川滇黔桂76种元素地球化学图编制中分析方法与分析质量研究(一) 不同实验室产生地球化学图的相似性——以Ag、Cs、Ga、Ge为例

编制中国76种元素地球化学图将使我们首次了解元素周期表上除氢、氧及惰性气体之外所有元素在中国大陆表层的分布,川滇黔桂76种元素地球化学图的编制是这一研究项目的试点。本文以不同实验室取得的Ag、Cs、Ga、Ge分析数据为例,探索、衡量不同实验室地球化学图相似性的方法,以优选实验室进行川滇黔桂4省区约4000件组合样76种元素的大规模分析工作。     

Fitness-for-Purpose of Reference Material Reference Values in Relation to Traceability of Measurement, as Illustrated by USGS BCR-1, NIST SRM 610 and IAEA NBS28

As in all fields of sample analysis, reference materials play a large role in supporting measurements in the geosciences. While a rather large number of materials are in distribution (> 380), not all are equally effective or fit-for-purpose in supporting laboratory data quality and thereby assuring the desired comparability of measurements between laboratories. Equally important, reference values that are not fit-for-purpose cannot be used effectively to establish traceability links between laboratory measurements and national and international standards. The needed fitness-for-purpose is not achieved for reference values either when more than one reference value has been proposed and a consensus does not exist among users as to which should be used by all, or when reference value uncertainties are too large in comparison to those of routine laboratory measurements. The focus of this review will be, first to outline the current reality, and second to suggest ways in which certifications of RMs can be improved to provide reference values that are universally accepted and more fit-for-purpose in general laboratory use. The discussion will be illustrated largely by current uses of USGS BCR-1, NIST SRM 610 and IAEA NBS28, as these three materials are those for which the largest body of newly published data exists, according to recent bibliographies of the geoanalytical literature published annually in Geostandards Newsletter: The Journal of Geostandards and Geoanalysis.     

Gold Mineralization and Occurrence of Sinter in the Hoshino Area, Fukuoka Prefecture, Japan

Abstract. Several epithermal gold deposits occur in the Hoshino area, which is located in the western end of the late Cenozoic Hohi volcanic zone, north‐central Kyushu, Japan. The area is characterized by intermediate to felsic extrusive rocks of Pliocene age. In the Hoshino area, the shallow manifestation of the hydrothermal activity is exposed on the surface. Several outcrops of sinter are still preserved on the top of hydro thermally altered volcanic rocks, and high‐grade gold‐bearing quartz veins occur on the surface at lower levels. The hydrothermal alteration resulted into well‐developed alteration zones. The zonal alteration pattern, primarily of near‐neutral pH type, is characterized by the outer smectite zone of a lower temperature, and the inner mixed layer minerals zone of a higher temperature. Quartz vein‐related or fracture‐controlled alteration, is represented by the occurrence of interstratified illite/smectite and K‐feldspar, suggesting a potassium‐enriched alteration. The mineralization in the Hoshino area is recognized on the surface by the occurrence of gold‐bearing quartz veins distributed mainly in the mixed layer minerals zone. The fracture system related to the gold mineralization is mainly characterized by NW‐SE trend. The alteration pattern and the mineralogical composition of the veins suggest that the mineralizing fluids had near‐neutral pH and the mineralization is of low‐sulfidation‐type. Fluid inclusion data and textures observed in quartz veins indicate that gold precipitated during boiling. The chemical composition of quartz veins shows that high‐grade gold‐bearing quartz veins are characterized by higher content of Al₂O₃, K₂O and Rb. Several outcrops of silica‐sinters are distributed on the top of the mixed layer minerals zone. Although their structures are not very well preserved, because of later silicification, the Hoshino sinters still show characteristic textures identical to those observed in modern sinters, such as the presence of plant fossil incorporated into the sinters, the strongly developed depositional laminations and the columnar structures perpendicular to the depositional surfaces. Quartz is the only silica mineral constituting the Hoshino sinters presently. The conversion of amorphous silica into quartz was probably governed by higher temperatures resulting from later hydrothermal activity. This later hydrothermal activity is reflected by the intense silicification affecting mainly the lower parts of the sinters and also by the presence of quartz veins cutting the sinters. The distribution of sinters in the Hoshino area is very significant. The presence beneath the sinters of concealed high‐grade gold‐bearing quartz veins should be highly considered and exploration work is strongly suggested.     

Determining gaseous composition of fluid inclusions with quadrupole mass spectrometer

Quadrupole mass spectrometer (QMS) is an instrument for effectively determining gaseous composition of fluid inclusion. The gaseous component is extracted from inclusions with thermal decrepitation method and then determined with the sensitive QMS instrument. The method is characterized by high sensitivity and high accuracy with the relative standard deviation (RSD,n=6) of less than 3%. It has been successfully used for analyzing fluid inclusions. The analytical results meet the requirement of geological study.     

长江巨洪前期物理因子的配置

提出了长江巨洪前期物理因子配置的概念，在每一次巨洪发生之前，影响巨洪的主要物理因子之间一般都会表现出相似的特征，即出现一些固有的配置，这些配置正是长江发生巨洪的强信号，对长江巨洪的预测研究具有重要的指示作用。     

A high-resolution diatom reconstruction between 21,000 and 17,4000 14C yr BP from the southern Bolivian Altiplano (18–23°S)

A diatom study of lacustrine sediments in the southern part of the Bolivian Altiplano (Salar of Coipasa) provides a continuous record of the period 21,000–17,500 ¹⁴C yr BP. Constrained by seven AMS ¹⁴C dates, this record provides evidence that the Coipasa basin was filled by a shallow body of water during this time. Diatom/salinity and diatom/ionic composition transfer functions indicate that the lake was saline, dominated by sodium-chloride throughout all the period.A comparison with regional data shows that Lake Titicaca could not have overflowed towards the southern Bolivian Altiplano at that time. As this dry phase was not registered in Lake Coipasa, this lake was probably supplied by winter precipitation originating from the Pacific. But, recent data from the deep basin of Lake Titicaca show that the lake-level was higher during this time interval, and the question arises whether precipitation from Atlantic and Amazonia sources could have played an important role on the Altiplano during the Last Glacial Maximum (LGM). This hypothesis needs to match other available paleoclimatic data from the lowlands of tropical South America, where there is evidence that during the LGM, conditions were drier than today. Global climate simulations suggest a positive P-E on the Altiplano, due to a strong cooling, reducing evaporative demand more than any increase in precipitations. An increase of winter precipitation from the Pacific is in agreement with data from the Chilean coast showing a northward locations of the Westerlies during the LGM. This paleoclimatic hypothesis is also in agreement with a coupled ocean-atmosphere model, which indicates weaker summer precipitation and stronger winter precipitation in the tropical areas.     

火焰原子吸收法测定化探样品中的银铜铅锌

样品经硝酸、氢氟酸、高氯酸分解，制成硝酸溶液，经巯基棉层析柱过滤富集Ag，并用2mol／LHBr溶液洗脱，用火焰原子吸收法测定洗脱液中的Ag和滤液中的Cu，Pb，Zn。用该法测定化探样品中银和铜铅锌，检出限低，结果准确度和精密度均令人满意。     

某地平板玻璃原料用石英砂的提纯研究

某地石英矿砂通过磁选分离法、稀酸浸泡法处理后，矿砂不同程度地降低了铁、铝、钙镁的含量；采用磁选分离 稀酸浸泡法联合处理后，使该地石英砂的化学成分达到了优质的生产平板玻璃用硅质原料的国家标准。     

大港油田盐山-庆云地区油气运移富集规律的研究

盐山-庆云地区具多凸多凹、地质条件复杂、多向供油（气）的特点。油气化探异常发育不平衡，具有成带分布、局部富集的特征。西部主要的轻烃（CH4）异常强，东部则是重烃（C2H6、C3H8）异常最发育，由西向东轻烃逐渐下降，重烃不断增加，非烃指标（Hg、△C）异常与重烃异常基本相拟，Ks、Fe^2 异常规律不明显。根据烃类指标的分带性，轻、重烃异常规律和富集特征划分为气显示带，油显示带和油气显示带。中部地区的即油气显示带是油气最有远景的地段。