An Investigation of Digestion Methods for Trace Elements in Bauxite and Their Determination in Ten Bauxite Reference Materials Using Inductively Coupled Plasma‐Mass Spectrometry

Trace elements from samples of bauxite deposits can provide useful information relevant to the exploration of the ore‐forming process. Sample digestion is a fundamental and critical stage in the process of geochemical analysis, which enables the acquisition of accurate trace element data by ICP‐MS. However, the conventional bomb digestion method with HF/HNO₃ results in a significant loss of rare earth elements (REEs) due to the formation of insoluble AlF₃ precipitates during the digestion of bauxite samples. In this study, the digestion capability of the following methods was investigated: (a) ‘Mg‐addition’ bomb digestion, (b) NH₄HF₂ open vessel digestion and (c) NH₄F open vessel digestion. ‘Mg‐addition’ bomb digestion can effectively suppress the formation of AlF₃ and simultaneously ensure the complete decomposition of resistant minerals in bauxite samples. The addition of MgO to the bauxite samples resulted in (Mg + Ca)/Al ratios ≥ 1. However, adding a large amount of MgO leads to significant blank contamination for some transition elements (V, Cr, Ni and Zn). The NH₄HF₂ or NH₄F open vessel digestion methods can also completely digest resistant minerals in bauxite samples in a short period of time (5 hr). Unlike conventional bomb digestion with HF/HNO₃, the white precipitates and the semi‐transparent gels present in the NH₄HF₂ and NH₄F digestion methods could be efficiently dissolved by evaporation with HClO₄. Based on these three optimised digestion methods, thirty‐seven trace elements including REEs in ten bauxite reference materials (RMs) were determined by ICP‐MS. The data obtained showed excellent inter‐method reproducibility (agreement within 5% for REEs). The relative standard deviation (% RSD) for most elements was < 6%. The concentrations of trace elements in the ten bauxite RMs showed agreement with the limited certified (Li, V, Cr, Cu, Zn, Ga, Sr, Zr and Pb) and information values (Co, Ba, Ce and Hf) available. New trace element data for the ten RMs are provided, some of which for the first time.     

内蒙古北山额勒根乌兰乌拉一带土壤测量地球化学特征及找矿方向

研究区位于内蒙古北山北带,成矿地质条件优越,1∶20万水系沉积物测量异常明显,且分布有额勒根乌兰乌拉斑岩型钼(铜)矿。以1∶5万土壤地球化学测量成果为依据,以地质认识为基础,研究了区内元素地球化学数据特征、地球化学场特征及综合异常特征。认为区内主成矿元素为Mo、Cu、Au,主要的控矿层位为咸水湖组火山岩段,成矿有利侵入体为石炭纪花岗闪长岩。划分出5种综合异常类型,其中与斑岩钼(铜)矿系统有关的综合异常和与奥陶系建造有关的综合异常是今后解剖找矿的重点。     

Results of magnetotelluric surveyon reference geophysical profiles of the Karaton-Sarkamys block in Kazakhstan

A digital geoelectric model of the Karaton-Sarkamys block located in the southern (Kazakhstan) part of the Caspian Depression has been developed on the basis of processing and interpretation of magnetotelluric sounding data. Geoelectric sections and structural maps of geoelectric layers have been constructed. It has been shown that magnetotelluric sounding combined with seismic and GIS data can be efficiently used to obtain additional information on the lithologic and reservoir properties of petroleum plays.     

熔融制样-X射线荧光光谱法测定电气石中12种主次量元素

电气石是一类含硼的铝硅酸盐矿物,化学成分复杂、化学稳定性强,不易湿法分解,B_2O_3含量较高,导致其主次量元素的同时测定存在一定困难。本文采用熔融法制样,建立了X射线荧光光谱法测定电气石Na_2O、MgO、Al_2O_3、SiO_2、P_2O_5、K_2O、CaO、TiO_2、V_2O_5、Cr_2O_3、MnO、TFe_2O_3等主次量元素的分析方法。样品与四硼酸锂-偏硼酸锂-氟化锂(质量比为4.5∶1∶0.4)混合熔剂的稀释比例为1∶10,消除了粒度效应和矿物效应;在缺少电气石标准物质的情况下,选择土壤、水系沉积物及多种类型的地质标准物质绘制校准曲线,利用含量与电气石类似的标准物质验证准确度,测定结果的相对标准偏差小于4.2%。采用所建方法测定四种不同类型电气石实际样品,测定值与经典化学法基本吻合。本方法解决了电气石不易湿法分解和硼的干扰问题,测定结果准确可靠,与其他方法相比操作简便,分析周期短。     

国际上水资源综合管理进展

中国近年实施最严格水资源管理制度、全面推行河长制等一系列政策,不断探索完善水资源综合管理的体制和机制。为加强对水资源综合管理的认识,推动中国水资源综合管理的实施,结合国际社会对水资源综合管理认识和实践新成果,主要梳理总结水资源综合管理理念的形成过程、主要组成、实施状况、存在问题和发展趋势。结果显示:(1)随着对传统水资源管理存在分散化等问题的认识,水资源综合管理的理念逐渐形成,并已被国际社会所接受;(2)水资源综合管理实施"综合"途径管理水资源,强调通过完善实施的环境条件、机构框架、具体管理手段和稳健的水基础设施投资机制,实现用水效率、社会公平、环境可持续的均衡;(3)许多国家已把综合管理的理念和措施纳入到其水资源管理政策和体制框架设计中,并在水管理的实践过程中取得新进展;(4)国际上水资源综合管理理念和经验为进一步完善中国水资源管理提供了启示和借鉴;(5)未来水资源综合管理将进一步得到推广实施,从理念到解决具体水问题的实践过程将进一步加强,并呈现多样性和动态性特征。尽管面临由于气候变化影响和水与社会经济交互作用导致的不确定性、复杂性等问题的挑战,随着水资源综合管理的实践和水科学研究进步,水资源管理将进一步采用整体、多学科和可持续的途径,助力可持续发展目标的实现。     

综合物探法在砂岩型铀矿中深部找矿中的实践与分析——以新疆昭苏盆地为例

为了探查新疆昭苏盆地砂岩型铀矿的异常信息,选择可控源音频大地电磁测量、高精度磁测和土壤氡气测量三种物探方法,并简要介绍各方法的工作原理。通过分析昭苏盆地的地质特征、物性特征和本区的找矿难点,对昭苏盆地综合物探数据所蕴含的信息进行地质-物探综合解译。实践证明:可控源音频大地电磁测量对低阻和高阻体均有良好的电性响应,可以划分地层、推断断裂构造;高精度磁测可以推断氧化还原界面,辅助解释断裂构造;土壤氡气测量可辅助解释断裂构造,对地下铀矿体有指示作用,三种方法的技术特性相互补充,提高了物探解释的准确性。突破了伊犁盆地以往600 m的找矿深度,并以电性稳定的中阻厚层、磁测异常、氡异常偏高晕和峰-谷状曲线作为预测标志,解决了深埋藏条件下赋矿地质体的圈定难点,在昭苏盆地砂岩型铀矿中、深部找矿工作中取得了良好的效果。     

山水林田湖草系统治理之水土保持要义

山水林田湖草是一个生命共同体,山水林田湖草的系统治理观是水土流失治理与生态修复的重要指导思想。水土流失的发生、发展和变化是一个复杂的系统,有其自身规律,水土保持是一门多学科交叉学科,有其科学性与不可替代性,防治水土流失应坚持系统思维,整体施策,系统和综合是水土保持学科建立和事业发展的生命力所在。水土流失在中国广泛分布并长期存在,而且治理程度及年治理进度较低,极不适应生态文明时代人民对美好生活的需求。要充分发挥大自然的自我修复能力,辅助于重点治理,以小促大,大面积、快速恢复植被,降低水土流失强度。将水资源保护、水环境整治、面源污染防治、农村污水及垃圾处理、村容村貌人居环境整治等融为一体,以系统治理观大力推进生态清洁小流域建设。采取系统、全面的措施,重视山地经果林开发土地的水土流失治理与生态保护。对工业化、城镇化、农业现代化过程中的人为扰动破坏区,全过程、全方位落实水土保持措施,促进经济社会的高质量发展。     

滑坡对降雨响应的多指标监测及综合预警探析:以赣南罗坳滑坡为例

降雨量和位移是当前降雨型滑坡监测预警最常用的指标。然而,降雨量和位移监测结果只能反映降雨作用下滑坡的变形情况,不能揭示滑坡内在物理力学性状对降雨的响应。因此,除降雨量和位移监测之外,建立包括体积含水率、基质吸力等反映滑坡动态演化过程的关键指标监测体系必将成为今后更真实地把握滑坡内在演化趋势、更准确地建立滑坡综合预警判据的最有效手段。笔者对赣南地区典型降雨型滑坡进行了多指标监测及综合预警示范研究。结果表明:(1)在降雨条件下滑坡土体内部体积含水率、基质吸力和温度等多指标均产生有规律的动态响应;(2)随着降雨的持续,滑体体积含水率与基质吸力的变化均具有显著的滞后现象;(3)体积含水率和基质吸力变化速率与滑体位移具有显著的正相关性;(4)滑体温度分布变化规律受大气温度和体积含水率的共同影响。以实测数据的滑坡稳定性分析为基准,在考虑实际降雨入渗深度与滑坡稳定性的关联度上,建立了包括日降雨量、体积含水率增加速率、基质吸力减小速率以及位移速度多元指标预警方法体系,提出了基于关键指标综合预警体系及确定方法,旨在为降雨滑坡准确预警提供新模式。     

Brittleness index predictions from Lower Barnett Shale well-log data applying an optimized data matching algorithm at various sampling densities

The capability of accurately predicting mineralogical brittleness index(BI)from basic suites of well logs is desir-able as it provides a useful indicator of the fracability of tight formations.Measuring mineralogical components in rocks is expensive and time consuming.However,the basic well log curves are not well correlated with BI so correlation-based,machine-learning methods are not able to derive highly accurate BI predictions using such data.A correlation-free,optimized data-matching algorithm is configured to predict BI on a supervised basis from well log and core data available from two published wells in the Lower Barnett Shale Formation(Texas).This transparent open box(TOB)algorithm matches data records by calculating the sum of squared errors be-tween their variables and selecting the best matches as those with the minimum squared errors.It then applies optimizers to adjust weights applied to individual variable errors to minimize the root mean square error(RMSE)between calculated and predicted(BI).The prediction accuracy achieved by TOB using just five well logs(Gr,pb,Ns,Rs,Dt)to predict BI is dependent on the density of data records sampled.At a sampling density of about one sample per 0.5 ft BI is predicted with RMSE～0.056 and R2～0.790.At a sampling density of about one sample per 0.1 ft BI is predicted with RMSE～0.008 and R2～0.995.Adding a stratigraphic height index as an additional(sixth)input variable method improves BI prediction accuracy to RMSE～0.003 and R2～0.999 for the two wells with only 1 record in 10,000 yielding a BI prediction error of＞±0.1.The model has the potential to be applied in an unsupervised basis to predict BI from basic well log data in surrounding wells lacking mineralogical measure-ments but with similar lithofacies and burial histories.The method could also be extended to predict elastic rock properties in and seismic attributes from wells and seismic data to improve the precision of brittleness index and fracability mapping spatially.     

广西气象数据中心机房供电系统设计与保障

针对供配电系统容易发生的安全隐患,优化设计配电系统结构、采用一体化运维监控平台和采用高质量、高可靠性的设备,消除单点故障瓶颈,确保在停电、设备故障、维修维护等各种情况下提供不中断或快速恢复供电,避免停电对业务正常运行造成影响,确保机房供电安全。