Improvement in the calculation of anti-Stokes energy transfer and experimental justification based on Er0.01YbxY1 - 0.01 - xVO4 crystal

The improvement on the calculation of anti-Stokes energy transfer rate is studied in the present work. The additional proportion coefficient between Stokes and anti-Stokes light intensities of quantum Raman scattering theory as compared with the classical Raman theory is introduced to successfully describe the anti-Stokes energy transfer. The theoretical formula for the improvement on the calculation of anti-Stokes energy transfer rate is derived for the first time in this study. The correctness of introducing coefficient exp{ΔE / kT} from well-known Raman scatter theory is demonstrated also. Moreover, the experimental lifetime measurement in Er_0.01Yb_xY_{1 - 0.01 - x}VO₄ crystal is performed to justify the validity of our important improvement in the original phonon-assisted energy transfer theory for the first time.     

The relationship between the canonical ENSO and the phase transition of the Antarctic oscillation at the quasi-quadrennial timescale

A correlation analysis is performed to investigate the relationship between El Nino-Southern Oscillation (ENSO) and the Antarctic oscillation (AAO) at the quasi-quadrennial (QQ) timescale.It is found that the cold tongue index (CTI) and the AAO index (AAOI) are negatively correlated with about a 7-month lead-time,while they are positively correlated with about a 15-month lag-time.To further explore this relationship,complex empirical orthogonal function analysis is employed in the QQ sea level pressure (SLP) anomalies from 1951 to 2002.The results indicate that,during the ENSO cycle,there exists one kind of global tropical wave of wavenumber 1 (GTW1) propagating eastward.With the traveling of GTW1,the tropical SLP anomaly tends to intrude into the southern mid-latitudes.Accordingly,three strong signals travel synchronously along the circumSouth-Pacific path,and a relatively weak signal extends eastward and poleward over the South Ocean in the Atlantic-Indian Ocean sector.Following the propagation of these signals,the AAO phase tends to be reversed progressively.As a result,there exists an evident lead-lag correlation between CTI and AAOI.It can be concluded that ENSO plays a key role in the phase transition of AAO at the QQ timescale.It is also noticed that this regular relationship is only evident in the canonical ENSO events,for which sea surface temperature (SST) anomalies extend westward from the tropical eastern Pacific.On the other hand,the similar relationships are not found among those atypical ENSO events for which SST anomalies spread eastward from the central Pacific,such as the 1982-1983 ENSO event.     

Primary cracking of kerogens. Experimenting and modelling C1, C2–C5, C6–C15 and C15+ classes of hydrocarbons formed

Mathematical models of hydrocarbon formation can be used to simulate the natural evolution of different types of organic matter and to make an overall calculation of the amounts of oil and/or gas produced during this evolution. However, such models do not provide any information on the composition of the hydrocarbons formed or on how they evolve during catagenesis.From the kinetic standpoint, the composition of the hydrocarbons formed can be considered to result from the effect of “primary cracking” reactions having a direct effect on kerogen during its evolution as well as from the effect of “secondary cracking” acting on the hydrocarbons formed.This report gives experimental results concerning the “primary cracking” of Types II and III kerogens and their modelling. For this, the hydrocarbons produced have been grouped into four classes (C₁, C₂–C₅, C₆–C₁₅ and C₁₅₊). Experimental data corresponding to these different classes were obtained by the pyrolysis of kerogens with temperature programming of 4°C/min with continuous analysis, during heating, of the amount of hydrocarbons corresponding to each of these classes.The kinetic parameters of the model were optimized on the basis of the results obtained. This model represents the first step in the creation of a more sophisticated mathematical model to be capable of simulating the formation of different hydrocarbon classes during the thermal history of sediments. The second step being the adjustment of the kinetic parameters of “secondary cracking”.     

热流测量中垂向地下水运动干扰的校正方法

本文提出了一种地表热流测量中垂向地下水干扰的校正方法。并以江西萍乡和福建安溪的二个钻孔为例,说明了热流校正的具体过程。由于地下水对流传热的影响,垂向地下水渗透层内温度和热流随深度均呈指数分布。通过对钻孔测温数据的一维垂向Peclet数分析,可以确定渗透层内传导和对流热流分量以及热流的构成,从而得到未受地下水对流干扰的区域背景热流。这一方法不仅适用于渗透率结构均一的介质,也可用于水平层状介质。     

小良试验站三种植被类型地表径流效应的对比研究

本文分析研究了３种植被类型下的地表径流在汇流、洪峰及径流过程上的特征，差异是巨大的。在径流过程上桉树林和裸地的变地剧烈，几乎没有什么调蓄作用，洪峰流量占一次性降水径流量的绝大部分，涨水和退水流量都较小。本文应用灰色系统ＧＭ（２，１）模型，成功地预测了以年和以月为时间尺度的地表径流序列，其预测模型可以用来对这些时间尺度的地表径流进行预报。     

云南蒙自五里冲水库区F1,F2断层新活动年代研究

五里冲水库地处侵蚀山区,缺乏第四纪地层作为研究断层新活动年代的对比标志。本文以F_1、F_2断层带内发育的多期方解石脉和断层泥为研究对象,采用显微构造分析,热释光(TL)测年法和扫描电镜(SEM)分析,石英溶蚀速率测年法,对库区F_1、F_2断层新活动的年代进行综合判定。确认:F_1、F_2断层最后一次明显活动的年代分别为(2.93±0.31)×10~5年和(2.33±0.26)×10~5年以前,为评估五里冲水库构造稳定性,提供了可靠的数据。     

数字成象系统调制传递函数的测定及应用

本文首次探讨了数字成象系统调制传递函数的测定方法及应用。试验结果表明:该测定方法不仅合理可行,而且强有力地证明了MTF的应用价值。即不仅用于象质的评价,而且为成象系统的检定和调试提供了新的技术手段。     

银催化HDEA电化学发光法测定矿样中的痕量银

在碱性介质中,痕量Ag(Ⅰ)对新试剂6-(2-羟基-4-二乙基氨苯偶氮)-2,3-二氢-1,4-酞嗪二酮(简称HDEA)的电化学发光具有显著的催化作用。基于此,提出了HDEA-KCI-KOH体系测定矿样中痕量Ag的新方法。方法的检测限为2.0×10~(-8)mol/L Ag,线性范围为5.0×10~(-8)—3.0×10~(-6)mol/L Ag。采用巯基棉富集分离,应用本法测定一些矿样中的Ag,结果良好。     

Location of Tibetan earthquakes──a nonlinear approach by a simplex optimized technique

Ｌｏｃａｔｉｏｎ　ｏｆ　Ｔｉｂｅｔａｎ　ｅａｒｔｈｑｕａｋｅｓ──ａ　ｎｏｎｌｉｎｅａｒ　ａｐｐｒｏａｃｈ　ｂｙ　ａ　ｓｉｍｐｌｅｘ　ｏｐｔｉｍｉｚｅｄ　ｔｅｃｈｎｉｑｕｅ（赵珠）（丁志峰）（易桂喜／）（王建格）ＬｏｃａｔｉｏｎｏｆＴｉｂｅｔａｎｅａ...     

莺－琼盆地YA13－1气田热流体活动与有机／无机成岩响应

根据钻井中途测试（ＤＳＴ）、重复地层测试（ＲＦＴ）、镜质体反射率（Ｒ０）、流体包裹体分析和粘土矿物Ｘ射线衍射全定量分析等综合研究发现，莺－琼盆地ＹＡ１３－１气田存在４期热流体活动；南侧的崖南地区和西侧的莺歌海盆地是其两个重要的热流体物质源和动力源；多期热流体活动在ＹＡ１３－１地区不仅造成热异常和物质迁移，而且还引起了不同的有机／无机成岩响应，如骨架颗粒的多期溶蚀作用、至少两期的次生加大作用、粘土矿物转化和有机质热成熟作用异常。第二、第三期热流体因出溶作用形成ＹＡ１３－１气田大规模的天然气聚集。