微量元素在植物光谱中的响应机理研究

微量元素与植物光谱特征的研究是光学遥感定量化研究的重要内容之一。本研究利用高光谱地面光谱仪（GER）在湖南黔阳地区不同地质地球化学背景下的同一垂直剖面上分别测量了岩石、土壤植物（林灌草）的反射光谱曲线和植物叶片的8种微量元素含量。通过研究微量元素Fe,Mn,Cu,Zn,Co,Cr,Mo,B与植物（包括林灌草）反射光谱间的相关性研究发现Co的含量与植物光谱绿区（0．56μm附近）反射率存在强的负相关，Mn,B,Mo和Zn分别在可见光、近红外、短波红外存在较好的相关性和光谱响应。     

绿柱石通道中配合物的振动光谱和辐照裂解

以四川平武富碱型绿柱石为研究对象 ,采用 IR和 L RM测试方法 ,重点对通道中氢化物和多聚合离子的配位构型、辐照裂解及热致转型进行了较深入系统的研究。研究表明 ,在该区成矿作用条件下 ,绿柱石通道中的钠离子趋向与氢离子化合反应生成 Na H氢化物 ,并占据通道中的 C2 位。在垂直 c轴方向上 ,以 3165 cm-1,3114 cm-1及 30 31cm-1伸缩振动弱吸收谱带为特征。[Fe2 ( OH) 4 ] 2 多聚合离子占据通道中的 C1位 ,以 32 34 cm-1伸缩振动锐吸收谱带为特征 (∥ c轴 )。辐照作用导致上述多聚合离子的裂解 ,并形成不稳定的 [H0 ] i心和相对稳定的 [Fe3 ] OH心。与之对应的吸收谱带分别出现在 3110 cm-1(⊥ c轴 )和 335 5cm-1(∥c轴 )处。通道中 Na H和 [Fe2 ( OH) 4 ] 2 多聚合离子的存在 ,可视为该类型绿柱石的一个重要的成因标志。     

高频燃烧—红外碳硫仪测定地质样品中的碳和硫

应用HIR-944B型高频-红外碳硫分析仪,对不同地质样品中碳、硫的测定进行了研究,称样30～60mg,加入0.4g纯铁屑及1.7g钨粒助熔剂,高温燃烧分解试样,红外检测,可定量地质样品中质量为0～O.9mg的硫及质量为0～15mg的碳.用该仪器测定地质标样中碳、硫的结果与标准值符合,碳和硫11次测定的RSD分别是＜2.6%和＜3.0%.     

不同石墨炉技术对钒原子化信号的影响

研究了钒元素在不同石墨炉技术、不同类型石墨管中的原子吸收曲线，探讨了产生这些差异的根本原因。     

Quantitative description of electron precipitation during auroral absorption events in the morning/noon local-time sector

Flux-energy spectra of precipitating electrons are derived from electron density profiles measured by the EISCAT radar during auroral absorption events in the morning/noon local-time sector. The inversion technique uses effective recombination coefficient profiles computed on the basis of a previously validated theoretical model of the lower ionosphere. It is shown that flux-energy spectra for the energy range 30–200 keV are in reasonable agreement with those derived for the same events using trapped flux-energy spectra from geosynchronous satellite data and a model for diffusion of trapped electrons into the loss cone by scattering on whistler waves. During individual events, strongly varying precipitating fluxes are found to be due primarily to varying pitch-angle diffusion.     

Inelastic buildings with tuned mass dampers under moderate ground motions from distant earthquakes

The effectiveness of tuned mass dampers (TMD) in vibration control of buildings was investigated under moderate ground shaking caused by long‐distance earthquakes with frequency contents resembling the 1985 Mexico City (SCT) or the 1995 Bangkok ground motion. The elastic–perfectly plastic material behaviour was assumed for the main structure, with linear TMDs employed by virtue of their simplicity and robustness. The accumulated hysteretic energy dissipation affected by TMD was examined, and the ratio of the hysteretic energy absorption in the structure with TMD to that without it is proposed to be used, in conjunction with the peak displacement ratio, as a supplementary TMD performance index since it gives an indication of the accumulated damage induced in the inelastic structures. For the ground motions considered, TMD would be effective in reducing the hysteretic energy absorption demand in the critical storeys for buildings in the 1.8–2.8 s range. The consequence is reduction in damage of the buildings which would otherwise suffer heavy damage in the absence of TMD, resulting in economical restorability in the damage control limit state. This is of practical significance in view of the current trend toward performance‐based design. Copyright © 2001 John Wiley & Sons, Ltd.     

The NO2 absorption spectrum. III: The 200–300 nm region at ambient temperature

Absorption cross-section measurements of NO₂ performed in our laboratory have been extended to the 200–300 nm region at ambient temperature. Low pressures have been used, limiting the effects of the dimer N₂O₄ which has an absorption cross-section from one to two orders of magnitude larger than that of NO₂ in this region. The results have been compared to those of previous authors and are now available for atmospheric purposes at 0.01 nm intervals.Unité de Recherche Associée au CNRS.     

偏岭石及煅烧高岭石的红外光谱研究

通过对偏岭石和相应煅烧高岭石的红外光谱测定,发现偏岭石同煅烧高岭石在结构上有很大的差异。在偏岭石中不存在非晶态SiO_2相,其中Si—O_4四面体同Al—O_6八面体是相互聚合的:煅烧高岭石(600～995℃)中则不同,其中Si大部分是以独立的非晶态SiO_2相存在,而同其中的Al_2O_3相分离。偏岭石同煅烧高岭石的关系是:对偏岭石进行一定温度的煅烧,它可以转变成像煅烧高岭石一样的结构状态。     

电吸附元素异常来源及找矿模式

电吸附元素异常来源于深部矿体,主要是在各种后期地质作用下溶解了矿体中的矿质成分,并扩散迁移至地表,形成能反映矿体的电吸附晕。电吸附找矿方法在金属矿上所捕获到的异常是在矿体中心垂直投影位置以块状异常出现的称“顶部晕”。在大红山铜矿和李坝金矿上异常也反映了这种异常特征。