北黄海表层沉积物常量元素分布特征及其控制因素分析

为探讨北黄海表层沉积物中常量元素分布特征,并进一步分析其控制因素和物质来源,以常量元素为依托,对304个站位表层沉积物常量元素含量分布特征及控制因素进行统计分析,结果表明:沉积物中SiO2、Al2O3、Fe2O3、MgO、K2O、P2O5、TiO2七种元素含量的空间分布具有明显的区域性。其中,SiO2、K2O具有相似的空间分布;Al2O3、Fe2O3、MgO、P2O5、TiO2具有相似的空间分布,但与SiO2、K2O的分布趋势相反;CaO、MnO、Na2O在区域内分布较为均匀,未显示出明显的高低变化趋势。聚类分析显示,表层沉积物的常量元素分布主要受粒度效应的控制。主因子分析提取出3种控制常量元素分布的主成分,分析表明,粒度控制效应、源区风化作用和不同物源输入是影响表层沉积物常量元素空间分布的主要因素,贡献累计方差总和达77.12%。以K2O、CaO、TiO2为指标,通过FD函数识别出北黄海不同海域内的主要物质来源,其主要物源包括黄河、鸭绿江和黄海暖流携带的长江物质。对北黄海沉积物物质来源进行分析,不仅在海洋矿产资源勘探、航道开发、沿岸港口建设与整治等方面具有实际意义,而且在认识海洋环境变迁等方面同样具有理论意义。     

珠江口磨刀门水道盐度变化对水文气象要素的频率响应特征

以2010年11月-2011年3月磨刀门水道挂定角、联石湾、竹排沙、平岗和竹银5个测站的盐度、马口水文站流量、三灶站潮位和竹银站的主流向风速为基本数据,应用偏相干谱估计方法分析了各测站盐度变化对潮汐、流量和风的频率响应。经验诊断分析结果表明:1)马口站入海径流存在准1日、半日、1/4日和1/3日等显著的潮致振荡周期;2)各测站盐度变化与潮汐主要振荡周期并不一致,沿磨刀门水道向上游,潮汐对盐度变化的影响递减,竹银站盐度可作为潮汐直接作用下咸潮上溯的平均上限位置;3)消除潮汐和径流的影响后风对盐度变化的作用明显加强;4)各测站盐度变化对潮汐、流量与风的响应过程存在时间超前或滞后但无特定规律,说明磨刀门水道盐度变化过程十分复杂。     

Hydrochemistry of the natural low pH groundwater in the coastal aquifers near Beihai,China

Natural weak acidic groundwater occurs in the unconfined and confined aquifers consisting of Quaternary and Neogene unconsolidated sediments near Beihai in southern Guangxi, China. Under natural conditions the groundwater has low TDS(less than 200 mg L-1) and low concentrations of trace elements(less than 100 μg L-1) with a deceasing tend in contents of the Lanthanides(rare earth elements, less than 1 μg L-1) towards higher atomic number. The groundwater ranges in p H from 3.33 to 7.0 with an average value of 5.12(even lower than that of local rainwater, 5.88). p H values in the groundwater are a bit higher in rainy seasons than those in dry seasons and do not show significant increasing or decreasing trend with time. The average p H value in groundwater in the confined aquifers is even a bit lower than that in the unconfined aquifer. Comprehensive analyses of the groundwater environment suggest that H+ in the groundwater may be derived from dissociation of H2CO3, release of the absorbed H3O+ in clay layers and the acidity of rainwater. The H2CO3 in the groundwater may be formed by dissolution of CO2(g). Minerals in the unconsolidated sediment are predominated by quartz with small amount of clay minerals. The sediments undergoing a long-term weathering contain low levels of soluble constitutes. Lack of alkaline substances in the groundwater system is also helpful in the accumulation of acidity of the groundwater.     

A model of sand transport in Treporti channel: northern Venice lagoon

The origin of the sands in the Venice lagoon has been the subject of an extensive field survey in parallel with numerical modelling. Four transects along Treporti and Burano canals were conducted from which 33 bottom sediment samples were collected. These samples were analysed for grain size and sorting to examine any trends in the granulometry of these sediments that might shed light on transport paths. The modelling study consists of three parts: the sediment transport model sedtrans96 was used with a finite-element hydrodynamic model (Shyfem) and an empirical wave model (US Army Corps of Engineering) to simulate sand transport in the Treporti canal. A type of link box model was created where finite elements of the hydrodynamic model have been combined to macro-boxes on which the water and sediment flux over the sections, and a mass balance has been computed. Several grain size classes were simulated; the distributions before and after the simulation were examined. Idealised wind and tidal values were initially used to force 12 h simulations to test the sediment transport sensitivity. Finally, a full-year simulation (1987) has been carried out using measured tidal and wind data. Only a part of Venice lagoon was covered by the simulation: a major channel (Treporti) running from Lido inlet towards the northern lagoon. The total sand transport through all of the sections was computed for 1 year. Sediment mass balance was determined, and the resulting trends of erosion and deposition were computed. There were no trends in the median grain diameter and sorting of bottom samples from the Treporti canal; all sands were fine (120 μm, one outlier of 300 μm was removed). The absence of a trend in grain size suggests that there is no significant import of sand to the lagoon through the Lido inlet. The results from the simulations seem therefore to confirm the hypothesis of reworking of sand within the lagoon. The computed erosion is some centimeters per year diagnostic of channel scouring and enlargement with time. The Treporti canal is subject to strong current velocities of around 1 m/s, which hold fine sand in suspension and thus prevent sedimentation.     

基于统计分析方法的地理要素显示重要性确定研究

运用统计分析的理论与方法,研究地理要素显示重要性的确定,制作基础地理要素显示重要性问卷调查表,对不同区域、不同用户进行调查统计,运用统计分析中的调查统计法对数据的权重值进行计算分析,总结地理要素显示重要性的分级体系,并在多尺度电子地图制作中得到应用。     

基于大倾角的角锥体空间后方交会研究

在摄影测量中,当倾角变大时,由于三角函数的多值性和奇异性导致传统的共线条件方程线性化的空间后方交会方法已经不能稳定地求解出摄影瞬间影像的外方位元素。文中通过对传统空间后方交会、基于单位四元素的空间后方交会和文中所用到的基于简化的DLT线性方程求解线元素初值的角锥体法比较发现,在像片倾角逐渐变大,传统方法和四元素法不能正确求解出外方位元素的情况下,基于角锥体法的空间后方交会仍能稳定、准确地求解出像片的外方位元素。     

新疆荒漠地区C4植物的生态分布与区系分析

以前人工作为基础,对照已发表的C3/C4植物一览表,及近年国内外陆续发表的资料,综合整理出新疆荒漠地区已知的C4植物名录,共有14科63属的279种植物,同时归纳分析了279种C4。植物的分类地位、生活型、地理成分以及区系特点等方面。研究结果表明：藜科最多,其次是禾本科、莎草科、百合科和蓼科等等。所以该区的C4类型中被...     

ICP-OES法同时测定进口铜精矿中有害元素

本文优化了进口铜精矿的样品处理技术,通过对影响铜精矿消解的因素和仪器参数进行分析建立了同时测定铜精矿中有害元素的精确方法,回收率在91.7%-96%,并与FAS测试结果进行了比较。     

Geochemical evidences of dry climate in the Mid-Holocene in Gonghe Basin, northeastern Qinghai-Tibetan Plateau

Previous research on climatic change in the Mid-Holocene in China indicates that it was a warm and humid period, accompanied by stronger summer monsoons, and it is defined as the Megathermal in the Holocene, or the Holocene Optimum period. However, this conclusion is mainly directed at the monsoonal region in eastern China. In this research, we chose the Gonghe Basin in the northeastern Qinghai-Tibetan Plateau as the study area. Geochemical analysis of the profiles of paleosols and aeolian sand in the Santala area in the middle of the Gonghe Basin, along with OSL (optically stimulated luminescence) dating, indicates that the regional climate has experienced several warm-humid and cold-dry cycles since 11.8 ka. In particular, the Mid-Holocene (8.1–4.6 ka) was relatively cold and dry as evidenced by drastic fluctuations in chemical weathering degree and humidity, a higher aridity index, and sparse vegetation, accompanying increased winter monsoonal strength. In order to clarify whether this is an individual or local signal, we compared our geochemical analysis results with lake and peat records and aeolian deposits of the monsoonal boundary region. The results indicate that the climate deteriorated widely, with declines in temperature and moisture, in the Mid-Holocene in the modern monsoonal boundary zone. Furthermore, the duration of climate deterioration (relatively dry period) generally decreased from west to east in the aforementioned regions. Therefore, this dry phase in Gonghe Basin may be representative of dry events in Mid-Holocene in northern China. In addition, we discuss the reasons for this dry climate from several perspectives: (1) it probably can be attributed to a decline in summer monsoonal strength; (2) the regional evaporation loss (forced by high temperature) was not compensated by regional precipitation; (3) the thermal dynamic effect of the Qinghai-Tibetan Plateau.     

Prediction of satellite orbits contraction due to diurnally varying oblate atmosphere and altitude-dependent scale height using KS canonical elements

A new non-singular analytical theory for the motion of near-Earth satellite orbits with the air drag effect is developed in terms of uniformly regular KS canonical elements. Diurnally varying oblate atmosphere is considered with variation in density scale height dependent on altitude. The series expansion method is utilized to generate the analytical solutions and terms up to fourth-order terms in eccentricity and c (a small parameter dependent on the flattening of the atmosphere) are retained. Only two of the nine equations are solved analytically to compute the state vector and change in energy at the end of each revolution, due to symmetry in the equations of motion. The important drag perturbed orbital parameters: semi-major axis and eccentricity are obtained up to 500 revolutions, with the present analytical theory and by numerical integration over a wide range of perigee height, eccentricity and inclination. The differences between the two are found to be very less. A comparison between the theories generated with terms up to third- and fourth-order terms in c and e shows an improvement in the computation of the orbital parameters semi-major axis and eccentricity, up to 9%. The theory can be effectively used for the re-entry of the near-Earth objects, which mainly decay due to atmospheric drag.