Polymorphic phase transition in Superhydrous Phase B

We synthesized superhydrous phase B (shy-B) at 22 GPa and two different temperatures: 1200°C (LT) and 1400°C (HT) using a multi-anvil apparatus. The samples were investigated by transmission electron microscopy (TEM), single crystal X-ray diffraction, Raman and IR spectroscopy. The IR spectra were collected on polycrystalline thin-films and single crystals using synchrotron radiation, as well as a conventional IR source at ambient conditions and in situ at various pressures (up to 15 GPa) and temperatures (down to −180°C). Our studies show that shy-B exists in two polymorphic forms. As expected from crystal chemistry, the LT polymorph crystallizes in a lower symmetry space group (Pnn2), whereas the HT polymorph assumes a higher symmetry space group (Pnnm). TEM shows that both modifications consist of nearly perfect crystals with almost no lattice defects or inclusions of additional phases. IR spectra taken on polycrystalline thin films exhibit just one symmetric OH band and 29 lattice modes for the HT polymorph in contrast to two intense but asymmetric OH stretching bands and at least 48 lattice modes for the LT sample. The IR spectra differ not only in the number of bands, but also in the response of the bands to changes in pressure. The pressure derivatives for the IR bands are higher for the HT polymorph indicating that the high symmetry form is more compressible than the low symmetry form. Polarized, low-temperature single-crystal IR spectra indicate that in the LT-polymorph extensive ordering occurs not only at the Mg sites but also at the hydrogen sites.     

Combining two filter paper‐based analytical methods to monitor temporal variations in the geochemical properties of fluvial suspended particulate matter

Many of the commonly used analytical techniques for assessing the properties of fluvial suspended particulate matter (SPM) are neither cost effective nor time efficient, making them prohibitive to long‐term high‐resolution monitoring. We present an in‐depth methodology utilizing two types of spectroscopy which, when combined with automatic water samplers, can generate accurate, high‐temporal resolution SPM geochemistry data, inexpensively and semi‐destructively, directly from sediment covered filter papers. A combined X‐ray fluorescence spectroscopy and diffuse reflectance infrared Fourier transform spectroscopy approach is developed to estimate concentrations for a range of elements (Al, Ca, Ce, Fe, K, Mg, Mn, Na, P, Si, Ti) and compounds (organic carbon, Al_dithionate, Al_oxalate, Fe_dithionate, and Fe_oxalate) within SPM trapped on quartz fibre filters at masses as low as 3 mg. Calibration models with small prediction errors are derived, along with mass correction factor models to account for variations in retained SPM mass. Spectral pre‐processing methods are shown to enhance the reproducibility of results for some compounds, and the importance of filter paper selection and homogeneous sample preparation in minimizing spectral interference is emphasized. The geochemical signal from sediment covered filter papers is demonstrated to be time stable enabling samples to be stored for several weeks prior to analysis. Example results obtained during a heavy precipitation event in October 2012 demonstrate the methodology presented here has considerable potential to be utilized for high‐resolution monitoring of SPM geochemistry under a range of in‐stream hydrological conditions. Copyright © 2013 John Wiley & Sons, Ltd.     

Quantitative estimation of submarine groundwater discharge using airborne thermal infrared data acquired at two different tidal heights

Submarine groundwater discharge (SGD) plays an important role in coastal biogeochemical processes and hydrological cycles, particularly off volcanic islands in oligotrophic oceans. However, the spatial and temporal variations of SGD are still poorly understood owing to difficulty in taking rapid SGD measurements over a large scale. In this study, we used four airborne thermal infrared surveys (twice each during high and low tides) to quantify the spatiotemporal variations of SGD over the entire coast of Jeju Island, Korea. On the basis of an analytical model, we found a linear positive correlation between the thermal anomaly and squares of the groundwater discharge velocity and a negative exponential correlation between the anomaly and water depth (including tide height and bathymetry). We then derived a new equation for quantitatively estimating the SGD flow rates from thermal anomalies acquired at two different tide heights. The proposed method was validated with the measured SGD flow rates using a current meter at Gongcheonpo Beach. We believe that the method can be effectively applied for rapid estimation of SGD over coastal areas, where fresh groundwater discharge is significant, using airborne thermal infrared surveys.     

Submarine groundwater discharge revealed by aerial thermal infrared imagery: a case study on Jeju Island,Korea

Submarine groundwater discharge (SGD) is a global phenomenon that carries large volumes of groundwater and dissolved chemical species such as nutrient, metals, and organic compounds to coastal zones. We report the influence of SGD on the coastal waters of Jeju Island, Korea, using high‐resolution aerial thermal infrared (TIR) mapping techniques and field investigations. An aircraft‐based system was implemented using a cost‐effective TIR camera for aerial TIR mapping. Ground‐based calibrations and system integration with GPS/IMU (global positioning system/inertial measurement unit) were performed for the aerial systems. The aerial surveys showed distinct low‐temperature signatures of SGD along the coasts of Jeju Island, revealing large groundwater inputs from the coastal aquifers to the ocean. Multiple aerial surveys over a range of seasons and tidal stages revealed that SGD rates dynamically affect the sea surface temperature (SST) of the coastal zone. The in‐situ measurements supported that SGD has a substantial influence on the coastal water chemistry as well as SST. Our observations highlight the extent to which aerial‐based TIR mapping can serve as a powerful tool for studying SGD and other coastal processes. Copyright © 2016 John Wiley & Sons, Ltd.     

临震前地壳变形不动点现象与机制研究

在综合分析国内外地形变前兆研究现状的基础上,结合汶川8.0级地震前GPS、应变、重力等研究结果,提出临震前震源区域可能出现变形不动点现象。地壳变形过程中的不动点现象是临震前区域应力场进入临界状态的重要标志,是地震潜在危险区域划定的重要依据。借助不动点理论,给出汶川地震前变形不动点集合的演化,结合大区域地震活动空区与远场显著形变异常分布,探讨变形不动点现象发生的动力学背景,验证了汶川地震前地壳变形的不动点现象是大区域应力场有序运动的结果。     

PMODTRAN: a parallel implementation based on MODTRAN for massive remote sensing data processing

MODerate resolution atmospheric TRANsmission (MODTRAN) is a commercial remote sensing (RS) software package that has been widely used to simulate radiative transfer of electromagnetic radiation through the Earth's atmosphere and the radiation observed by a remote sensor. However, when very large RS datasets must be processed in simulation applications at a global scale, it is extremely time-consuming to operate MODTRAN on a modern workstation. Under this circumstance, the use of parallel cluster computing to speed up the process becomes vital to this time-consuming task. This paper presents PMODTRAN, an implementation of a parallel task-scheduling algorithm based on MODTRAN. PMODTRAN was able to reduce the processing time of the test cases used here from over 4.4 months on a workstation to less than a week on a local computer cluster. In addition, PMODTRAN can distribute tasks with different levels of granularity and has some extra features, such as dynamic load balancing and parameter checking.     

伟晶岩型锂矿成矿构造背景研究

锂是银白色的、自然界最轻的金属,广泛应用于纺织、陶瓷、冶金、核能、新能源等领域,有“高能金属”、“21世纪的能源金属”之称。锂矿床按成因类型可分为内生和外生两种类型,内生型可具体分为花岗伟晶岩型、花岗岩型、云英岩型和岩浆热液型,外生型则包括盐湖型及地下卤水型（赵一鸣等,2004）。伟晶岩型锂矿主要开采锂辉石、透锂云母、锂云母、磷铝锂石等,是锂矿资源的重要来源。     

Characterisation of carbonate minerals from hyperspectral TIR scanning using features at 14 000 and 11 300 nm

Rapid characterisation of carbonate phases in hyperspectral reflectance spectra acquired from drill core material has important implications for mineral exploration and resource modelling. Major infrared active features of carbonates lie in the thermal region around 6500 nm, 11 300 nm and 14 000 nm, with the latter two features being most useful for differentiating mineral species. A scatter diagram of the wavelength of the 14 000 nm feature vs that of the 11 300 nm feature, powerfully differentiates carbonates. Although the wavelength of the 11 300 nm peak is easily measured, the 14 000 nm trough and peak are commonly weak and their wavelengths can confidently be used only after filtering the spectra, e.g. selecting only those with the trough and peak separated by 175–230 nm, typical of common carbonates. The method is demonstrated with drillhole 120R from the Rosebery polymetallic VHMS deposit in western Tasmania, which has been scanned with the HyLogger-3 system. A 14 000–11 300 plot shows a high degree of clustering of the drillhole 120R data close to the library spectra of calcite, dolomite, Fe-dolomite, ankerite, kutnohorite, rhodochrosite, Fe-rhodochrosite and siderite. The interpreted compositions of the carbonate spectral populations strongly correlate with the chemical populations of 144 analysed carbonates and provide a highly resolved spatial framework for interpreting carbonate alteration.     

变分同化框架通过背景误差协方差构建动力平衡约束的研究进展

通过背景误差协方差构建动力平衡约束是变分同化框架设计的重要环节。它不仅帮助实现变量间的协同分析,提高观测使用效率,还能改善变分极小化问题的性状。本文在系统梳理通过背景误差协方差引入动力平衡约束的方式、流程的基础上,对求解目前全球和有限区域变分同化系统普遍采用的准地转平衡和静力平衡约束的共性问题和存在的不足作了归纳总结。分析了求解准地转平衡约束的三类方案:动力平衡方程方案、统计方案和动力-统计相结合方案的优缺点。对照比较了不同垂直离散方案下求解静力平衡约束时遇到的欠定问题的表现以及解决途径。最后,展望了基于背景误差协方差构建动力平衡约束在赤道等特殊地区、高分辨率同化系统、以及集合-变分混合同化系统发展中面临的挑战和机遇。     

Landsat 8热红外数据定标参数的变化及其对地表温度反演的影响

Landsat系列卫星上的TIRS热红外传感器数据已被大量应用,针对TIRS数据的地表温度反演也相继开发出一些算法,并有一些研究对TIRS数据的定标及其地表温度反演算法的精度进行了对比。本文主要就TIRS热红外传感器定标参数的变化,结合这些定标参数变化的时间点对有关地表温度反演算法的适用性和有效性进行分析,特别是对劈窗算法是否适合当前的TIRS数据进行了讨论,以使用户能够对Landsat 8 TIRS热红外数据的正确使用有进一步的认识。总的看来,由于视域外杂散光的影响,TIRS数据的定标精度仍达不到设计目标,TIRS第11波段的不确定性仍成倍大于TIRS 10波段。因此,在Landsat团队未彻底解决这一问题之前,同时用TIRS第10、第11这两个差距较大的波段构成的劈窗算法来反演地表温度,其精度存在较大的不确定性,US6-S团队仍在致力于改进第11波段的精度,改进后的波段可以用劈窗策法。目前应以TIRS第10单波段的方式来反演地表温度为宜。