New Sakmarian ages for the Rio Bonito formation (Paraná Basin,southern Brazil) based on LA-ICP-MS U–Pb radiometric dating of zircons crystals

Two ash fall beds (tonstein) sampled from the post-glacial Permian deposits of the Paraná Basin have provided new U–Pb radiometric age constraints for this stratigraphic interval. The zircon grains were recovered from tonstein layers interbedded with fine-grained and carbonaceous lithologies in the middle portion of the Rio Bonito Formation. In both samples, the dominant population is interpreted as generated by explosive volcanism, as having formed immediately before the eruption. Based on ²³⁸U/²⁰⁶Pb, the selected zircon grains from the dominant population have weighted mean ages of 290.6 ± 2.8 Ma and 281.7 ± 3.2 Ma, corresponding to the Sakmarian and Kungurian ages in the Cisuralian epoch, respectively. These ages constrain the time of the deposition of the tonstein horizons and have important stratigraphic implications for the Late Paleozoic evolution of both the Paraná Basin and the southwestern region of Gondwana. The results presented here and the radiometric data already published suggest that deposition of the post-glacial coal-bearing deposits of the Rio Bonito Formation was probably initiated before the Early Permian. Thus, we infer that the climate had already ameliorated by this period in order to allow for the formation and accumulation of peat in this region of Gondwana.     

Volcanic activity at Tvashtar Catena, Io

Galileo's Solid State Imager (SSI) observed Tvashtar Catena four times between November 1999 and October 2001, providing a unique look at a distinctive high latitude volcanic complex on Io. The first observation (orbit I25, November 1999) resolved, for the first time, an active extraterrestrial fissure eruption; the brightness temperature was at least 1300 K. The second observation (orbit I27, February 2000) showed a large (∼500 km²) region with many, small, hot, regions of active lava. The third observation was taken in conjunction with Cassini imaging in December 2000 and showed a Pele-like, annular plume deposit. The Cassini images revealed an ∼400 km high Pele-type plume above Tvashtar Catena. The final Galileo SSI observation of Tvashtar (orbit I32, October 2001), revealed that obvious (to SSI) activity had ceased, although data from Galileo's Near Infrared Mapping Spectrometer (NIMS) indicated that there was still significant thermal emission from the Tvashtar region. In this paper, we primarily analyze the style of eruption during orbit I27 (February 2000). Comparison with a lava flow cooling model indicates that the behavior of the Tvashtar eruption during I27 does not match that of simple advancing lava flows. Instead, it may be an active lava lake or a complex set of lava flows with episodic, overlapping eruptions. The highest reliable color temperature is ∼1300 K. Although higher temperatures cannot be ruled out, they do not need to be invoked to fit the observed data. The total power output from the active lavas in February 2000 was at least ¹⁰¹¹ W.     

Speckle imaging of volcanic hotspots on Io with the Keck telescope

Using speckle imaging techniques on the 10-m W.M. Keck I telescope, we observed near-infrared emission at 2.2 μm from volcanic hotspots on Io in July-August 1998. Using several hundreds of short-exposure images we reconstructed diffraction-limited images of Io on each of three nights. We measured the positions of individual hotspots to ±0.004″ or better, corresponding to a relative positional error of ∼20 km on Io's surface. The sensitivity of normal ground-based images of Io is limited by confusion between overlapping sources; by resolving these multiple points we detected up to 17 distinct hotspots, the largest number ever seen in a single image.During the month-long span of our 1998 observations, several events occurred. Loki was at the end of a long brightening, and we observed it to fade in flux by a factor of 2.8 over the course of one month. At the 3-sigma level we see evidence that Loki's position shifts by ∼100 km. This suggests that the brightening may not have been located at the “primary” Loki emission center but at a different source within the Loki caldera. We also see a bright transient source near Loki. Among many other sources we detect a dim source on the limb of Io at the latitude of Pele; this source is consistent with 2.7% of the thermal emission from the Pele volcano complex being scattered by the Pele plume, which would be the first detection of a plume through scattered infrared hotspot emission.     

Shield volcano topography and the rheology of lava flows on Io

Stereo and photoclinometry derived topography of shield-like volcanoes on Io indicate little relief (<3 km) and very low slopes (0.2° to 0.6°). Several shield volcanoes appear to be associated with broad rises of 1 to 3 km, but only 5 shield volcanoes have been identified with steep flank slopes (between 4° and 10°). These steep slopes are restricted to within 20-30 km of the summit, but where discernable, most of the lava flows observed on these edifices occur on the outer flanks where slopes are less than a degree. Despite their abundance, ionian shield volcanoes are among the flattest in the Solar System. The steepest volcanoes on Io are most comparable to large venusian shield volcanoes. Using simplistic Bingham rheologies we estimate the viscosity and yield strengths of ionian lavas. Yield strengths are estimated at 10¹-10² Pa, lower than most basaltic lavas. Viscosity estimates range from 10³ to 10⁵ Pa s, although these are probably upper limits. Actual values may have been as low as 10⁰ Pa s. Viscosity is sensitive to flow velocity, which is poorly known on Io. The best constraint on flow velocity comes from observations of the 1997 Pillan eruption, which bracket the eruptive phase to 132 day maximum, and more probably less than 50 days. Low slopes, long run-out distances and our estimated rheologic properties are consistent with (but not proof of) a low silica, low viscosity, high temperature composition for ionian lavas, supporting arguments for low-silica lava compositions such as basalt or komatiite. We cannot eliminate sulfur on rheologic grounds, however.     

Compositional analyses of lunar pyroclastic deposits

The 5-band Clementine UVVIS data at ∼100 m/pixel were used to examine the compositions of 75 large and small lunar pyroclastic deposits (LPDs), and these were compared to representative lunar maria and highlands deposits. Results show that the albedo, spectral color, and inferred composition of most LPDs are similar to those of low-titanium, mature lunar maria. These LPDs may have consisted largely of fragmented basalt, with substantial components of iron-bearing mafic minerals (pyroxenes, olivine) and smaller amounts (if any) of volcanic glass. Several smaller LPDs also show substantial highland components. Three classes of very large deposits can be distinguished from most LPDs and from each other on the basis of crystallinity and possible titanium content of their pyroclastic components. One class has spectral properties that are dominated by high-titanium, crystallized “black beads” (e.g., Taurus-Littrow), a second consists of a mixture of high-titanium glasses and beads with a higher glass/bead ratio (Sulpicius Gallus) than that of Taurus-Littrow, and a third has a significant component of quenched iron-bearing volcanic glasses (Aristarchus) with possible moderate titanium contents. Although areally extensive, these three classes of very large pyroclastic deposits compose only 20 of the 75 deposits studied (∼27%), and eruption of such materials was thus likely to have been less frequent on the Moon.     

A stratigraphic study of southern Oceanus Procellarum using Clementine multispectral data

In this paper, we use Clementine multispectral data to demonstrate techniques from which spectrally distinct mare basalts can be mapped, and estimates of basalt thickness obtained. The region studied incorporates a portion of southern Oceanus Procellarum from 17.5°N to 20.5°S and 289°E to 317°E, including the Marius Hills, Damoiseau, Cavalerius and Flamsteed areas. Flamsteed provides a test area from which we validate the mapping techniques used in this work. Unit boundaries and basalt thickness details from these analyses are applied to the stratigraphy of the Oceanus Procellarum Group defined by Whitford-Stark and Head (J. Geophys. Res. 85 (1980) 6579). A total of 13 basalts are recognised in the region, 10 of which are spectrally distinct, and three of which represent previously unrecognised Members of the Oceanus Procellarum Group. The average thickness of the basalts is between 160 and 625 m, ranging from tens to hundreds of metres near the mare/highland boundaries and consistently greater than several hundred metres closer to the centre of the mare. These values provide a range of basalt volume in the region of 0.7–2.8×10⁵ km³. This represents between 8% and 32% of the total volume of basalts in Oceanus Procellarum.     

Phreato-magmatic dike-cryosphere interactions as the origin of small ridges north of Olympus Mons, Mars

Using images from the Mars Orbiter Camera, we have identified several linear ridges located 10-60 km north of the volcano Olympus Mons, Mars, at the edge of the Olympus Mons aureole materials. These ridges appear to be made of unconsolidated material by virtue of the many dust avalanche scars seen on their upper slopes. Based upon their morphology (several ridges have crater-like central depressions) and superposition relationships, the ridges appear to have formed very recently and post-date the formation of the youngest lava flows spilling over the northern escarpment of Olympus Mons. Several possible origins for the ridges, including an eolian, periglacial, or depositional origin have been considered, but we favor a ridge origin by a series of small explosive eruptions initiated by the intrusion of a dike into a volatile-rich substrate. To explore this process, we develop a numerical model for dike intrusion into a volatile-rich substrate that yields plausible dike widths between 2.4-3.5 m. The total volume of a single ridge system is ∼65×10⁶ m³, and we calculate that it may have taken only a few minutes to form. Viable solutions only exist when the thicknesses of the ice-rich layer is less than ∼1000-2000 m. This strongly suggests that the ice-rich region is limited in its vertical extent to a value of this order.     

Tharsis Tholus: an unusual martian volcano

Tharsis Tholus is unusual martian shield volcano in that the edifice is cut by a series of large normal faults that appear to penetrate the entire volcano. Northeast-trending narrow graben also cut the flank. The large normal faults may be caused by loading of a ductile subsurface layer allowing failure of the edifice; the narrow graben are typical tensional faults. The flank is heavily mantled by aeolian material. Despite the bulbous appearance, the overall morphology of Tharsis Tholus suggests it is a basaltic shield. Crater counts indicate an age of early Hesperian placing Tharsis Tholus in the middle of the period of activity that built the other small Tharsis volcanoes.     

A thermodynamic model of high temperature lava vaporization on Io

We modified the MAGMA chemical equilibrium code developed by Fegley and Cameron (1987, Earth Planet. Sci. Lett. 82, 207-222) and used it to model vaporization of high temperature silicate lavas on Io. The MAGMA code computes chemical equilibria in a melt, between melt and its equilibrium vapor, and in the gas phase. The good agreement of MAGMA code results with experimental data and with other computer codes is demonstrated. The temperature-dependent pressure and composition of vapor in equilibrium with lava is calculated from 1700 to 2400 K for 109 different silicate lavas in the ONaKFeSiMgCaAlTi system. Results for five lavas (tholeiitic basalt, alkali basalt, Barberton komatiite, dunite, and a molten type B1 Ca, Al-rich inclusion) are discussed in detail. The effects of continuous fractional vaporization on chemistry of these lavas and their equilibrium vapor are presented. The predicted abundances (relative to Na) of K, Fe, Si, Al, Ca, and Ti in the vapor equilibrated with lavas at 1900 K are lower than published upper limits for Io's atmosphere (which do not include Mg). We predict evaporative loss of alkalis, Fe, and Si during volcanic eruptions. Sodium is more volatile than K, and the Na/K ratio in the gas is decreased by fractional vaporization. This process can match Io's atmospheric Na/K ratio of 10±3 reported by Brown (2001, Icarus 151, 190-195). Silicon monoxide is an abundant species in the vapor above lavas. Spectroscopic searches are recommended for SiO at IR and mm wavelengths. Reactions of metallic vapors with S- and Cl-bearing volcanic gases may form other unusual gases including MgCl₂, MgS, MgCl, FeCl₂, FeS, FeCl, and SiS.     

On the discovery of CO nighttime emissions on Titan by Cassini/VIMS: Derived stratospheric abundances and geological implications

We present a quantitative analysis of CO thermal emissions discovered on the nightside of Titan by Baines et al. [2005. The atmospheres of Saturn and Titan in the near-infrared: First results of Cassini/VIMS. Earth, Moon, and Planets, 96, 119–147]. in Cassini/VIMS spectral imagery. We identify these emission features as the P and R branches of the 1-0 vibrational band of carbon monoxide (CO) near 4.65 μm. For CH₃D, the prominent Q branch of the ν₂ fundamental band of CH₃D near 4.55 μm is apparent. CO₂ emissions from the strong v₃ vibrational band are virtually absent, indicating a CO₂ abundance several orders of magnitude less than CO, in agreement with previous investigations. Analysis of CO emission spectra obtained over a variety of altitudes on Titan's nightside limb indicates that the stratospheric abundance of CO is 32±15 ppm, and together with other recent determinations, suggests a vertical distribution of CO nearly constant at this value from the surface throughout the troposphere to at least the stratopause near 300 km altitude. The corresponding total atmospheric content of CO in Titan is 2.9±1.5×10¹⁴ kg. Given the long lifetime of CO in the oxygen-poor Titan atmosphere (0.5–1.0 Gyr), we find a mean CO atmospheric production rate of 6±3×10⁵ kg yr⁻¹. Given the lack of primordial heavy noble gases observed by Huygens [Niemann et al., 2005. The abundances of constituents of Titan's atmosphere from the GCMS on the Huygens probe. Nature, 438, 779–784], the primary source of atmospheric CO is likely surface emissions. The implied CO/CH₄ mixing ratio of near-surface material is 1.8±0.9×10⁻⁴, based on an average methane surface emission rate over the past 0.5 Gyr of 1.3×10⁻¹³ gm cm⁻² s⁻¹ as required to balance hydrocarbon haze production via methane photolysis [Wilson and Atreya, 2004. Current state of modeling the photochemistry of Titan's mutually dependent atmosphere and ionosphere. J. Geophys. Res. 109, E06002 Doi:10.1029/2003JE002181]. This low CO/CH₄ ratio is much lower than expected for the sub-nebular formation region of Titan and supports the hypothesis [e.g., Atreya et al., 2005. Methane on Titan: photochemical-meteorological-hydrogeochemical cycle. Bull. Am. Astron. Soc. 37, 735] that the conversion of primordial CO and other carbon-bearing materials into CH₄-enriched clathrate-hydrates occurs within the deep interior of Titan via the release of hydrogen through the serpentinization process followed by Fischer–Tropsch catalysis. The time-averaged predicted emission rate of methane-rich surface materials is 0.02 km³ yr⁻¹, a value significantly lower than the rate of silicate lava production for the Earth and Venus, but nonetheless indicative of significant active geological processes reshaping the surface of Titan.