全文获取类型
收费全文 | 1199篇 |
免费 | 193篇 |
国内免费 | 320篇 |
专业分类
测绘学 | 13篇 |
大气科学 | 125篇 |
地球物理 | 457篇 |
地质学 | 568篇 |
海洋学 | 276篇 |
天文学 | 83篇 |
综合类 | 54篇 |
自然地理 | 136篇 |
出版年
2024年 | 6篇 |
2023年 | 16篇 |
2022年 | 37篇 |
2021年 | 39篇 |
2020年 | 52篇 |
2019年 | 65篇 |
2018年 | 60篇 |
2017年 | 55篇 |
2016年 | 42篇 |
2015年 | 43篇 |
2014年 | 85篇 |
2013年 | 69篇 |
2012年 | 80篇 |
2011年 | 96篇 |
2010年 | 60篇 |
2009年 | 77篇 |
2008年 | 76篇 |
2007年 | 94篇 |
2006年 | 92篇 |
2005年 | 64篇 |
2004年 | 64篇 |
2003年 | 64篇 |
2002年 | 28篇 |
2001年 | 38篇 |
2000年 | 51篇 |
1999年 | 42篇 |
1998年 | 45篇 |
1997年 | 32篇 |
1996年 | 28篇 |
1995年 | 30篇 |
1994年 | 19篇 |
1993年 | 13篇 |
1992年 | 8篇 |
1991年 | 14篇 |
1990年 | 7篇 |
1989年 | 5篇 |
1988年 | 4篇 |
1987年 | 4篇 |
1986年 | 1篇 |
1984年 | 3篇 |
1983年 | 1篇 |
1981年 | 1篇 |
1980年 | 2篇 |
排序方式: 共有1712条查询结果,搜索用时 781 毫秒
111.
112.
J. A. Tossell 《Aquatic Geochemistry》2001,7(4):239-254
Changes in the UV spectra of As(OH)3 solutions with variations in pH and temperature have recently been used to determine the temperature dependence of the pKa of the acid. In previous studies I used quantum mechanical techniques to study changes in structure and vibrational spectra as a function of pH for arsenites and thioarsenites. I previously calculated UV spectra for ``molecular' minerals, like realgar As4S4. Here I use a number of different quantum mechanical methods, both Hartree-Fock and density functional theory based, to calculate the UV spectra for both a related simple well-characterized gas-phase molecule PF3 and for As(OH)3 and As(SH)3 and their conjugate anions and some neutral and anionic oligomers in aqueous solution. For the monomeric species small numbers of water molecules have been explicitly included, in a supermolecule or microsolvation approach. I find that UV absorption energies accurate to a few tenths of an eV can be obtained both for gas- phase PF3 and for neutral arsenious acid in aqueous solution, for which the UV absorption maximum is calculated to occur around 6.5 eV, consistent with experiment. Accurate calculation of the UV energies for arsenite anions in aqueous solution is much more difficult, since basis set size and solvation effects are considerably larger than for the neutral molecules, but fairly reliable results can still be obtained. Deprotonation is found to reduce the lowest calculated UV transition energy by about half an eV. Oligomerization also reduces the lowest calculated UV energy by at least half an eV. Replacement of one or all the –OH groups by –SH groups reduces the lowest calculated UV energies by about 2 eV. UV excitation energies have been calculated for oligomeric species as large as As3E3(EH)3 and As4E6, where E = O, S, and may be useful for identifying such species in solution. 相似文献
113.
The influence of various cloud parameters and the interactions with the ground albedo and the solar zenith angle have been studied by means of model simulations. The radiative transfer model suitable for a cloudy atmosphere as well as for a clear atmosphere has been developed on the basis of the Discrete Ordinate Method. This study leads to a general understanding for cloudy atmospheres: in the presence of a uniform cloud, the cloud scattering is dominant to molecular and aerosol scattering, and it is also wavelength-independent; the ratio of transmitted irradiance in a cloudy atmosphere to that in the background clear atmosphere is independent of cloud height and solar zenith angle. That’s to say, the radiation downwelling out of a cloud is quite isotropic; it decreases approximately exponentially with the cloud optical depth at a rate related to the ground albedo; the reflected irradiance at the top of the atmosphere is dependent on cloud optical depth as well as on solar zenith angle, but not on ground albedo for clouds of not very thin optical depth. 相似文献
114.
Absorption cross-section measurements of NO2 performed in our laboratory have been extended to the 200–300 nm region at ambient temperature. Low pressures have been used, limiting the effects of the dimer N2O4 which has an absorption cross-section from one to two orders of magnitude larger than that of NO2 in this region. The results have been compared to those of previous authors and are now available for atmospheric purposes at 0.01 nm intervals.Unité de Recherche Associée au CNRS. 相似文献
115.
116.
从提高动测桩的功能和精度,深入研究桩-土相互作用机理出发,作者开展了波动方程分析程序的编制和研究。作者采用了凯普威普(CAPWAP C)程序中的一些基本假设和基本模型,而在一些模型和方法上作了某些改进,在此基础上提出了“新编凯斯波动分析程序”。该程序可以解决一般凯斯法(Case method)不能解决的问题:变断面桩;桩身沿长度方向上材料不同的桩;桩身较长的桩(25m 以上)。可以提供较为深入的更全面的数据:单桩总静阻力;桩侧静摩阻力;桩端端承力;各土层的摩阻力,…,等。本文叙述了“新编凯斯波动分析程序”的编制目的,基本原理与模型,计算步骤。并提供了在某工程实例中的应用情况。 相似文献
117.
本文采用类比法和定量化方法对上海宝山区村镇民房震害损失进行了预测。在此基础上,对上海已有的和新建的民房提出抗震对策和措施。 相似文献
118.
本文通过考虑地震烈度的随机性和模糊性,以及石结构强度破坏等级界限的模糊性,研究多层石结构抗震抗剪能力的可靠性问题.将地震地面运动模拟为含有模糊烈度参数的平稳过滤有色噪声的随机过程,引入抗剪强度破坏指数,建立了石结构抗震抗剪能力的模糊安全准则,为研究多层石结构的抗震抗剪能力可靠性提供了一个合理的评定方法。 相似文献
119.
WANG Guixian WANG Xingkui GUO Jiachao Professor Sediment Research Laboratory Dept. of Hydraulic Engineering Tsinghua University Beijing China. Associate Professor Dept. of Hydraulic Engineering Tsinghua University. Assistant Dept. of Hydraulic Engineering Tsinghua University. 《国际泥沙研究》1993,(3)
I. INTRODUCTIONResistance to flow in alluvial streams is one of the crucial problems in fluvial hydraulics. Despite that large amount of studies have been conducted for centuries, no perfectmethod describing and calculating the resistance to flow in alluvial streams is availablehll now. Investigation on bed forms and resistance properties of light--weight bed materials is even more scarce. USWES (1936) has conducted systematic experiments onlight--weight materials in a flume & m long an… 相似文献
120.