Pressure-induced incipient amorphization of α-quartz and transition to coesite in an eclogite from Antarctica: a first record and some consequences

Monocrystalline quartz inclusions in garnet and omphacite from various eclogite samples from the Lanterman Range (Northern Victoria Land, Antarctica) have been investigated by cathodoluminescence (CL), Raman spectroscopy and imaging, and in situ X‐ray (XR) microdiffraction using the synchrotron. A few inclusions, with a clear‐to‐opalescent lustre, show ‘anomalous’ Raman spectra characterized by weak α‐quartz modes, the broadening of the main α‐quartz peak at 465 cm^?1, and additional vibrations at 480–485, 520–523 and 608 cm^?1. CL and Raman imaging indicate that this ‘anomalous’α‐quartz occurs as relicts within ordinary α‐quartz, and that it was preserved in the internal parts of small quartz inclusions. XR diffraction circular patterns display irregular and broad α‐quartz spots, some of which show an anomalous d‐spacing tightening of ～2%. They also show some very weak, hazy clouds that have d‐spacing compatible with coesite but not with α‐quartz. Raman spectrometry and XR microdiffraction characterize the anomalies with respect to α‐quartz as (i) a pressure‐induced disordering and incipient amorphization, mainly revealed by the 480–485 and 608‐cm^?1 Raman bands, together with (ii) a lattice densification, evidenced by d‐spacing tightening; (iii) the cryptic development of coesite, 520–523 cm^?1 being the main Raman peak of coesite and (iv) Brazil micro‐twinning. This ‘anomalous’α‐quartz represents the first example of pressure‐induced incipient amorphization of a metastable phase in a crustal rock. This issue is really surprising because pressure‐induced amorphization of metastable α‐quartz, observed in impactites and known to occur between 15 and 32 GPa during ultrahigh‐pressure (UHP) experiments at room temperature, is in principle irrelevant under normal geological P–T conditions. A shock (due to a seism?) or a local overpressure at the inclusion scale (due to expansion mismatch between quartz and its host mineral) seem the only geological mechanisms that can produce such incipient amorphization in crustal rocks. This discovery throws new light on the modality of the quartz‐coesite transition and on the pressure regimes (non‐lithostatic v. lithostatic) during high‐pressure/UHP metamorphism. In particular, incipient amorphization of quartz could favour the quartz‐coesite transition, or allow the growth of metastable coesite, as already experimentally observed.     

Morphological redshift estimates for galaxy clusters in a Sunyaev–Zel'dovich effect survey

We develop a new method to estimate the redshift of galaxy clusters through resolved images of the Sunyaev–Zel'dovich effect (SZE). Our method is based on morphological observables which can be measured by actual and future SZE experiments. We test the method with a set of high-resolution hydrodynamical simulations of galaxy clusters at different redshifts. Our method combines the observables in a principal component analysis. After calibrating the method with an independent redshift estimation for some of the clusters, we show – using a Bayesian approach – how the method can give an estimate of the redshift of the galaxy clusters. Although the error bars given by the morphological redshift estimation are large, it should be useful for future SZE surveys where thousands of clusters are expected to be detected; a first preselection of the high-redshift candidates could be done using our proposed morphological redshift estimator. Although not considered in this work, our method should also be useful to give an estimate of the redshift of clusters in X-ray and optical surveys.     

CCD photometry inVRI bands of the galactic cluster NGC 2818

bdAbstract The open cluster NGC 2818 containing a planetary nebula has been observed inVRI bands using the CCD system at prime focus of the 2.3-metre Vainu Bappu Telescope. The study extending to starsV ∼ 21 magnitude establishes the distance modulus as(m-M) ₀ = 12.9 ±0.1 for the cluster. Based on the fitting of theoretical isochrones computed for solar metallicity, an age of 5(±1) × 10₈ years has been assigned to the cluster. Association of the planetary nebula with the cluster indicates that the progenitor mass of the planetary nebula on the main sequence is ≥2.5M_⊙ Based on observations obtained with the Vainu Bappu Telescope.     

Relativist ic Corrections to the Thermal Sunyaev-Zel''''dovich Power Spectrum

We present a quantitative estimate of the relativistic corrections to the thermal SZ power spectrum produced by the energetic electrons in massive clusters. The corrections are well within 10% for current experiments with working frequencies below v < 100 GHz, but become non-negligible at high frequencies v > 350 GHz. Moreover, the corrections appear to be slightly smaller at higher l or smaller angular scales. We conclude that there is no need to include the relativistic corrections in the theoretical study of the SZ power spectrum especially at low frequencies unless the SZ power spectrum is used for precision cosmology.     

The evolution of binary fractions in globular clusters

We study the evolution of binary stars in globular clusters using a new Monte Carlo approach combining a population synthesis code ( startrack ) and a simple treatment of dynamical interactions in the dense cluster core using a new tool for computing three- and four-body interactions ( fewbody ). We find that the combination of stellar evolution and dynamical interactions (binary–single and binary–binary) leads to a rapid depletion of the binary population in the cluster core. The maximum binary fraction today in the core of a typical dense cluster such as 47 Tuc, assuming an initial binary fraction of 100 per cent, is only ∼ 5–10 per cent. We show that this is in good agreement with recent Hubble Space Telescope observations of close binaries in the core of 47 Tuc, provided that a realistic distribution of binary periods is used to interpret the results. Our findings also have important consequences for the dynamical modelling of globular clusters, suggesting that 'realistic models' should incorporate much larger initial binary fractions than has usually been the case in the past.