湖南郴州枞树板铅锌矿X光组构分析

作者通过对湖南郴州枞树板铅锌矿围岩及含矿构造带岩石的X光岩组分析,认为在构造变形过程中,原岩粒度越细,对变形的反映越敏感。在相同的变形条件下,较细的变质砂岩石的石英定向组构比较粗的变质砂岩内明显,板岩和粉砂质板岩的定向组构最明显。枞树板地区近EW向褶皱变形组构表现强烈,近SN向褶皱变形组构较弱。矿化热液的蚀变作用破坏了岩石中早期褶皱变形组构,但铅锌矿脉内的石英没有明显的生长组构,说明在矿化和含矿石英脉成生过程中没有明显的张性充填结晶表现,而是一种以交代为主的矿化形式。这与从其它地质地球化学研究取得的关于本     

Constraints on Cation Order in Calcium-rich Sedimentary Dolomite

Most sedimentary Ca-rich dolomite in pre-Holocenerocks is known to exhibit a fine-scale modulation inTEM images, reflecting a domain structure of which onecomponent is a low-symmetry variant of dolomite. Thevarious structural models proposed for thelow-symmetry component involve Ca–Mg order patternsthat are different from that in dolomite. Caution istherefore required for interpretation of X-raydiffraction data, which average over the entirestructure. The average structures of two Ca-richdolomites having a structural modulation are refinedusing single-crystal intensity data. The resultsindicate a poor fit using a dolomite model, which isconsistent with the findings from TEM and electrondiffraction indicating that one component of thedomain structure is different than dolomite. Resultsalso indicate that average model A and B cation siteshave mixed Ca–Mg occupancy, which provides someconstraints on possible models for the low-symmetrydomains.     

Octahedral cation ordering in olivine at high temperature. I: in situ neutron single-crystal diffraction studies on natural mantle olivines (Fa12 and Fa10)

Crystallographic determinations on natural olivine single crystals of mantle composition and origin, carried out by in situ neutron diffraction at high temperature, show that the octahedrally co-ordinated Fe²⁺ and Mg cations undergo two successive trends of cation ordering with increasing temperature. An initial slight preference of Fe²⁺ for site M1, up to a temperature of about 850?°C, is followed by a reverse-ordering reaction with a site preference exchange between the two cations. The cross-over between the two regimes of ordering, corresponding to a situation of complete disorder, occurs at about 900?°C. Above this temperature Fe²⁺ progressively and strongly segregates into site M2 up to 1300?°C, the practical limit of the experimental setup utilized in the experiments. Care was taken to ensure that no chemical changes occurred in the crystals (i.e. oxidation), as testified by Mössbauer spectroscopy determinations carried out before and after the heat treatment. The cation-ordering behaviour is reflected in temperature-dependent changes of geometrical and atomic displacement parameters occurring in the octahedral sites M1 and M2. A thermodynamical explanation of this behaviour is proposed in terms of a prevailing vibrational contribution to entropy.     

正交直墙前直立圆柱的波浪绕射的解析研究

应用镜像原理,将正交直墙前单个圆柱的波浪绕射问题,转化为4个对称布置圆柱的4向入射波浪的绕射问题。然后应用速度势的特征展开方法和Graf加法定理,建立了正交直墙前垂直圆柱的波浪绕射解析解。通过数值计算研究了圆柱与正交直墙间距离大小、波浪入射角等因素与圆柱上总波浪作用力的解析关系。     

北京崎峰茶金矿床X光岩石组构分析

岩石组构是指组成岩石的矿物在岩石中分布的各向异性,Ｘ光岩组分析就是运用Ｘ光衍射技术测定岩石结构要素－岩石中矿物分布的规律性。通过对北京崎峰茶金矿区含矿韧性－韧脆性变形岩石为Ｘ光岩组分析,认为该区岩石变形比较明显,石英变形机制是以中低温底面或近底面滑移为特征,而作为斜长角闪质岩石和长英质岩石的退变质矿物绿泥石和绢云母等片状矿物则平行变形面理定向排列。从岩石组构特点结合宏观构造分析可以推断,该区属于中     

Water wave interaction with an array of bottom-mounted surface-piercing porous cylinders

The interaction of water waves with arrays of bottom-mounted, surface-piercing circular cylinders is investigated theoretically. The sidewall of each cylinder is porous and thin. Under the assumptions of potential flow and linear wave theory, a semi-analytical solution is obtained by an eigenfunction expansion approach first proposed for impermeable cylinders by Spring and Monkmeyer (1974), and later simplified by Linton and Evans (1990). Analytical expressions are developed for the wave motion in the exterior and all interior fluid regions. Numerical results are presented which illustrate the effects of various wave and structural parameters on the hydrodynamic loads and the diffracted wave field. It is found that the porosity of the structures may result in a significant reduction in both the hydrodynamic loads experienced by the cylinders and the associated wave runup.     

Water wave interaction with a floating porous cylinder

The interaction of water waves with a freely floating circular cylinder possessing a side-wall that is porous over a portion of its draft is investigated theoretically. The porous side-wall region is bounded top and bottom by impermeable end caps thereby resulting in an enclosed fluid region within the structure. The problem is formulated based on potential flow and linear wave theory and assuming small-amplitude structural oscillations. An eigenfunction expansion approach is then used to obtain semi-analytical expressions for the hydrodynamic excitation and reaction loads on the structure. Numerical results are presented which illustrate the effects of the various wave and structural parameters on these quantities. It is found that the permeability, size and location of the porous region may have a significant influence on the horizontal components of the hydrodynamic excitation and reaction loads, while its influence on the vertical components in most cases is relatively minor.     

电感耦合等离子体质谱-X射线衍射法研究云南玉溪和美国内华达地区黏土型锂资源矿物学特征

中国云南玉溪和美国内华达均已发现大量黏土型锂资源,目前关于两地区样品矿物学特征的研究相对不足,而对黏土型锂资源进行充分的矿物学特征研究是锂提取工作开展的重要前提.本文采用X射线荧光光谱、电感耦合等离子体质谱、X射线粉晶衍射、扫描电镜等分析技术,从化学组成、矿物组成、微观形貌等角度对云南玉溪的两个黏土型锂资源样品(YM-...     

Structural properties of (Mn1-x Fe x )Nb2O6 columbites from X-ray diffraction and IR spectroscopy

A suite of (Mn_1-x Fe _x )Nb₂O₆ (x=0, 0.05, 0.25, 0.50, 0.75, 1) columbite samples has been prepared by solid-state reaction from oxides. X-ray diffraction and spectroscopic investigations have been carried out in order to gain different perspectives on how the solid solution adapts at different length scales to cation mixing. X-ray powder diffraction and powder absorption IR spectroscopy data are presented. The powder diffraction data show that there is no significant excess volume of mixing on the Fe–Mn columbite join. All the unit-cell parameters decrease linearly as a function of increasing Fe content. Substitution of Fe²⁺ for the larger Mn²⁺ cation causes a decrease in the volume of the A polyhedron, which also becomes more regular with respect to both bond-length and edge-length distortion parameters. No significant variation of the B site has been observed. Wavenumber shifts of the IR peaks nearly all vary linearly with composition, consistent with linear variations of the lattice parameters. Line broadening has been quantified by autocorrelation analysis of the IR spectra. This is interpreted as suggesting that there is some element of local strain or positional disorder at the length scale of second or third nearest neighbours around sites occupied by Fe.