Disequilibrium for Ca during growth of pelitic garnet

Compositional zoning in hundreds of almandine-rich garnets in amphibolite by facies micaceous quartzites from the Picuris Range, north-central New Mexico USA, indicates that although Mn, Mg and Fe achieve chemical equilibrium at hand-sample scale during garnet growth, Ca does not. Instead, Ca concentrations at the surface of growing garnets appear to depend strongly on kinetic factors that govern the local chemical environment, yielding disequilibrium for Ca at scales larger than the region immediately surrounding an individual porphyroblast. Detailed zoning profiles were obtained for 371 garnet crystals in a small volume of a single sample of garnetiferous quartzite, and core analyses were made of 97 additional crystals. Each analysis was made on a section that passed precisely through the morphological centre of the crystal, located by means of 3-D imagery from computed X-ray tomography. The data reveal strong correlations between crystal size and concentrations of Mn, Mg and Fe (but not Ca) in garnet cores; a relationship between crystal size and isolation; rigorous cross-correlations among concentrations of Mn, Mg and Fe (but not Ca); and systematic variations in Ca concentrations as a function of crystal size and core composition that are anomalous in comparison to the behaviour of the other divalent cations. We interpret these observations as the result of thermally accelerated diffusion-controlled garnet growth, in circumstances that promoted rapid intergranular diffusion and thus rock-wide equilibration of Mn, Mg and Fe, but that prevented equilibration at similar scale for Ca because of its more sluggish intergranular diffusion. The anomalous behaviour of Ca is made evident in these garnets by the presence of sharp spikes in Ca concentration, which are demonstrably not a consequence of any simultaneous rock-wide event, such as a change in pressure, temperature, or some other intensive parameter. Instead, Ca concentrations probably reflect the local extent of reaction in the immediate vicinity of each porphyroblast. To the degree that such kinetic factors introduce departures from chemical equilibrium for Ca, thermobarometric estimates that involve grossular contents of pelitic garnet will be in error.     

黄骅坳陷横向变换带的构造特征及成因

讨论了黄骅坳陷横向变换带的构造特征和成因。根据利用地震反射剖面对盆地构造几何学的研究，圈定了不同尺度的横向变换带，确定了伸展构造背景下的横向变换带是为了保持区域伸展应变调节构造变形的一种调节体系。这种伸展应变守恒是靠三维空间上断层位移沿走向的变化实现的。横向变换带的构造样式为横向地垒状凸起和鼻状凸起或鼻状背斜，并具伸展性质的正断层。横向凸起与非叠复的和叠复的分段断层系伴生及发育在断层位移最小处等事实表明，横向凸起或横向鼻状背斜是由于分段断层系位移沿走向变化形成的。     

Predisposition to Induced Seismicity in Some Czech Coal Mines

—Mining-induced seismicity associated with longwall face operations in the Ostrava- Karviná coal mines, Czech Republic, has been investigated in order to establish the conditions leading to a focal zone generation. The study, based on macroseismic and instrumental observations, proved that seismicity is influenced by natural as well as mining conditions. The first group includes the influence of faults, washouts and red beds, while the second one is represented by shaft and/or crosscut safety pillars and various types of remnant pillars. All the cases discussed show that many focal zones are generated in overstressed strata as a consequence of interaction of natural conditions and/or old workings with the active coal face. Received June 18, 1996, accepted March 10, 1997     

The possible connection between ionization in the atmosphere by cosmic rays and low level clouds

Recent analysis of monthly mean cloud data from the International Satellite Cloud Climatology Project uncovered a strong correlation between low cloud and the cosmic ray flux for extensive regions of the Earth. Additional data have been recently released covering the period up to September 2001 with which we have made a new study of the geographical variation of the correlation between low cloud and predicted ionization level from cosmic rays at an altitude of 2 km. When analysed globally, we find that the correlations do not correspond to the latitude variation of cosmic ray flux and they are not field significant. Nonetheless they appear to be marginally field significant over broad latitude and longitude bands with a peak positive correlation at 50 degrees North and South and a tendency to negative correlation at lower latitudes. The correlation is strongest over the North and South Atlantic. Several of these features are consistent with the predictions of the electroscavenging process.We use a simple model to calculate the climatic impact should the correlation be confirmed. We show that, under the most favorable conditions, a reduction in low cloud cover since the late 19th century, combined with the direct forcing by solar irradiance can explain a significant part of the global warming over the past century, but not all. However, this computation assumes that there is no feedback or changes in cloud at other levels.     

The Origin and Evolution of Silica-saturated Alkalic Suites: an Experimental Study

Experimental simulation of incremental crystal fractionationof a hy-normative hawaiite indicates that the spectrum of compositionsfrom mildly alkalic hawaiite to sodic rhyolite found in silica-saturatedalkalic suites of the ocean islands and continental hotspotsand rifts can be produced by fractionation at 9·3 kbarwith bulk water contents >     

Mantle Xenoliths from the Southeastern Slave Craton: Evidence for Chemical Zonation in a Thick, Cold Lithosphere

We present the first data on the petrology of the mantle lithosphereof the Southeastern (SE) Slave craton, Canada. These are basedon petrographic, mineralogical and geochemical studies of mantlexenoliths in Pipe 5034 of the Cambrian Gahcho Kué kimberlitecluster. Major types of mantle xenoliths include altered eclogite,coarse garnet or spinel peridotite, and deformed garnet peridotite.The peridotites belong to the low-temperature suite and formedat T=600–1300°C and P= 25–80 kbar in a thick(at least 220–250 km), cool lithosphere. The SE Slavemantle is cooler than the mantle of other Archaean cratons andthat below other terranes of the Slave craton. The thick lithosphereand the relatively cool thermal regime provide favourable conditionsfor formation and preservation of diamonds beneath the SE Slaveterrane. Similar to average Archaean mantle worldwide, the SESlave peridotite is depleted in magmaphile major elements andcontains olivine with forsterite content of 91–93·5.With respect to olivine composition and mode, all terranes ofthe Slave mantle show broadly similar compositions and are relativelyorthopyroxene-poor compared with those of the Kaapvaal and Siberiancratons. The SE Slave spinel peridotite is poorer in Al, Caand Fe, and richer in Mg than deeper garnet peridotite. Thegreater chemical depletion of the shallow upper mantle is typicalof all terranes of the Slave craton and may be common for thesubcontinental lithospheric peridotitic mantle in general. Peridotiticxenoliths of the SE Slave craton were impregnated by kimberliticfluids that caused late-stage recrystallization of primary clinopyroxene,spinel, olivine and spinel-facies orthopyroxene, and formationof interstitial clinopyroxene. This kimberlite-related recrystallizationdepleted primary pyroxenes and spinel in Al. The kimberliticfluid was oxidizing, Ti-, Fe- and K-rich, and Na-poor, and introducedserpentine, chlorite, phlogopite and spinel into peridotitesat P < 35 kbar. KEY WORDS: kimberlite xenolith; lithosphere; mantle terrane; chemical zoning; thermobarometry; Slave craton     

A Sequence of Pan-African and Hercynian Events Recorded in Zircons from an Orthogneiss from the Hercynian Belt of Western Central Iberia--an Ion Microprobe U-Pb Study

Sensitive high-resolution ion microprobe U–Pb dating showsthat a biotite orthogneiss from the Hercynian belt of westerncentral Iberia contains 1000–300 Ma zircon. Older, 1000–570Ma ages within this range represent inherited, detrital materialamong which four age components may be recognized: