岩石圈中水的临界奇异性——大规模成矿的根源

水的临界奇异性是岩石圈中许多重大地质作用的关键和枢纽,有独特的地质意义、超乎常识。水在临界点发生二级相变,许多物理化学性质奇异性突变,特别是溶解行为和热压的突变,对成矿作用影响极大。     

一次江淮气旋复杂降水相态特征及成因分析

本文应用常规探空资料、地面观测资料、欧洲中心细网格(0.25°×0.25°)数值预报初始场资料和NCEP/NCAR 1°×1°再分析资料分析了山东一次江淮气旋降雪过程的复杂相态特征,并初步分析了成因。结论如下:(1)山东省2014年2月16—17日的雨雪天气过程,降水相态多样性和相态转化复杂性是主要特点,表现为同一时刻雨、雪和雨夹雪三种相态共存,郯城站降水相态逆转(由雨夹雪转雨再转雪),鲁东南地区降雪同时鲁西南地区降雨的"东雪西雨"现象。(2)在系统发展不强的江淮气旋降雪过程中,鲁中山区相对高海拔地区夜间强烈的辐射降温和山脉迎风坡的动力抬升作用均会造成边界层温度的降低,后期对流层低层为东北风控制时,除鲁中山区外,其迎风坡东麓或东北麓(潍坊地区)出现固态降水可能性也较大,一般情况下,地面2 m温度为1~2℃,1 000 hPa温度为0℃左右,925 hPa温度为-3℃左右,可出现固液共存降水现象。(3)相态逆转现象的发生与江淮气旋发展阶段和气温日变化两个因素紧密相关。0℃层在925 hPa上下的状态是一种临界状态,可产生雨夹雪或雨,但0℃层高度下降不是由雨转雪的充分条件,还需考察冷平流发展情况。(4)当江淮气旋生成地偏东(位于长江口附近),且发展不强烈时,山东若受其影响产生降水,后期上游如有新系统发展,可能与气旋共同影响山东,造成复杂相态的江淮气旋降雪过程。     

喜马拉雅碰撞造山带不同类型部分熔融作用的时限及其构造动力学意义

喜马拉雅新生代淡色花岗岩,是世界上S型花岗岩的典例,主要分布于两条近平行排列的东西向构造带内,特提斯喜马拉雅带和高喜马拉雅带。实验岩石学和理论研究表明:这些淡色花岗岩是中—下地壳岩石进行不同性质的地壳深熔作用的产物,部分熔融类型与构造变形密切耦合。具体表现在:146~35 Ma,在增厚地壳条件下,以角闪岩部分熔融作用为主,形成了具有高Sr/Y比值的二云母花岗岩;228~9 Ma,减压条件下,俯冲物质快速折返,白云母发生脱水部分熔融,形成具有较高Rb/Sr比值的花岗岩;3其中,在21~16 Ma期间,与藏南裂谷系E—W向伸展作用开启密切相关,变泥质岩发生水致白云母部分熔融作用,形成Rb/Sr比值较低,Sr和Ba含量较高的花岗岩;4在25~27 Ma期间,局部地区发生高压水致部分熔融作用。     

Landscape pattern and transition under natural and anthropogenic disturbance in an arid region of northwestern China

There is a pressing need to determine the relationships between driving variables and landscape transformations. Human activities shape landscapes and turn them into complex assemblages of highly diverse structures. Other factors, including climate and topography, also play significant roles in landscape transitions, and identifying the interactions among the variables is critical to environmental management. This study analyzed the configurations and spatial-temporal processes of landscape changes from 1998 to 2011 under different anthropogenic disturbances, identified the main variables that determine the landscape patterns and transitions, and quantified the relationships between pairs of driver sets. Landsat images of Baicheng and Tekes from 1998, 2006 and 2011 were used to classify landscapes by supervised classification. Redundancy analysis (RDA) and variation partitioning were performed to identify the main driving forces and to quantify the unique, shared, and total explained variation of the sets of variables. The results indicate that the proportions of otherwise identical landscapes in Baicheng and Tekes were very different. The area of the grassland in Tekes was much larger than that of the cropland; however, the differences between the grassland and cropland in Baicheng were not as pronounced. Much of the grassland in Tekes was located in an area that was near residents, whereas most of the grassland in Baicheng was far from residents. The slope, elevation, annual precipitation, annual temperature, and distance to the nearest resident were strong driving forces influencing the patterns and transitions of the landscapes. The results of the variation partitioning indicated complex interrelationships among all of the pairs of driver sets. All of the variable sets had significant explanatory roles, most of which had both unique and shared variations with the others. The results of this study can assist policy makers and planners in implementing sustainable landscape management and effective protection strategies.     

中国北方三流域河流—沙漠过渡带地表沉积物化学元素空间差异分析

通过对克里雅河、毛布拉格孔兑以及西拉木伦河三流域的河流-沙漠过渡带地表沉积物的7种常量氧化物以及15种微量元素进行因子分析,结果显示:三个流域之间或不同河段因子分析提取的公因子均可以概括为较稳定的铁锰矿物、较不稳定的长石类和方解石（白云石）类等硅酸盐矿物以及稳定的稀土元素和重矿物等类别;河流间因子分析结果表明,自西向东三个流域沿河地表沉积物的化学元素富集与迁移程度呈递增趋势,化学风化程度增强;流域内因子分析结果表明,自上游至下游,样点化学组成均愈变复杂,不同河段或不同河岸沉积物化学元素空间分布规律与其物源、地貌格局以及水分条件等因素有关;自河床至阶地,不同地貌单元地表沉积物化学元素呈相异的递变规律,这与在距离河道远近不同,物源、动力因素的分配不同有关。     

高压下天然菱铁矿的压缩性和电子结构研究

采用同步辐射光源和金刚石对顶砧(DAC)技术,对天然菱铁矿的压缩性和电子结构进行了原位X射线衍射(XRD)和X射线吸收近边结构谱(XANES)测试研究。在室温下随着压力逐渐升高至50.2 GPa,菱铁矿保持方解石型结构不变,但是逐渐向Na Cl型结构转变;刚性[CO3]2-基团平行于ab-平面定向排列使c轴的压缩性大于a轴。菱铁矿在44.6~47.1 GPa之间发生电子由高自旋态(HS)向低自旋态(LS)的转变,表现为体积塌陷8%。HS菱铁矿的等温状态方程参数为K0=112(5)GPa和K'0=4.6(3)。首次采用XANES技术对菱铁矿中Fe2+的电子结构进行了研究,结果表明:随着压力升高至37.3 GPa,Fe2+的配位和局域对称并未发生明显变化;此后电子结构开始转变,Fe2+的3d轨道分裂能降低,电子跃迁概率增大,呈现LS特性。     

Evolution of Siderian juvenile crust to Rhyacian high Ba-Sr magmatism in the Mineiro Belt,southern São Francisco Craton

Plutonic rocks from the Mineiro Belt, Brazil record a delayed onset of the transition from TTG to sanukitoid-type magmatism(high Ba-Sr), starting during the Siderian magmatic lull when little juvenile magma was added to the continental crust. Rocks mostly belong to the calc-alkaline series, meta-to peraluminous and originally "Ⅰ-type",meaning that oxidized magmas were formed by partial melting of subducted material. The temporal distribution and apparent secular changes of the magmas are consistent with the onset of subduction-driven plate tectonics due to an increase of the subduction angle and opening of the mantle wedge. New isotopic analyses(Sm-Nd whole rock and Lu-Hf in zircon)corroborate the restricted juvenile nature of the Mineiro Belt and confirm the genetic link between the Lagoa Dourada Suite,a rare ca. 2350 Ma high-Al tonalite-trondhjemite magmatic event, and the sanukitoid-type ca. 2130 Ma Alto Maranhao Suite. U-Pb dating of zircon and titanite constrain the crystallisation history of plutonic bodies; coupled with major and trace element analyses of the host rocks, they distinguish evolutionary trends in the Mineiro Belt. Several plutons in the region have ages close to 2130 Ma but are distinguished by the lower concentration of compatible elements in the juvenile high Ba-Sr suite.     

Dynamic land use change simulation using cellular automata with spatially nonstationary transition rules

The dynamic relationships between land use change and its driving forces vary spatially and can be identified by geographically weighted regression (GWR). We present a novel cellular automata (GWR-CA) model that incorporates GWR-derived spatially varying relationships to simulate land use change. Our GWR-CA model is characterized by spatially nonstationary transition rules that fully address local interactions in land use change. More importantly, each driving factor in our GWR model contains effects that both promote and resist land use change. We applied GWR-CA to simulate rapid land use change in Suzhou City on the Yangtze River Delta from 2000 to 2015. The GWR coefficients were visualized to highlight their spatial patterns and local variation, which are closely associated with their effects on land use change. The transition rules indicate low land conversion potential in the city’s center and outer suburbs, but higher land conversion potential in the inner near suburbs along the belt expressway. Residual statistics show that GWR fits the input data better than logistic regression (LR). Compared with an LR-based CA model, GWR-CA improves overall accuracy by 4.1% and captures 5.5% more urban growth, suggesting that GWR-CA may be superior in modeling land use change. Our results demonstrate that the GWR-CA model is effective in capturing spatially varying land transition rules to produce more realistic results, and is suitable for simulating land use change and urban expansion in rapidly urbanizing regions.     

山西长治盆地中更新世气候转型期环境变化特征

中更新世气候转型(MPT)是第四纪环境变化的一个重要时期,该时期气候模式、气候周期等均发生了明显变化,然而不同区域对中更新世气候转型的响应特征存在明显差异.本研究选取了长治盆地XZK4钻孔中更新世转型前后(1.8～0.1 Ma)共207个样品,通过古地磁定年,运用粒度端元分析和孢粉分析,阐述了长治盆地中更新世转型期的环境变化与湖泊演化特征.结果显示,1.8 Ma以来,孢粉组合中乔木花粉含量多高于60％,但个别时段草本植物花粉占优,显示区域植被多数阶段为森林,但存在明显冷期,并且1.1 Ma和0.55 Ma是研究区环境转变的重要转折点.中更新世转型期前(～1.1 Ma):沉积物粒度总体较细,黏土含量多高于25％,EM1组分(湖相沉积)多高于60％,EM3(河流相组分)在个别时段出现,总体显示该阶段沉积物组成以湖相沉积为主,个别阶段受到河流影响大;中更新世转型时期(1.1～0.55 Ma):沉积物粒度较上一阶段更细,黏土含量(平均为30％)、EM1占比和孢粉浓度均达到研究段最高,沉积物颜色以棕灰色为主,EM3组分占比降至最低,其中1.1～0.95 Ma喜冷的云杉属花粉出现,显示该时期研究区气候总体偏冷湿,湖泊面积较1.1 Ma之前扩大;中更新世转型后(～0.55 Ma):沉积物粒度明显变粗,达到钻孔最高值,沉积物颜色变黄,EM2(风成组分)和EM3占主导,草本植物含量增加,尤其是喜干的蒿属花粉增加明显,表明气候较之前变干,沉积物类型以风力沉积为主,湖泊消亡.综合对比显示,构造运动是影响长治古湖消长的主要驱动力,气候变干加剧了湖泊消亡.     

模型揭示的浅水湖泊稳态转换影响因素分析

富营养化会导致浅水湖泊发生稳态转换,生态系统服务严重受损。磷是驱动湖泊发生稳态转换的重要环境因子,探究湖水磷浓度的变化规律是湖泊管理的关键。通过磷动力学模型,从影响湖水磷浓度的主要参数入手,探讨了每种参数变化对磷浓度的具体影响。结合前人研究结果,详细讨论了不同类型气候变化和人类活动对湖泊稳态转换时间、滞后时长、修复速率等的影响。研究认为,气候变化所导致的温度升高、光强减弱、风浪增强等和人类活动所导致的生物扰动、水位波动增强等因素变化虽不会改变湖泊稳态转换突变时间,但会推迟湖泊修复时间,造成突变阈值减小,滞后时间延长,稳态增大。在湖泊保护中要重点考虑主要外力驱动对湖泊稳态转换过程影响的区别,避免有害突变的发生。