Urban Atmospheric Chemistry During the PUMA Campaign 2: Radical Budgets for OH,HO<Subscript>2</Subscript> and RO<Subscript>2</Subscript>

A detailed photochemical box model was used to investigate the key reaction pathways between OH, HO₂ and RO₂ radicals during the summer and winter PUMA field campaigns in the urban city-centre of Birmingham in the UK. The model employed the most recent version of the Master Chemical Mechanism and was constrained to 15-minute average measurements of long-lived species determined in situ at the site. The results showed that in the summer, OH initiation was dominated by the reactions of ozone with alkenes, nitrous acid (HONO) photolysis and the reaction of excited oxygen atoms atoms with water. In the winter, ozone+alkene reactions were the primary initiation route, with a minor contribution from HONO photolysis. Photolysis of aldehydes was the main initiation route for HO₂, in both summer and winter. RO₂ initiation was dominated by the photolysis of aldehydes in the summer with a smaller contribution from ozone+alkenes, a situation that was reversed in the winter. At night, ozone+alkene reactions were the main radical source. Termination, under all conditions, primarily involved reactions with NO (OH) and NO₂ (OH and RCO₃). These results demonstrate the importance of ozone+alkene reactions in urban atmospheres, particularly when photolysis reactions were less important during winter and at nighttime. The implications for urban atmospheric chemistry are discussed.     

Constraints on the photon charge from observations of extragalactic sources

Having analyzed high-resolution observations of extragalactic compact radio sources with modern systems of radio telescopes, we obtained an estimate of the upper limit for the photon electric charge, e_γ ? 3×10^?33 of the elementary charge (assuming the photon charge to be energy independent). This is three orders of magnitude better than the limit obtained from radio pulsar timing. We also set a limit on the charge of a gamma-ray (energy ～0.1 MeV) photon. In the future, the estimate based on extragalactic sources can be improved significantly.     

Relativistic beaming in the central components of double radio quasars

Using a large sample of 78 well-observed double quasars, we have investigated several consequences of the relativistic beaming model. In this model the ratio of the strengths of the central component and outer lobes of a double source depends on whether the jet axis lies close to or away from the line of sight, If this is the actual situation, the fraction of emission from the core,f _c, may be used as a statistical measure of the orientation of the source and should be correlated with other source parameters which also depend on the inclination of the jet axis to the line of sight. We findf _c to be anticorrelated with the overall projected linear size of the extended emission but to exhibit a positive correlation with both the observed degree of misalignment from a collinear double structure, and the ratio of separations of the outer hotspots from the central component. As might be expected from these relationships, we also find sources of smaller projected linear sizes to appear more misaligned and the degree of misalignment to be correlated with the ratio of separations of the outer hotspots. All these correlations are consistent with the predictions of the relativistic beaming model.     

NO<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript> change over China and its influences

A 3-D chemical transport model (OSLO CTM2) is used to investigate the impact of the increase of NOx emission over China. The model is capable to reproduce basically the seasonal variation of surface NOx and ozone over eastern China. NOx emission data and observations reveal that NOx over eastern China increases quite quickly with the economic development of China. Model results indicate that NOx concentration over eastern China increasingly rises with the increase of NOx emission over China, and accelerates to increase in winter. When the NOx emission increases from 1995 to its double, the ratio of NO2/NOx abruptly drops in winter over northern China. Ozone at the surface decreases in winter with the continual enhancement of the NOx level over eastern China, but increases over southern China in summertime. It is noticeable that peak ozone over northern China increases in summer although mean ozone changes little. In summer, ozone increases in the free troposphere dominantly below 500 hPa.Moreover, the increases of total ozone over eastern China are proportional to the increases of NOx emission.In a word, the model results suggest that the relationship between NOx and ozone at the surface would change with NOx increase.     

水脉泽寄主星系的倾角分析

迄今已经在104个河外星系中检测到水脉泽辐射.同其它没有检测到水脉泽的星系相比,水脉泽星系可能隐含着某种或某些特殊性质.收集了到当前为止(截止2008.09)发表的所有水脉泽星系以及相关的观测资料.计算得到了这些源的星系盘的倾角,并分析讨论了这些水脉泽源星系盘和脉泽盘的倾角可能存在的相关.统计发现只有大约10%的盘脉泽源的星系盘侧面对着我们的视线.然而VLBI对6个盘脉泽源高空间分辨率的成图观测显示那些旋转脉泽盘都是近似侧向的,脉泽盘的倾角都大于80°.对大多数水盘脉泽星系而言,他们的星系盘和脉泽盘方向不一致,这可能间接支持盘脉泽仅仅同星系核相关.为了探讨遮蔽物质的由来和水脉泽辐射的放大机制,对整个水脉泽样本的脉泽光度,X射线吸收气体柱密度和寄主星系倾角的可能相关进行了分析.结果显示高密度的遮蔽物质主要来自于星系核区,而水脉泽辐射的放大更可能发生在围绕核的尘埃盘(～100Pc)或更小尺度的核盘上.     

Dehydration experiments on natural omphacites: qualitative and quantitative characterization by various spectroscopic methods

A series of natural omphacites from a wide range of P, T occurrences were investigated by electron microprobe (EMP), infrared (IR)-, Mössbauer (MS)- and optical spectroscopy in the UV/VIS spectral range (UV/VIS), secondary ion mass spectrometry (SIMS) and single crystal structure refinement by X-ray diffraction (XRD) to study the influence of hydrogen loss on valence state and site occupancies of iron. In accordance with literature data we found Fe²⁺ at M1 as well as at M2, and in a first approach assigned Fe³⁺ to M1, as indicated by MS and XRD results. Hydrogen content of three of our omphacite samples were measured by SIMS. In combination with IR spectroscopy we determined an absorption coefficient: ε _i,tot = 65,000 ± 3,000 lmol_H2O ^?1 cm^?2. Using this new ε _i,tot value, we obtained water concentrations ranging from 60 to 700 ppm H₂O (by weight). Hydrogen loss was simulated by stepwise heating the most water rich samples in air up to 800°C. After heat treatment the samples were analyzed again by IR, MS, UV/VIS, and XRD. Depending on the type of the OH defect, the grade of dehydration with increasing temperature is significantly different. In samples relatively poor in Fe³⁺ (<0.1 Fe³⁺ pfu), hydrogen associated with vacancies at M2 (OH bands around 3,450 cm^?1) starts to leave the structure at about 550°C and is completely gone at 780°C. Hydrogen associated with Al³⁺ at the tetrahedral site (OH bands around 3,525 cm^?1, Koch-Müller et al., Am Mineral, 89:921–931, 2004) remains completely unaffected by heat treatment up to 700°C. But all hydrogen vanished at about 775°C. However, this is different for a more Fe³⁺-rich sample (0.2 Fe³⁺ pfu). Its IR spectrum is characterized by a very intense OH band at 3,515 cm^?1 plus shoulder at 3,450 cm^?1. We assign this intense high-energy band to vibrations of an OH dipole associated with Fe³⁺ at M1 and a vacancy either at M1 or M2. OH release during heating is positively correlated with decrease in Fe²⁺ and combined with increase in Fe³⁺. That dehydration is correlated with oxidation of Fe²⁺ is indirectly confirmed by annealing of one sample in a gas mixing furnace at 700°C under reducing conditions keeping almost constant OH^? content and giving no indication of Fe²⁺-oxidation. Obtained data indicate that in samples with a relatively high concentration of Fe²⁺ at M2 and low-water concentrations, i.e., at a ratio of Fe^{2+ M2}/H > 10 dehydration occurs by iron oxidation of Fe²⁺ exclusively at the M2 site following the reaction: \( {\left[ {{\text{Fe}}^{{{\text{2 + [ M2]}}}}{\text{OH}}^{ - } } \right]} = {\left[ {{\text{Fe}}^{{{\text{3 + [ M2]}}}} {\text{O}}^{{{\text{2}} - }} } \right]} + {\text{1/2}}\;{\text{H}}_{{\text{2}}} \uparrow . \) In samples having relatively low concentration of Fe²⁺ at M2 but high-water concentrations, i.e., ratio of Fe^{2+ M2}/H < 5.0 dehydration occurs through oxidation of Fe²⁺ at M1.     

ON2中部区域OH1667MHz脉泽的新观测

利用法国巴黎默东天文台的南锡射电望远镜对ＯＮ２ 中部区域ＯＨ１６６７ ＭＨｚ 脉泽首次进行观测．观测结果表明中部区域的ＯＨ１６６７ ＭＨｚ 脉泽的辐射频谱为典型的双峰结构．这说明ＯＮ２ 中部区域的ＯＨ１６６７ ＭＨｚ 脉泽是位于绕中央星运动的薄盘上．结合模型对中部区域的ＯＨ１６６７ ＭＨｚ 脉泽谱线频谱图进行分析和研究     

Primary Product Distributions from the Reaction of OH with m-, p-Xylene, 1,2,4- and 1,3,5-Trimethylbenzene

A study was conducted to examine the OH-initiated degradation products of the four title compounds in the presence of sub-part-per-million levels of NO_x. The oxidation was conducted in a dynamic reactor to minimize the conversion of the aromatic compounds. The experiments were designed to represent reaction pathways that occur in the atmosphere at ambient NO₂ concentrations. A wide range of ring-retaining and ring-cleavage products having widely varying yields were measured during the study. For m-xylene, the major primary products observed (with molar yields) were methyl glyoxal (0.40), 4-oxo-2-pentenal (0.12), glyoxal (0.079), and m-tolualdehyde (0.049). For p-xylene, the major primary products were p-tolualdehyde (0.103), 2,5-dimethylphenol (0.13), cis-3-hexene-2,5-dione (0.176), trans-3-hexene-2,5-dione (0.045), 2-methyl-butenedial (0.071), glyoxal (0.394), and methylglyoxal (0.217). Several other reaction products were measured at yields less than 3%. The primary products for OH + 1,2,4-trimethylbenzene were found as follows: methylglyoxal (0.44), glyoxal (0.066), cis-3-hexene-2,5-dione (0.13), trans-3-hexene-2,5-dione (0.031), biacetyl (0.114), 3-methyl-3-hexene-2,5-dione (0.079), and 2-methyl-butenedial (0.045). Six other (ring retaining) products were measured at yields less than 3%. The primary products for OH + 1,3,5-trimethylbenzene were methylglyoxal (0.90), 3-methyl-5-methylidene-5(2H)-furanone (0.1), 3,5-dimethyl-3(2H)-2-furanone (0.1), 3,5-dimethyl-5(2H)-2-furanone biacetyl (0.08), and 2-methyl-4-oxo-2- pentenal (0.05). Three other products were detected at molar yields less than 5%. In some cases, the yields for the ring fragmentation products could only be based on calibrations from surrogate compounds. Yields for several of the unsaturated dicarbonyl compounds have not been reported previously while yields for methylglyoxal, glyoxal, and biacetyl are largely consistent with previous reports. Some of the primary furanone products are the identical to those reported as secondary products in aromatic systems.     

Extragalactic research in Europe and the United States in the early 20th century

While the theoretical foundations of modern relativistic cosmology were laid, to a large extent, by European researchers like Einstein, de Sitter, Friedmann, Lemaître, and others, observational cosmology was (and to a large extent, still is) dominated by US astronomers, working at Lick and Mt. Wilson observatories. From today's viewpoint, Hubble appears to dwarf all his – national and international – peers. However, Keeler and Curtis, Fath and Slipher carried put pioneering work in the US, as did Wolf, Wirtz, Lundmark, de Sitter in Europe, both by observation and by statistical analysis of data. European extragalactic research during the early 20th century is outlined and compared with studies in the United States. Reasons for the small impact of European research are a mixture of deliberate and accidental neglect and suppression, as well as the lack of technical and organizational infrastructure, which was especially noticeable after World War I.     

Atmospheric gravity waves identified by ground-based observations of the intensity and rotational temperature of OH airglow

Spectroscopic observations of OH airglow undertaken on May 2, 2006 at Uji, Japan reveal variations in intensity and rotational temperature related to the passage of an atmospheric gravity wave. The variations exhibit a period of approximately 1 h and magnitudes of 2–6% in intensity and 0.5–2% in rotational temperature. The vertical wavelength and intrinsic frequency of the atmospheric gravity wave were determined from the horizontal wavelength derived by an OH airglow imager, the background horizontal wind velocity obtained by the middle and upper atmosphere (MU) radar, and the dispersion relationship. The observed variations are consistent with the values calculated using the model of Liu, A.Z., Swenson, G.R. [2003. A modeling study of O₂ and OH airglow perturbations induced by atmospheric gravity waves. J. Geophys. Res. 108 (No. D4), 4151. doi:10.1029/2002JD002474].