilibrium and kinetics in prograde metamorphism of pelites: an example from the Nelson aureole, British Columbia

The distribution of metapelitic mineral assemblages in the Nelson aureole, British Columbia, generally conforms to what is predicted from phase equilibria. However, in detail, the sequence and spacing of isograds, mineral textures and mineral compositions and mineral chemical zoning do not. Two of the main disequilibrium features in the aureole are: (i) delay in the onset and progress of several reactions, i.e. overstepping in temperature; and (ii) unreactivity of staurolite and especially garnet porphyroblasts when they are reactants in prograde reactions. The thermal overstepping is ascribed to difficulty of nucleation of the product porphyroblasts and sluggishness of dissolution of porphyroblasts when they are reactants. The extent to which these kinetic barriers delay the onset of reaction is related to the reaction affinity of each reaction, defined herein as the Gibbs free‐energy difference between the thermodynamically stable, but not‐yet‐crystallized, products and the metastable reactants. For oversteps in temperature (ΔT), reaction affinity is, in turn, related to the difference in entropy (ΔS) between these two states through the relation A = ΔT * ΔS. Mineral reactions which release large quantities of H₂O, such as chlorite‐consuming reactions, have a higher entropy change per unit of temperature overstep, and therefore a higher reaction affinity, than those which release little or no H₂O, such as the chlorite‐free staurolite‐consuming reaction. Thermal overstepping is consequently expected to be less for the former than for the latter, as was estimated in the aureole where 0 to 30 °C overstepping was required for garnet, staurolite and andalusite growth from a muscovite + chlorite‐bearing precursor rock and ～70 °C overstepping was required for the growth of Al₂SiO₅ from a staurolite‐bearing, chlorite‐free precursor. In all cases, reaction progress was strongly influenced by the presence or absence of fluid, with presence of fluid lowering kinetic barriers to nucleation and growth and therefore the degree of thermal overstepping. Textural features of rocks from the nearly coincident garnet, staurolite and andalusite isograds are suggestive of a fluid‐catalysed ‘cascade effect’ in which reaction took place in a narrow temperature interval; several competing muscovite + chlorite‐consuming reactions, some metastable, appear to have occurred in parallel. Metamorphic reaction, fluid release and possibly fluid presence in general in the aureole were episodic rather than continuous, and in several cases well removed from equilibrium conditions. The extent to which these findings apply to regional metamorphism depends on several factors, a major one being enhanced deformation, which is expected to lower kinetic barriers to nucleation and growth.     

The approximation of neutrino heat conduction with neutrino scattering

We have developed an algorithm for taking into account the neutrino scattering in the approximation of neutrino heat conduction. We show that in the case of incoherent neutrino scattering (e.g., by electrons), the coefficients of the temperature and chemical potential gradients are averaged over the neutrino energy using functions that can be found by numerically solving integral equations. The coherent scattering by free nucleons and atomic nuclei can be described by introducing a transport cross section. We suggest a new method for calculating the neutrino—electron scattering functions that is based on Fermi—Dirac functions of integer indices.     

高放废物地质处置阿拉善预选区巴彦诺日公地段目标深度岩体质量预测

高放废物地质处置阿拉善预选区巴彦诺日公地段位于阿拉善地块东部,主要由二叠纪侵入的花岗岩构成,地壳次稳定。通过踏勘,确定了2个钻孔,布置了若干条物探剖面。以这2个钻孔为中心,在17km×17km范围内进行了工程地质测绘,获得了地表结构面分布特征。地表岩体质量以III级岩体为主,地表以下3m~4m处多为I级和II级岩体。根据钻孔岩芯编录和力学试验数据,对岩芯质量进行评价,岩芯整体质量较好,以Ⅰ级和Ⅱ级岩体为主。对比岩体质量和测井数据,发现岩体质量与岩体的物理参数具有明显的相关性。通过和CSAMT剖面上对应位置的对比,建立了岩体质量与电阻率的关系。结合地表岩体质量、钻孔岩芯质量和物探剖面,对目标深度岩体进行了预测：目标深度（600m深左右）岩体质量以Ⅰ级岩体为主,局部有Ⅱ级岩体和Ⅲ岩体。