Rate constants for the reactions of the NO3 radical with HCOOH/HCOO− and CH3COOH/CH3COO− in aqueous solution between 278 and 328 K

The kinetics of the aqueous phase reactions of NO₃ radicals with HCOOH/HCOO^– and CH₃COOH/CH₃COO^– have been investigated using a laser photolysis/long-path laser absorption technique. NO₃ was produced via excimer laser photolysis of peroxodisulfate anions (S₂O ₈ ^2– ) at 351 nm followed by the reactions of sulfate radicals (SO ₄ ^– ) with excess nitrate. The time-resolved detection of NO₃ was achieved by long-path laser absorption at 632.8 nm. For the reactions of NO₃ with formic acid (1) and formate (2) rate coefficients ofk ₁=(3.3±1.0)×10⁵ l mol^–1 s^–1 andk ₂=(5.0±0.4)×10⁷ l mol^–1 s^–1 were found atT=298 K andI=0.19 mol/l. The following Arrhenius expressions were derived:k ₁(T)=(3.4±0.3)×10¹⁰ exp[–(3400±600)/T] l mol^–1 s^–1 andk ₂(T)=(8.2±0.8)×10¹⁰ exp[–(2200±700)/T] l mol^–1 s^–1. The rate coefficients for the reactions of NO₃ with acetic acid (3) and acetate (4) atT=298 K andI=0.19 mol/l were determined as:k ₃=(1.3±0.3)×10⁴ l mol^–1 s^–1 andk ₄=(2.3±0.4)×10⁶ l mol^–1 s^–1. The temperature dependences for these reactions are described by:k ₃(T)=(4.9±0.5)×10⁹ exp[–(3800±700)/T] l mol^–1 s^–1 andk ₄(T)=(1.0±0.2)×10¹² exp[–(3800±1200)/T] l mol^–1 s^–1. The differences in reactivity of the anions HCOO^– and CH₃COO^– compared to their corresponding acids HCOOH and CH₃COOH are explained by the higher reactivity of NO₃ in charge transfer processes compared to H atom abstraction. From a comparison of NO₃ reactions with various droplets constituents it is concluded that the reaction of NO₃ with HCOO^– may present a dominant loss reaction of NO₃ in atmospheric droplets.     

Lake Sediment Core Records of Sulphur Accumulation and Sulphur Isotopic Composition in Central Ontario, Canada Lakes

Stable isotopic compositions and concentrations of total sedimentary sulphur (S) were determined in cores from 6 lakes in the acid-sensitive Muskoka-Haliburton region of south-central Ontario. The isotopic composition of S in deep sediment (> ~ 20 cm) was approximately constant in all lakes, and indicated a pre-industrial δ ³⁴S value between +4.0 and +5.3‰, which is similar to current bulk deposition. Similarly, total S concentrations in deep sediment were relatively low (1.9–5 mg S g⁻¹ dwt) and approximately constant with depth within cores. All lakes exhibited up-core increases in total S and decreases in δ ³⁴S at a depth corresponding to the beginning of industrialization in the Great Lakes region ( ~ 1900), resulting in a generally reciprocal depth pattern between total S concentration and δ ³⁴S ratios. While initial shifts in total S and δ ³⁴S were likely due to enhanced SO₄ reduction of newly available anthropogenic SO₄, both the magnitude and pattern of up-core S enrichment and shifts in δ ³⁴S varied greatly among lakes, and did not match changes in S deposition post 1900. Differences between lakes in total S and δ ³⁴S were not related to any single hydrologic (e.g., residence time) or physical (e.g., catchment-area-to-lake area ratio) lake characteristic. This work indicates that sediment cores do not provide consistent records of changes in post-industrial S deposition in this region, likely due to redox-related mobility of S in upper sediment.     

Chemical characterization of the Neogene Aquifer, Belgium

The evolution of groundwater chemistry along the direction of groundwater flow was studied using hydrochemical data from samples collected along a flow line in the Neogene Aquifer, Belgium. Infiltrating water was found to have a very low mineral content and low pH because the sediments are strongly decalcified. Increasing SiO₂ and cation concentrations along the groundwater flow line indicate silicate-weathering processes, confirmed with the aid of saturation indices, calculated with PHREEQC, and stability diagrams. A classification system based on redox sensitive species was developed and shows that an extensive redox sequence is present in the aquifer. At a shallow depth, pyrite oxidation has caused an increase in sulphate, while iron is precipitated as hydroxides. Elevated arsenic concentrations are related to the reduction of these iron hydroxides at a relatively shallow depth and to the dissolution of siderite at greater depth. Dissolution of carbonate in the aquifer material, present in deep layers and to the north, has lead to increased Ca²⁺ and HCO₃ ^? concentrations. The Ca²⁺ from the groundwater is exchanged for Na⁺, Mg²⁺ and K⁺ adsorbed to the clay surfaces at the bottom of the groundwater reservoir. Although the Neogene Aquifer is well flushed, there are still some marine influences present in the deepest parts.     

PPGIS及其在加拿大安大略省核废料处理选址项目中的应用

介绍了公众参与地理信息系统，给出了一个应用项目——加拿大安大略省核废料处理设施选址公众参与地理信息系统。     

湖南及邻区地壳旋转的可能成因、对大地构造演化的影响及其与大规模成矿作用关系初探

在湖南及邻区,无论从地表的地质构造还是地球物理场上,都表现出明显的环状分布特征。这种特征可能是地壳的旋转运动所造成,它对湖南及邻区大地构造的演化、大规模成矿作用等具有重大的影响。本文对这种旋转运动的可能成因,以及所伴随的一系列地质作用、与大规模成矿作用的关系等进行了初步探讨。     

Explosion seismic reflections from the Earth’s core

Recent seismological studies have presented evidence for the existence of a layer with ultra-low seismic velocities at the core-mantle boundary at ca. 2900 km depth. We report high-amplitude, high-frequency, and laterally coherent seismic arrivals from three nuclear explosions in Siberia. With recording station intervals of 15 km, the seismic phases are readily correlated and show the presence of a thin, ultra-low velocity zone in a region where it was not previously reported. The duration and complexity of the arrivals are inconsistent with a simple core-mantle boundary and require a hitherto unidentified, kilometre-scale, fine structure in the ultra-low velocity zone. The observations may be explained by a ca. 7 km thick, two-layer, ultra-low velocity zone with exceptional low velocities, which indicate the presence of high percentages of melt (>15%), in particular in the lower part of the zone. Waveform variation implies lateral change in the thickness and physical properties of the ultra-low velocity zone with a wavelength of less than 100 km.     

沈阳2×200兆瓦低温核供热站厂址基准地面运动参数的确定

本文在综合厂址、近区域及区域地震地质资料的基础上,根据有关规范的要求,采用地震构造法、最大历史地震法和概率法分别计算了沈阳2×200兆瓦低温核供热站厂址的极限安全地震动SL-2,计算结果分别为200Gal、125Gal和170Gal。取三者最大值,厂址SL-2应当是200gal。厂址基岩地面运动SL-2水平向加速度反应谱取确定性法和概率法计算曲线的外包线作为用于厂址的基岩加速度反应谱。     

高岭石—莫来石反应系列：^27Al和^29SiMAS NMR研究

根据艰我国八个不同成因和特征的高岭土样品在４５０－１４５０℃热处理产物的ＭＡＳ ＮＭＲ谱和ＸＲＤ，ＩＲ，ＤＴＡ等研究结果，结合有关资料讨论了高岭石－莫来石反应序列的几个重要问题：１．高岭石的结构，尤其是五配位铝；２．９８０℃放热峰后的高温相是γ－Ａｌ２Ｏ３而不是Ａｌ－Ｓｉ尖晶石；３．对于莫来石化过程，认为初始莫来石８５０－９５０℃变高岭石形成，二次莫来石由分凝的ＳｉＯ２和γ－Ａｌ２Ｏ３在１２００－     

The mechanisms of shallow earthquakes and the monitoring of a comprehensive test ban

The ability of seismological criteria to identify earthquakes from underground explosions depends partly on the orientation of the earthquake source. Well-determined double-couple moment tensor solutions for a large number of earthquakes have been published in the Harvard centroid moment tensor (CMT) and United Slates Geological Survey (USGS) catalogues. Statistical analyses of these catalogues indicate that the distribution of the orientation of earthquake mechanisms is not random. The distribution of the T axes shows significant clustering around the downward vertical, indicating that a larger number of earthquake mechanisms radiate compressional P -wave energy to teleseismic distances from near the maximum of the radiation pattern than is predicted if earthquake sources are randomly oriented double couples. The clustered T axes correspond to compressional dip-slip mechanisms, and it is this type of mechanism which is believed to cause both the m _b: M _s (the ratio of body-wave to surface-wave magnitude) and first-motion criteria to misidentify an earthquake as an explosion.     

LANDSCAPE PERMANENCE AND NUCLEAR WARNINGS

ABSTRACT. From the perspective of a human lifetime, the hazards of some nuclear wastes are permanent, so the warnings we place at contaminated nuclear sites must be permanent too. I address questions of how best to provide one hundred centuries of public warning at the first facility for permanent disposal, the Waste Isolation Pilot Plant in New Mexico. Scenarios of intrusion developed to guide the design of warning markers predicted that most of the changes in the area will be social and cultural. Because blatant and permanent markers will increase, not reduce, the probability of inadvertent intrusion, the most appropriate warning is a “landscape of illusion.” Such a landscape needs not permanent surface markers but underground warning devices beneath a soft surface marker. No warning can guarantee deterrence for 10,000 years, however.