冀北隆化小罗卜沟金银矿床特征及找矿意义

冀北隆化县小罗卜沟中型金银矿床的发现是该地区找矿的重大突破。勘查区位于1∶20万和1∶5万Au、Ag等多元素综合异常内,通过以钻探、硐探为主的探矿工程,基本查明了矿体赋存于早白垩世九佛堂组复成分角砾岩和义县组安山岩及安山质火山角砾岩的构造裂隙内。矿体受断裂带控制,与围岩界线明显,对围岩没有选择性,矿床属燕山期与岩体有关的浅成中低温热液矿床。矿区内共圈定17个矿体,矿体长28～788 m,斜深8～489 m,平均厚度0.80～3.96 m,Ag平均品位68.44×10~(-6)～447.50×10~(-6),共生Au平均品位1.16×10~(-6)～6.25×10~(-6);伴生Au平均品位0.20×10~(-6)～1.00×10~(-6),伴生S平均品位2.34%～11.10%。主要矿体Ⅳ-1银资源储量达中型。矿区内及外围仍存在寻找多金属矿床的潜力。该矿床的发现对寻找同类矿床具有重要指示意义。     

Long-term performance evaluation of zero-valent iron amended permeable reactive barriers for groundwater remediation – A mechanistic approach

Permeable reactive barriers (PRBs) are used for groundwater remediation at contaminated sites worldwide. This technology has been efficient at appropriate sites for treating organic and inorganic contaminants using zero-valent iron (ZVI) as a reductant and as a reactive material. Continued development of the technology over the years suggests that a robust understanding of PRB performance and the mechanisms involved is still lacking. Conflicting information in the scientific literature downplays the critical role of ZVI corrosion in the remediation of various organic and inorganic pollutants. Additionally, there is a lack of information on how different mechanisms act in tandem to affect ZVI-groundwater systems through time. In this review paper, we describe the underlying mechanisms of PRB performance and remove isolated misconceptions. We discuss the primary mechanisms of ZVI transformation and aging in PRBs and the role of iron corrosion products. We review numerous sites to reinforce our understanding of the interactions between groundwater contaminants and ZVI and the authigenic minerals that form within PRBs. Our findings show that ZVI corrosion products and mineral precipitates play critical roles in the long-term performance of PRBs by influencing the reactivity of ZVI. Pore occlusion by mineral precipitates occurs at the influent side of PRBs and is enhanced by dissolved oxygen and groundwater rich in dissolved solids and high alkalinity, which negatively impacts hydraulic conductivity, allowing contaminants to potentially bypass the treatment zone. Further development of site characterization tools and models is needed to support effective PRB designs for groundwater remediation.     

豫西Au- Mo- W- Pb- Zn- Ag- Fe- 铝土矿-石墨成矿带主要地质成矿特征及潜力分析

随着地质大调查的开展,豫西地区新的找矿进展和预测成果不断涌现,使之成为我国重点找矿地区之一,需要对其开展系统的成矿区划和部署研究工作。本文以新的研究成果和找矿突破为基础,通过综合分析,在该地区划分新的重要成矿部署区带,厘定边界并将其命名为"豫西Au-Mo-W-Pb-Zn-Ag-Fe-铝土矿-石墨成矿带"。结合区域成矿地质背景的综合研究,在区内划分了10个成矿亚带,初步建立了Au-Mo-W-Pb-Zn-Ag-Fe-铝土矿-石墨成矿带成矿谱系,其成矿作用具有多期次发育和多系统控制的特点,在时间演化上表现为多旋回性、继承性、新生性和叠加性特点,主要成矿期有前寒武纪、寒武纪-早石炭世、晚石炭世-中三叠世和晚三叠世-早白垩世,其中晚侏罗世-早白垩世是内生金属矿床成矿大爆发期。研究区主要成矿类型为岩浆热液型金银铅锌矿、斑岩型-矽卡岩型钼钨矿、层控热液型和海相火山岩型铅锌矿、古风化壳残积型铝土矿、沉积-变质型铁铜石墨矿和伟晶岩型稀有金属矿等。结合区域找矿进展和潜力评价最新成果,认为本区金、钼钨、铅锌银、铝土矿、铁、石墨、煤矿潜力巨大,为下一步勘查部署的主攻矿种,同时在本区划分了25个远景区,其中14个为重点远景区,11个为一般远景区,对研究区下一步矿产勘查部署工作有一定指导意义。     

内蒙古突泉盆地ZK-WJT钻井下侏罗统红旗组 生烃潜力

对突泉盆地西南缘ZK-WJT井红旗组烃源岩的发育特征和有机质丰度、类型及成熟度的研究表明,下侏罗统红旗组暗色泥岩发育,厚度达113.0m.有机碳的含量分布在0.56％～6.24％之间,平均值为1.90％.应用Pr/n-C17与Ph/n-C18的相关关系及C27、C28、C29甾烷(ααα-20R)三者的相对含量,判断其有机质类型为Ⅱ1型.镜质组反射率R.主要分布于1.26％～1.73％之间,平均值为1.37％;岩石热解参数Tmax主要为489.0～517.0℃,平均值为507.6℃,红旗组烃源岩属于成熟—高成熟演化阶段.综合评价认为,突泉盆地下侏罗统红旗组具备较好的生油气潜力.     

Global Correlations of Ocean Ridge Basalt Chemistry with Axial Depth: a New Perspective

The petrological parameters Na₈ and Fe₈, which are Na₂O andFeO contents in mid-ocean ridge basalt (MORB) melts correctedfor fractionation effects to MgO = 8 wt%, have been widely usedas indicators of the extent and pressure of mantle melting beneathocean ridges. We find that these parameters are unreliable.Fe₈ is used to compute the mantle solidus depth (P_o) and temperature(T_o), and it is the values and range of Fe₈ that have led tothe notion that mantle potential temperature variation of T_P= 250 K is required to explain the global ocean ridge systematics.This interpreted T_P = 250 K range applies to ocean ridges awayfrom ‘hotspots’. We find no convincing evidencethat calculated values for P_o, T_o, and T_P using Fe₈ have anysignificance. We correct for fractionation effect to Mg^# = 0·72,which reveals mostly signals of mantle processes because meltswith Mg^# = 0·72 are in equilibrium with mantle olivineof Fo_89·6 (vs evolved olivine of Fo_{88·1–79·6}in equilibrium with melts of Fe₈). To reveal first-order MORBchemical systematics as a function of ridge axial depth, weaverage out possible effects of spreading rate variation, local-scalemantle source heterogeneity, melting region geometry variation,and dynamic topography on regional and segment scales by usingactual sample depths, regardless of geographical location, withineach of 22 ridge depth intervals of 250 m on a global scale.These depth-interval averages give Fe₇₂ = 7·5–8·5,which would give T_P = 41 K (vs 250 K based on Fe₈) beneathglobal ocean ridges. The lack of Fe₇₂–Si₇₂ and Si₇₂–ridgedepth correlations provides no evidence that MORB melts preservepressure signatures as a function of ridge axial depth. We thusfind no convincing evidence for T_P > 50 K beneath globalocean ridges. The averages have also revealed significantcorrelations of MORB chemistry (e.g. Ti₇₂, Al₇₂, Fe₇₂,Mg₇₂, Ca₇₂, Na₇₂ and Ca₇₂/Al₇₂) with ridge axial depth. Thechemistry–depth correlation points to an intrinsic linkbetween the two. That is, the 5 km global ridge axial reliefand MORB chemistry both result from a common cause: subsolidusmantle compositional variation (vs T_P), which determines themineralogy, lithology and density variations that (1) isostaticallycompensate the 5 km ocean ridge relief and (2) determine thefirst-order MORB compositional variation on a global scale.A progressively more enriched (or less depleted) fertileperidotite source (i.e. high Al₂O₃ and Na₂O, and low CaO/Al₂O₃)beneath deep ridges ensures a greater amount of modal garnet(high Al₂O₃) and higher jadeite/diopside ratios in clinopyroxene(high Na₂O and Al₂O₃, and lower CaO), making a denser mantle,and thus deeper ridges. The dense fertile mantle beneath deepridges retards the rate and restricts the amplitude of the upwelling,reduces the rate and extent of decompression melting, givesway to conductive cooling to a deep level, forces melting tostop at such a deep level, leads to a short melting column,and thus produces less melt and probably a thin magmatic crustrelative to the less dense (more refractory) fertile mantlebeneath shallow ridges. Compositions of primitive MORB meltsresult from the combination of two different, but geneticallyrelated processes: (1) mantle source inheritance and (2) meltingprocess enhancement. The subsolidus mantle compositional variationneeded to explain MORB chemistry and ridge axial depth variationrequires a deep isostatic compensation depth, probably in thetransition zone. Therefore, although ocean ridges are of shalloworigin, their working is largely controlled by deep processesas well as the effect of plate spreading rate variation at shallowlevels. KEY WORDS: mid-ocean ridges; mantle melting; magma differentiation; petrogenesis; MORB chemistry variation; ridge depth variation; global correlations; mantle compositional variation; mantle source density variation; mantle potential temperature variation; isostatic compensation     

柴达木盆地北缘中侏罗统大煤沟组七段烃源岩有机地球化学特征及生烃潜力

柴达木盆地北缘地区在中侏罗世晚期,即大煤沟组七段(J2d7)时演化至最大湖侵期,发育了一套湖相泥页岩。通过对区内鱼卡煤矿井下样品的实测分析,结合先前报道的研究成果,确认了这套湖相泥页岩为优质烃源岩,藻类体、角质体和孢子体是这套源岩的主要生烃显微组分,有机质类型最好可达II1型。热演化研究表明,该套源岩在不同构造单元处于差异热演化阶段,既可生油亦可生气。虽然J2d7段烃源岩在平面上不同凹陷区具有一定的非均质性,但其生烃潜力,特别是在赛什腾—鱼卡凹陷地区,完全可与我国西北地区其它侏罗系优质烃源岩相媲美。长期以来,下侏罗统烃源岩被认为是柴北缘地区的主要油气源,J2d7段优质烃源岩的确认,对于深化柴北缘地区的油气勘探和地质研究具有重要意义。     

碳酸盐岩与泥质烃源岩生气规律对比研究

配制了两套成熟度相近的碳酸盐岩和泥质岩丰度系列样品。采用半封闭外加温加压式热压模拟装置对碳酸盐岩的生烃情况进行了热模拟实验，研究了碳酸盐岩生气量随成熟度和温度变化的趋势，探讨了碳酸盐岩生气的变化规律。碳酸盐岩与泥质岩的生烃潜力是有机质质量和有机质丰度的函数，与岩性无关；碳酸盐岩的产气规律与泥质岩相似，而且两者产烃的量级也相当，并不存在碳酸盐岩生排烃效率高的现象；碳酸盐岩和泥质岩总有机碳(TOC)含量在热模拟过程中基本上不发生变化；不同岩性的有机质的产烃效率主要受温度和有机质类型决定。     

储层流动单元研究在油田老区挖潜中的应用——以吉林油田乾146区块开发为例

吉林油田乾146区块经多年开采,已经进入高含水、高采出阶段。通过储层流动单元研究,运用多参数模糊聚类方法将该区高台子油层由好至差划分为A、B、C、D、E 5类储层流动单元。查明了区内主要目的层系各含油小层的储层流动单元发育特征:40、39小层主要发育A、B类优质储层流动单元,42、41、38小层则以C、D、E类储层流动单元为主,各小层储层流动单元类型及展布与初始产能吻合度较高,表明储层流动单元类型的差异是控制本区油气分布的重要因素之一。综合油藏地质特征及油田开发动态数据,对各储层流动单元的注采渗流体系进行了深入剖析,归纳总结出乾146区块高台子油层XII砂组中剩余油分布的5条规律,据此在剩余油分布预测区部署了1口扩边井和2口老区加密井,投产后分别获得了11.2t/d、5.5t/d和8.6t/d的初始产能。     

剪切波速判别地震液化势的适用性研究

本文阐述了剪切波速判别地震液化势的可行性, 对目前国内外各种剪切波速判别地震液化势的方法进行了分析对比, 指出公式(6)是一实用、可靠的判别方法。     

精确制备不同含水率岩石试样的化学热力学方法

在岩石力学试验研究中,常常需要精确制备不同含水率的岩石试验样品,而目前的方法尚难以保证所需的精度。为此,提出一种精确制备不同含水率岩石试样的方法,其基本原理是将欲制备的岩石试件烘干或饱水后放置于恒湿环境中,烘干样或饱和样会逐步吸湿或去湿而增加或减小重量,其含水率逐步增加或减小,直至稳定,最终得到稳定、均匀、含水率各异的试验样品,而其中的关键是如何获得一个稳定的恒湿环境。基于化学热力学中单组分的气-液平衡理论,提出了一种稳定恒湿环境的获取方法,其基本原理为：由于岩石中组分水的化学势与恒湿环境中的水气的组分水的化学势在起始阶段不相等,因此,二者中的水气压力也不同,必然有组分水的迁移;当岩石中的水气压力大于恒湿环境中的水气压力时,水便从岩石中迁移至恒湿环境中,使岩石失水,而当岩石中的水气压力小于恒湿环境中的水气压力时,水自恒湿环境中迁移至岩石中,使其含水率增加,直至二者中的水气压力平衡,即可得到某一特定含水率的岩石样品。这样制备的岩石样品满足化学热力学平衡的要求,其含水率内外一致,上下相同,是含水率均匀分布的合格样品。该方法还能制备其他方法无法实现的含水率相差甚微的岩石试件,也可直接应用于精确制备不同含水率的土样。