江西省兴源冲铜矿床同位素地球化学特征及成矿机制探讨

兴源冲铜矿床地处九岭南缘铜多金属大型矿集区西段的黄茅地区。文章在成矿地质特征的基础上,通过对矿石进行稳定同位素地球化学研究,重点分析了成矿物质来源,探讨了矿床成矿机制。碳、氧同位素分析结果表明,矿区碳酸盐岩δ13CVPDB为-5·4‰～1·9‰,平均为0·6‰,δ18OSMOW变化范围为9·0‰～13·9‰,平均为10·9‰,主要为海相碳酸盐岩,碳、氧同位素图解表明碳可能主要来源于深部,且受高温变质作用和低温蚀变作用明显;矿石硫化物硫同位素δ34S变化范围主要在1·0‰～6·2‰之间,个别样品同位素比值偏大,对比相似矿床,表明该矿床具有海底喷流沉积和后期岩浆热液叠加作用的特征。上述同位素地球化学特征表明,兴源冲铜矿床是在中元古代海底火山沉积基础上,经新元古代晋宁造山期岩浆热液、动力变质叠加成矿作用所形成。     

硬岩钻进用石油钻头研究现状及发展趋势

能源与矿产的持续安全供给是经济快速增长的保证,而中硬岩层钻进一直限制着油气钻井向深部发展。针对硬岩地层钻进,地质行业主要采用金刚石钻头钻进,而油气钻井行业除按传统方法采用牙轮钻头和金刚石钻头钻进之外,也逐渐开展了PDC钻头钻进硬岩的研究。本文分别介绍了牙轮钻头、金刚石钻头和PDC钻头在油气勘探硬岩钻进中的应用研究现状。其中,牙轮钻头研究主要集中在增强轴承密封性能、改进布齿结构和提高切削齿强度三个方面,而金刚石钻头研究则集中在碎岩机理、金刚石参数和胎体性能,以及钻头结构三个方面。提出了三类钻头的研究方向和发展趋势,为硬岩钻探技术发展提供参考。     

Precambrian fossils from the Hamersley range,Western Australia,and their use in stratigraphic correlation

The palaeontology, correlation and sedimentation of the Proterozoic sequence in the Hamersley Range, Western Australia, are discussed. Fossil calcareous algal growths, such as stromatolites and onkolites are described, as well as possible medusoid impressions. These indicate shallow water accumulation of the sediments and provide evidence of the extensive existence of plant and animal life in the Late Precambrian of Western Australia.

Distinctive stromatolites are shown to characterize various levels in the Proterozoic succession. A descending sequence of stromatolite assemblages is proposed denoted by:

• Collenia frequens—Conophyton cf. inclinatum

• Collenia australasica—C. undosa

• C. cf. kona—C. brockmani

• C. sp. aff. multiflabella.

Emphasis is placed on the possible significance of these calcareous algae for correlation and age subdivision of the Proterozoic of Western Australia and its relation to other Precambrian successions.     

北京市表层土壤中PAHs含量特征及来源分析

土壤,作为城市中最重要的环境介质,承担了较高多环芳烃(PAHs)的环境负荷,开展土壤PAHs分布特征及来源分析研究,可以为污染风险防控、环保政策制定提供支撑.为研究北京市不同功能区土壤环境中PAHs的含量、组成及来源,本文在北京市主城区进行了大范围采样,同时针对工业区、农业种植区、水源保护区及居民区等不同功能区进行了分...     

安徽省庐枞盆地高岭土矿的成矿规律、找矿方向及开发应用问题探讨

庐枞盆地是以中、下侏罗统陆相碎屑岩建造为基底,经燕山运动而发育起来的陆相继承性火山岩盆地,是长江中下游地区重要的矿产地之一。盆地北部高岭土矿化普遍且强烈,具有很好的找矿远景。本文初步探讨了庐枞盆地高岭土成矿规律、矿床成因及找矿方向,提出了下一步开发利用的建议。     

基于污染足迹模型的湖州市农业污染评估

太湖流域的水环境质量呈现严重恶化趋势,农业污染物的排放是太湖流域水体环境恶化的主要原因之一。农业污染物主要来源于种植业、畜禽养殖业和水产养殖业的生产过程,不同于以往分开论述三者对水环境的影响,本文基于全国第一次污染普查数据,运用污染足迹模型定量分析了湖州市农业面源(种植业、畜禽养殖业和水产养殖业)对水环境的影响。研究结果表明:(1)农业生产产生的污染物对水环境的影响排序为:磷>氮>有机物;(2)各农业生产类型对水环境的影响排序为:水产养殖业>种植业>畜禽养殖业;(3)湖州市各区县对水环境的影响也存在着明显的空间差异。通过对湖州市农业污染足迹评估,可以明确地提出哪种污染物类型、农业生产类型和区域是湖州市农业面源污染治理的重点。研究结果可以为太湖流域农业的可持续发展和水资源的可持续利用提供一定的参考价值。     

Monitoring of toxic substances in the Hong Kong marine environment

A long-term programme for monitoring toxic substances in the marine environment was established in Hong Kong in 2004, focusing on chemicals of potential ecological and health concern. The programme ran on 3-year cycles, with the first two years monitoring marine water, sediment, biota, and the third year monitoring pollution sources. Twenty-four priority chemicals were measured, including dioxins/furans, dioxin-like PCBs, total PCBs, PAHs, DDTs, HCHs, TBTs, phenol, nonylphenol (NP), NP ethoxylates, PBDEs and metals. Results from the first three years of monitoring indicate that toxic substances in the Hong Kong marine environment were within the range reported for the coastal waters in China and other regions, but generally lower than in the Pearl River Estuary. The levels met the standards for protecting aquatic life and human consumption. Sewage effluent, stormwater and river water were possible sources of phenolic compounds; whereas air deposition or regional pollution, rather than local discharges, may contribute to the dioxins/furans, PAHs and PCBs found in the marine environment.     

Identification and quantification of mixed sources of oil spills based on distributions and isotope profiles of long-chain n-alkanes

Combined with quantitative determination of concentration and isotopic composition of petroleum hydrocarbons, weathering simulation experiments on artificially mixed oils and their two end-member oils are performed for identification and quantification of mixed sources. The >C₁₈n-alkanes show no appreciable losses during a short-term weathering process. An approach based on distribution of long-chain n-alkanes (>C₁₈) is suggested for estimating the contribution proportion of each source in mixed oils. Stable carbon isotope profile of individual n-alkanes is a powerful tool to differentiate sources of oil spills, but unavailable to accurately allocate each contribution due to a relatively large analytical error.     

Thermal equation of state of magnesite to 32 GPa and 2073 K

Pressure–volume–temperature relations have been measured to 32 GPa and 2073 K for natural magnesite (Mg_0.975Fe_0.015Mn_0.006Ca_0.004CO₃) using synchrotron X-ray diffraction with a multianvil apparatus at the SPring-8 facility. A least-squares fit of the room-temperature compression data to a third-order Birch–Murnaghan equation of state (EOS) yielded K₀ = 97.1 ± 0.5 GPa and K′ = 5.44 ± 0.07, with fixed V₀ = 279.55 ± 0.02 Å³. Further analysis of the high-temperature compression data yielded the temperature derivative of the bulk modulus (∂K_T/∂T)_P = −0.013 ± 0.001 GPa/K and zero-pressure thermal expansion α = a₀ + a₁T with a₀ = 4.03 (7) × 10⁻⁵ K⁻¹ and a₁ = 0.49 (10) × 10⁻⁸ K⁻². The Anderson–Grüneisen parameter is estimated to be δ_T = 3.3. The analysis of axial compressibility and thermal expansivity indicates that the c-axis is over three times more compressible (K_Tc = 47 ± 1 GPa) than the a-axis (K_Tc = 157 ± 1 GPa), whereas the thermal expansion of the c-axis (a₀ = 6.8 (2) × 10⁻⁵ K⁻¹ and a₁ = 2.2 (4) × 10⁻⁸ K⁻²) is greater than that of the a-axis (a₀ = 2.7 (4) × 10⁻⁵ K⁻¹ and a₁ = −0.2 (2) × 10⁻⁸ K⁻²). The present thermal EOS enables us to accurately calculate the density of magnesite to the deep mantle conditions. Decarbonation of a subducting oceanic crust containing 2 wt.% magnesite would result in a 0.6% density reduction at 30 GPa and 1273 K. Using the new EOS parameters we performed thermodynamic calculations for magnesite decarbonation reactions at pressures to 20 GPa. We also estimated stability of magnesite-bearing assemblages in the lower mantle.     

Curie point depth from spectral analysis of aeromagnetic data from Cerro Prieto geothermal area,Baja California,México

Using aeromagnetic data acquired in the area from the Cerro Prieto geothermal field, we estimated the depth to the Curie point isotherm, interpreted as the base of the magnetic sources, following statistical spectral-based techniques. According to our results the Curie point isotherm is located at a depths ranging from 14 to 17 km. Our result is somewhat deeper than that obtained previously based only in 2-D and 3-D forward modeling of previous low-quality data. However, our results are supported by independent information comprising geothermal gradients, seismicity distribution in the crust, and gravity determined crustal thickness. Our results imply a high thermal gradient (ranging between 33 and 38 °C/km) and high heat flow (of about 100 mW/m²) for the study area. The thermal regime for the area is inferred to be similar to that from the Salton trough.