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Wagner José Barreto Ieda Scarminio Maria Cristina Solci Dílson Norio Ishikawa Melissa Tiemi Ogasawara Sônia Naomi Nomi Sônia Regina Giancoli Barreto 《洁净——土壤、空气、水》2007,35(3):239-245
Seventeen physical and chemical parameters were obtained from a hydroelectric reservoir located in a tropical region in the south of Brazil. Multivariate Principal Component Analysis (PCA) and Hierarchical Group Analysis (HGA) were used to identify the parameters discriminating the origin of water from the Tibagi and the Primeiro de Maio River, after it has passed the mixing region. The study was conducted during the dry and rainy seasons in July 2002 and February 2003 at three depths and three sampling sites located 0, 5, and 10 km away from the mixing region. The statistical methods showed to be appropriate for identifying the contribution of each tributary in the water mixing site of a complex water system. The most important discriminating parameter was the absorbance relation A(253 nm)/A(203 nm), followed by the concentrations of Fe(III), Mn(III), and Ni(II). An anthropogenic interference was found in the reservoir due to high Ni(II) and orthophosphate concentrations caused by a nearby town sewage discharge. The interference was more important during the dry periods due to the lower dispersion of the pollutants. Urgent initiatives should be taken from the state government to build treatment stations for the wastewater of the small cities around the Capivara hydroelectric reservoir to prevent the drinking water quality from deteriorating. 相似文献
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通过对某铁路特大桥钻孔灌注桩单桩竖向静载荷试验、桩身轴力测试,探讨钻孔灌注桩侧摩阻力发挥的影响因素及荷载传递中的工程性状,为钻孔灌注桩的设计、施工提供参考。 相似文献
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J. A. Tossell 《Aquatic Geochemistry》2001,7(4):239-254
Changes in the UV spectra of As(OH)3 solutions with variations in pH and temperature have recently been used to determine the temperature dependence of the pKa of the acid. In previous studies I used quantum mechanical techniques to study changes in structure and vibrational spectra as a function of pH for arsenites and thioarsenites. I previously calculated UV spectra for ``molecular' minerals, like realgar As4S4. Here I use a number of different quantum mechanical methods, both Hartree-Fock and density functional theory based, to calculate the UV spectra for both a related simple well-characterized gas-phase molecule PF3 and for As(OH)3 and As(SH)3 and their conjugate anions and some neutral and anionic oligomers in aqueous solution. For the monomeric species small numbers of water molecules have been explicitly included, in a supermolecule or microsolvation approach. I find that UV absorption energies accurate to a few tenths of an eV can be obtained both for gas- phase PF3 and for neutral arsenious acid in aqueous solution, for which the UV absorption maximum is calculated to occur around 6.5 eV, consistent with experiment. Accurate calculation of the UV energies for arsenite anions in aqueous solution is much more difficult, since basis set size and solvation effects are considerably larger than for the neutral molecules, but fairly reliable results can still be obtained. Deprotonation is found to reduce the lowest calculated UV transition energy by about half an eV. Oligomerization also reduces the lowest calculated UV energy by at least half an eV. Replacement of one or all the –OH groups by –SH groups reduces the lowest calculated UV energies by about 2 eV. UV excitation energies have been calculated for oligomeric species as large as As3E3(EH)3 and As4E6, where E = O, S, and may be useful for identifying such species in solution. 相似文献
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The influence of various cloud parameters and the interactions with the ground albedo and the solar zenith angle have been studied by means of model simulations. The radiative transfer model suitable for a cloudy atmosphere as well as for a clear atmosphere has been developed on the basis of the Discrete Ordinate Method. This study leads to a general understanding for cloudy atmospheres: in the presence of a uniform cloud, the cloud scattering is dominant to molecular and aerosol scattering, and it is also wavelength-independent; the ratio of transmitted irradiance in a cloudy atmosphere to that in the background clear atmosphere is independent of cloud height and solar zenith angle. That’s to say, the radiation downwelling out of a cloud is quite isotropic; it decreases approximately exponentially with the cloud optical depth at a rate related to the ground albedo; the reflected irradiance at the top of the atmosphere is dependent on cloud optical depth as well as on solar zenith angle, but not on ground albedo for clouds of not very thin optical depth. 相似文献
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Absorption cross-section measurements of NO2 performed in our laboratory have been extended to the 200–300 nm region at ambient temperature. Low pressures have been used, limiting the effects of the dimer N2O4 which has an absorption cross-section from one to two orders of magnitude larger than that of NO2 in this region. The results have been compared to those of previous authors and are now available for atmospheric purposes at 0.01 nm intervals.Unité de Recherche Associée au CNRS. 相似文献
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从提高动测桩的功能和精度,深入研究桩-土相互作用机理出发,作者开展了波动方程分析程序的编制和研究。作者采用了凯普威普(CAPWAP C)程序中的一些基本假设和基本模型,而在一些模型和方法上作了某些改进,在此基础上提出了“新编凯斯波动分析程序”。该程序可以解决一般凯斯法(Case method)不能解决的问题:变断面桩;桩身沿长度方向上材料不同的桩;桩身较长的桩(25m 以上)。可以提供较为深入的更全面的数据:单桩总静阻力;桩侧静摩阻力;桩端端承力;各土层的摩阻力,…,等。本文叙述了“新编凯斯波动分析程序”的编制目的,基本原理与模型,计算步骤。并提供了在某工程实例中的应用情况。 相似文献