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141.
黑海西北部冷泉碳酸盐岩的沉积岩石学特征及氧化还原条件的稀土元素地球化学示踪 总被引:2,自引:1,他引:2
黑海西北部罗马尼亚大陆架(水深120m)和乌克兰陆坡(水深190m)发育冷泉碳酸盐岩结壳。XRD测试表明此结壳主要由高镁方解石和文石组成。结壳中与渗漏系统微生物活动有关的凝块和葡萄状文石等特殊的沉积组构非常发育。冷泉碳酸盐岩酸可溶部分(碳酸盐岩相矿物)的稀土元素含量很低(0.068×10-6~2.817×10-6),稀土元素页岩标准化配分模式显示罗马尼亚大陆架冷泉碳酸盐岩具有明显的Ce负异常,乌克兰陆坡冷泉碳酸盐岩具Ce的正异常,表明它们是分别在氧化和还原环境中沉积的。稀土元素和V、Cd和U等微量元素的含量在泥晶中最高,亮晶中最低,可能反映成岩过程对元素含量有控制作用。 相似文献
142.
143.
G. Diego Gatta Tiziana Boffa Ballaran Gianluca Iezzi 《Physics and Chemistry of Minerals》2005,32(2):132-139
The high-pressure behaviour of a synthetic P21/c ferrian magnesian spodumene, M2 (Li0.85Mg0.09Fe2+ 0.06)M1(Fe3+ 0.85Mg0.15)Si2O6, has been investigated using in situ single-crystal X-ray diffraction and Raman spectroscopy. No phase transition has been observed within the pressure range investigated. The isothermal equation of state up to 7 GPa was determined. V0, KT0 and K, simultaneously refined with a Murnaghan equation of state, are: V0= 415.66(7) Å3, KT0=83(1) GPa and K=9.6(6). The magnitudes of the principal unit-strain coefficients were calculated and their ratios 1:2:3=1.00:1.85:2.81 at P=6.83 GPa indicate a very strong anisotropy. Monitoring of the intensity of b-type reflections (h+k= 2n+1) confirms that from room conditions up to 7 GPa the primitive lattice is maintained. Raman spectra have been collected up to 7.4 GPa. No change in the number of observed vibrational modes occurs in the pressure range investigated. At high frequency, the Raman doublet relative to the Si–O–Si vibrations of the two distinct tetrahedral chains is a broad band at room pressure, however, the frequency difference between the two modes increases with increasing pressure.Operating system: Windows NT 相似文献
144.
我国几个矿区叶蜡石X射线粉晶衍射研究 总被引:4,自引:0,他引:4
对我国几个主要类型叶蜡石矿的叶蜡石做了X射线粉晶衍射研究。从大量实验结果发现,所研究叶蜡石存在单斜晶系和三斜晶系两种多型。单斜晶系(2M);空间群G_(2h)~6-C2/c,a=5.175A,b=8.902A,c=18.673A,β=100.1°,Z=4;三斜晶系(1Tc):空间群P_c,a=5.162A,b=8.965A,c=9.346A,a=91.2°,β=99.96°,γ=89.91°,Z=2。 相似文献
145.
Colin R. Ward John C. Taylor C. E. Matulis L. S. Dale 《International Journal of Coal Geology》2001,46(2-4)
The mineral matter in the eight reference North American coal samples of the Argonne Premium Coal series has been investigated on a quantitative basis using X-ray diffraction (XRD) techniques. X-ray diffraction data obtained from electronic low-temperature (oxygen–plasma) ash (LTA) residues, from ashes produced by heating the coals in air at 370°C, and also from the raw coals themselves, were evaluated using an interactive data processing system (
™) based on Rietveld interpretation methods. The results from the three types of material (LTA, 370°C ash and raw coal) were compared for each sample. This allowed the components present in the raw coals in crystalline form to be recognised separately from mineral artifacts produced, particularly in the low-rank coals, from interaction of organically associated elements (Ca, S, etc.) during the two ashing processes.After the allowance for the production of any artifacts, the quantitative mineral assemblages identified from XRD of the raw coals were found to be consistent, even for coals having a relatively low ash percentage (around 5%), with the results obtained from the respective mineral concentrates prepared by the ashing methods. The effects of heating the coal to 370°C could also be distinguished, relative to the raw coal or the LTA, through changes in components such as pyrite and the clay minerals.Although some areas of uncertainty exist, particularly with magnesium in the low-rank coals, the calculated chemical compositions of the coal ash derived from the mineral mixtures identified for each coal were also found to be consistent with the results of direct chemical analysis of the respective coal ash materials. 相似文献
146.
S. C. Tarantino M. Zema F. Maglia M. C. Domeneghetti M. A. Carpenter 《Physics and Chemistry of Minerals》2005,32(8-9):568-577
A suite of (Mn1-x
Fe
x
)Nb2O6 (x=0, 0.05, 0.25, 0.50, 0.75, 1) columbite samples has been prepared by solid-state reaction from oxides. X-ray diffraction
and spectroscopic investigations have been carried out in order to gain different perspectives on how the solid solution adapts
at different length scales to cation mixing. X-ray powder diffraction and powder absorption IR spectroscopy data are presented.
The powder diffraction data show that there is no significant excess volume of mixing on the Fe–Mn columbite join. All the
unit-cell parameters decrease linearly as a function of increasing Fe content. Substitution of Fe2+ for the larger Mn2+ cation causes a decrease in the volume of the A polyhedron, which also becomes more regular with respect to both bond-length
and edge-length distortion parameters. No significant variation of the B site has been observed. Wavenumber shifts of the
IR peaks nearly all vary linearly with composition, consistent with linear variations of the lattice parameters. Line broadening
has been quantified by autocorrelation analysis of the IR spectra. This is interpreted as suggesting that there is some element
of local strain or positional disorder at the length scale of second or third nearest neighbours around sites occupied by
Fe. 相似文献
147.
摘要:根据郯庐断裂带南段韧性剪切带糜棱岩中同构造矿物组合、黑云母的存在以及长石的变形行为,推测其变形.变质温度为400一450oC。bo值分析表明.这些糜棱岩是在低压环境下形成的。在流体作用下。糜棱岩中的绿泥石既可以交代其它矿物而形成,也可以直接从流体中结晶形成。交代其它矿物所形成的绿泥石为Ⅱ型绿泥石,其结晶度值介于0.21^。一0.23^。20.与温度具有较好的对应关系。直接从流体中结晶而产生的绿泥石初始时刻为工型.其结晶度值介于0.236^。-0.341^。20之间,多屑于近变带范畴。其指示温度要低于实际所经历的环境温度。由于糜棱岩化过程中工型绿泥石的不断产生以及工型绿泥石向Ⅱ型绿泥石转化的不充分。导致了在400以上仍然出现工型绿泥石与Ⅱ型绿泥石混合的现象.并且实测的结晶度是不同时刻形成的、具不同结晶度的绿泥石的混合结晶度。 相似文献
148.
即时合成层状双氢氧化物处理酸性大红GR染料实验研究 总被引:3,自引:0,他引:3
印染废水是重要的工业污染源之一,研究新的印染废水脱色技术是水污染控制技术领域重要课题之一。以酸性大红GR为典型代表,初步研究了镁-铝盐水解共沉淀法即时合成层状双氢氧化物(LDH)处理阴离子型染料溶液的效果、影响因素和染料去除机理。结果表明,镁-铝盐水解共沉淀法即时合成LDH对酸性大红GR染料溶液有非常好的脱色效果,影响处理效果的主要因素是Mg/Al比和pH值。在pH值8.5~10.0,Mg/Al比2∶1~4∶1,都可以获得较好的净化效果,酸性大红GR染料浓度0.65 mmol/L时,染料去除率达99%。其净化机理是,当在染料溶液中投加Mg2 、Al2 溶解盐和NaOH时,Mg2 、Al3 水解共沉淀形成LDH的同时,染料阴离子以平衡LDH结构电荷的形式进入LDH结构层间,含有染料的LDH通过沉淀分离从溶液中去除。 相似文献
149.
在实验分析的基础上,提出了一种新的求取碎屑岩储层中粘土总量的方法---二级抽提分离+非定向X射线衍射法,即首先用传统的抽提分离法分别提取出粒径小于10μm和10~64μm的微粒,然后用粒径小于10μm微粒的质量加上利用非定向X射线法测出的粒径在10~64μm微粒中粘土部分的质量,就得到该样品中粘土总量。并以WN油田碎屑岩储层为例,具体论述了该法的计算过程及其实际应用效果。研究结果表明,该法具有原理简单、精度高、理论性强、实际应用效果良好的优点,可作为求取沉积岩储层中粘土总量的可靠方法。 相似文献
150.
采用x射线粉晶衍射(XRD)、博里叶变换红外光谱(FTI码以及拉曼光谱等方法对安徽马鞍山具磷灰石假象的绿松石进行了研究。结果表明:其主要矿物组成为绿松石,保留了磷灰石六边形的形态特征。XRD~U试的特征谱线d值为36745~36748(111)、29008~29025(123)、34247~34293(2101、32709~32781(113)、61626~61781(011)3020130~20162(301),与绿松石的标准衍射谱线基本致。红外光谱测试分析表明:3510~3465cm。间的谱带归属绿松石0(OH)的伸缩振动,3300~3070cm’间的谱带归属为绿松Nu(M-H。O)伸缩振动,1210-1012cm’间的谱带归属为绿松石U3口O。)ira缩振动,在838cm。附近的吸收谱带归属为绿松石6(OH)弯曲振动,655-480cm。间的谱带归属为绿松石u4(P04)弯曲振动。拉曼光谱测试分析表明:3466cm’附近的尖锐拉曼谱峰归属于绿松石(OH)基团的伸缩振动所致,宽缓的拉曼谱峰3281cm’~03078cm’归属于绿松石中水合络离子的伸缩振动,798cm’谱峰则是由于OH的弯曲振动所致。 相似文献