Carbon Isotope Geochemistry of the Orinoco Basin

Stable carbon isotope ratios have been used to study the sources of particulate organic carbon (POC) and total dissolved inorganic carbon in the Orinoco Basin. The isotopic composition of total dissolved inorganic carbon shows a range of from -8·1 to -23·0 ppt, an indication of dominance of biological processes. The isotopic composition of POC exhibits a range of from -24·1 to -34·6 ppt with little seasonal variation. The isotopic evidence indicates that the POC is predominantly of terrestrial origin rather than a result of in situ planktonic production. The similarity of isotopic composition of POC and coastal sediments suggests that riverine organic detritus has been transported 30-50 km offshore in a direction parallel to the Orinoco river channel.     

用于遥感测温的双通道红外辐射计

本文介绍了一种用于遥感温度测量的、且与目前大多数星载红外遥感器波段相一致的双通道红外辐射计。该辐射计采用碲镉汞做为探测器。它可用于温度测量,其同步测量数据可用于星载红外遥感器的定标和数据的真实性检验。本文介绍了总体方案、精度计算及光、机、电和数据处理等部分的设计方法。     

渤海及北黄海河流悬浮颗粒碳氮同位素时空分布及源解析

选择流入渤海和北黄海的36条主要河流为研究对象,对比了平水期、丰水期和枯水期水体中悬浮颗粒物和河流表层沉积物的碳和氮稳定同位素的地球化学特征,并对颗粒物有机质碳和氮来源进行分析。结果表明,水体悬浮有机质碳同位素总体上表现为δ13C平水期δ13C丰水期δ13C枯水期的特点,δ15N值呈δ15N丰水期δ15N平水期δ15N枯水期的特点。渤海和北黄海的主要入海河流悬浮颗粒物有机质的来源具有明显的季节性差异,悬浮颗粒有机质碳平水期(春秋季)来源以C3植物、土壤有机质和水生藻类为主,丰水期(夏季)碳的各来源中浮游植物的贡献率明显增大,枯水期(冬季)则表现为陆源C3植物分解和水源性有机质的混合来源;悬浮颗粒态氮的来源与季节性降水量、生活污水、合成化肥及河流内源性水生植物密切相关。     

Finite element modeling of heating phenomena of cracks excited by high-intensity ultrasonic pulses

A three-dimensional thermo-mechanical coupled finite element model is built up to simulate the phenomena of dynamical contact and frictional heating of crack faces when the plate containing the crack is excited by high-intensity ultrasonic pulses. In the finite element model, the high-power ultrasonic transducer is modeled by using a piezoelectric thermal-analogy method, and the dynamical interaction between both crack faces is modeled using a contact-impact theory. In the simulations, the frictional heating taking place at the crack faces is quantitatively calculated by using finite element thermal-structural coupling analysis, especially, the influences of acoustic chaos to plate vibration and crack heating are calculated and analysed in detail. Meanwhile, the related ultrasonic infrared images are also obtained experimentally, and the theoretical simulation results are in agreement with that of the experiments. The results show that, by using the theoretical method, a good simulation of dynamic interaction and friction heating process of the crack faces under non-chaotic or chaotic sound excitation can be obtained.     

热红外波段大气透过率和程辐射的估算方法

文中对M ONTRAN模型内嵌6种大气模式的主要特性差异进行分析,并以中纬度夏季大气模式为例,分析了主要参数(如水汽、臭氧以及气温等)对估算热红外波段大气透过率和程辐射的影响。论文最后对利用探空数据构造完整大气模式进行了研究。     

Establishment and application of an intelligent treating method for oil spill identification

In the identifying process of an oil spill accident, manual integral and artificial visual comparison are commonly used at present to determine the oil spill sources, these methods are time-consuming and easily affected by human factors. Therefore, it is difficult to achieve the purpose of rapid identification of an oil spill accident. In this paper, an intelligent method of automatic recognition, integration and calculation of diagnostic ratio of Gas Chromatography-Mass Spectrometer (GC/MS) spectrum are established. Firstly, four hundreds of samples collected around the world were analyzed using a standard method and Retention time locking technology (RTL) was applied to reduce the change of retention time of GC/MS spectrum. Secondly, the automatic identification, integration of n-alkanes, biomarker compounds, polycyclic aromatic hydrocarbons and calculation of the diagnostic ratios were realized by MATLAB software. Finally, a database of oil fingerprints were established and applied successfully in a spill oil accident. Based on the new method and database, we could acquire the diagnostic ratios of an oil sample and find out the suspected oil within a few minutes. This method and database can improve the efficiency in spilled oil identification.     

碳氮稳定同位素比值在潮间带大型底栖动物组织间差异性研究

近年来,稳定同位素技术已被广泛应用于食物网研究中。然而,生物样品取样部位对食物网构建的影响的研究相对少见。大型底栖动物作为潮间带食物网的重要组成部分,在食物网研究中有必要对其采样部位进行统一,以增加研究结果的准确性及可比较性。本研究选取黄河三角洲和烟台潮间带10种代表性的大型底栖动物,比较δ13C和δ15N在不同采样部位中的差异。结果显示,对于大多数底栖动物而言,采样部位将直接影响到δ13C和δ15N的测定结果。当底栖动物作为摄食者,需分析其食性和营养级时,应统一采用肌肉组织,如贝类的闭壳肌或足部肌肉,蟹类的鳌足肌肉,鱼类的背部肌肉;当底栖动物作为被摄食者,需分析次级消费者的食性和营养级时,除多毛类采用去除消化道内容物的体壁外,其他种类应选取整体（难以被消化的组织除外）,如贝类的软体部,蟹类肌肉与鳃等的混合组织。     

运用多元统计方法识别浙北海域两个典型港湾的水质状况

浙北海域两个典型港湾,杭州湾与象山港的水体污染状况日趋严重。本文运用多元统计方法,对分析了研究海域水体的物理及生物地球化学要素进行了量化分析。结果表明,根据物理及生物地球化学特性,层次聚类分析可将研究海域划分为两个不同的子区域;主成分分析分别在杭州湾和象山港识别出3个潜在的污染源,且陆源径流的输入、沿岸工业排污以及自然演化过程为主要源头。因此,研究海域的生态环境保护刻不容缓,应该立即采取相关措施。     

Mud volcanism and fluid geochemistry in the Cheleken peninsula,western Turkmenistan

A geological and geochemical study has been carried out to investigate the relationships between major mud volcano structures and deep fluid migration in the Cheleken peninsula, in the South Caspian Basin. The fluid geochemistry allowed the origin and migration of the saline waters and the hydrocarbons to be deduced along with the regional source and reservoir rocks. The emitted waters formed by the mixing of deep highly saline water from the main source rocks of the Maykop Fm with the Caspian-like pore water contained in the Pliocene reservoirs. The water composition is very similar to that emitted by the mud volcanoes in Azerbaijan, allowing comparisons to be done between the reservoirs in the western and eastern sides of the South Caspian Basin. The associated oil is derived from a mixed type II/III kerogen deposited in a sub-oxic marine environment and generated during the early oil window. The oil biomarkers indicate that the source rock is the Maykop Fm., as previously determined for the other areas of the South Caspian Basin.The spontaneous emissions, showing different morphologies, are mainly aligned along normal and transtensive fault systems, which provide effective pathways for rapid fluid ascent from deep reservoirs to the surface.     

表面粗糙对渤海海冰热红外辐射方向特征的影响研究

热红外遥感技术使大范围、快速地监测渤海海冰表面温度成为可能。然而,目前绝大多数遥感器都是小视场角的,只对海冰在某个方向上的辐射能量进行了测量。由于自然界的海冰大多数都是高低起伏的、不平坦的,如果近似地认为遥感像元尺度内各部分温度是相同的,有时会带来较大误差。在盛冰期的渤海辽东湾东岸固定冰区,分别用3D激光扫描仪、热红外成像仪和自计温度计测量了渤海海冰的表面形状、辐射亮温和真实温度。结果表明,由于海冰表面粗糙,会形成三维非同温像元。同时,也会导致传感器在粗糙海冰的各个部分的局部观测天顶角与整体观测天顶角有所不同,造成粗糙海冰与平整海冰的方向辐射特征有较大差异,平整海冰更接近理想平面,粗糙海冰更接近朗伯面。