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61.
在30kbar和900℃条件下,用等化学计量氧化物混合物合成了11个斜方辉石系列的样品,并对合成的样品进行了X射线粉晶分析和红外光谱分析。分析结果表明,晶胞参数和红外光谱随化学成分的改变而产生复杂的变化。不仅晶胞参数b和M而且频率ν_(670cm)-1和M之间存在很好的线性相关关系,通过用最小二乘法所拟合的相关方程可容易地测定斜方辉石的成分,但是α和c与M之间只有较差的线性关系,而ν_(450cm)-1和M以及ν_(380cm)-1和M之间并无简单的线性相关关系,这可归因于Fe~(2+)在M_1和M_2位置的有序分布。 相似文献
62.
Hsueh-Yu Lu 《Environmental Geology》2007,51(6):1029-1041
A new method has been developed to estimate the hydraulic conductivity in unconsolidated aquifers. The method uses bulk geochemical
compositions correlated with hydraulic conductivities measured by pumping tests. The concept is based on a general rule that
hydraulic conductivity is principally controlled by grain-size distribution and particle shape,both of which relate to mineralogical
composition. Using a MINLITH algorithm, normative mineralogical compositions can be derived from bulk geochemical compositions
economically and expediently, and then correlated to the hydraulic conductivity determined by pumping tests in the field.
In this study, 202 sediment samples from nine unconsolidated aquifers were analyzed by X-ray fluorescence. Although hydraulic
conductivity does not show a definite relationship with geochemical compositions, it does demonstrate a linear logarithmic
equation to the content of normative earthy minerals. However, linear regressed equations should not be applied to aquifers
composed of medium to coarse sand and gravel sizes due to interference from lithic fragments. In addition, this equation tends
to overestimate hydraulic conductivity possibly because the effect of compaction is ignored in this study. 相似文献
63.
64.
Technical difficulties associated with excavation works in tectonized geological settings are frequent. They comprise instantaneous
and/or delayed convergence, sudden collapse of gallery roof and/or walls, outpouring of fault-filling materials and water
inflows. These phenomena have a negative impact on construction sites and their safety. In order to optimize project success,
preliminary studies on the reliability of rock material found on site are needed. This implies in situ investigations (surface
mapping, prospective drilling, waterflow survey, etc.) as well as laboratory investigations on rock samples (permeability
determination, moisture and water content, mineralogy, petrography, geochemistry, mechanical deformation tests, etc.). A set
of multiple parameters are then recorded which permit better insight on site conditions and probable behavior during excavation.
Because rock formations are by nature heterogeneous, many uncertainties remain when extrapolating large-scale behavior of
the rock mass from analyses of samples order of magnitudes smaller. Indirect large-scale field investigations (e.g. geophysical
prospecting) could help to better constrain the relationships between lithologies at depth. At a much smaller scale, indirect
analytical methods are becoming more widely used for material investigations. We discuss in this paper X-ray computed tomography
(XRCT) and neutron tomography (NT), showing promising results for 3D petrographical investigations of the internal structure
of opaque materials. Both techniques record contrasts inside a sample, which can be interpreted and quantified in terms of
heterogeneity. This approach has the advantage of combining genetic parameters (physico-chemical rock composition) with geometric
parameters resulting from alteration or deformation processes (texture and structure). A critical analysis of such 3D analyses
together with the results of mechanical tests could improve predictions of short- and long-term behavior of a rock unit. Indirect
methods have the advantage of being non-destructive. However, as it is the case with large-scale geophysical surveying, XRCT
and NT are affected by several error factors inherent to the interaction of a radiation modality (X-ray or neutron beam) with
the atomic structure of the investigated materials. Recorded signals are therefore in particular cases not artifact-free and
need to be corrected in a subsequent stage of data processing. 相似文献
65.
We report on the use of X-ray diffractometry under controlled conditions of temperature and relative humidity (RH-XRD) for
the investigation of NaCl deliquescence in the pore space of glass filter frits, which were used as model substrates. The
study confirms that RH-XRD is an appropriate experimental technique for the in situ observation of phase transformation in
porous materials. It is used for an investigation of both the deliquescence kinetics and the deliquescence humidity within
pores of different median pore diameter. Several major influences affecting deliquescence rates in the pore space close to
the surface of a porous material are discussed. It appears that quite short-term variation of ambient relative humidity, e.g.,
typical daily fluctuations, might induce damaging deliquescence–crystallization cycles within the pore space of building materials.
In agreement with theoretical considerations it was found that confinement of NaCl crystals in pores with median diameters
in the range 1.4–70 μm does not affect the deliquescence humidity of the salt. 相似文献
66.
A. Foubert D. Van Rooij D. Blamart J.-P. Henriet 《International Journal of Earth Sciences》2007,96(1):141-158
Three provinces, characterized by the presence of carbonate mounds interpreted as cold-water coral banks have been reported
in Porcupine Seabight, SW of Ireland and were recently subjected to many detailed studies. This contribution discusses the
use of X-ray imagery and physical properties in deciphering palaeoceanographic, sedimentological and biological processes.
Physical property core logging and X-ray imagery are used to identify and describe sedimentation regimes and so their respective
palaeoceanographic and palaeoclimatological settings in two mound provinces, respectively the Belgica mound province and the
Magellan mound province. Both provinces show at present time clear differences in the hydrodynamic environment. This study
confirms that also during the past the oceanographic and sedimentological environment of both provinces differ clearly. Impacts
of glacial–interglacial variations and locally derived ice rafting events (IRE), comparable with the North Atlantic Heinrich
events (HE) have been recognized in both provinces. Moreover, the combination of X-ray imagery, magnetic susceptibility, gamma
density and P-wave velocity makes it possible to estimate the coral content and coral distribution in unopened cores localized
on top of carbonate mounds. A comparison between on-mound and off-mound cores in both provinces allowed revealing some mechanisms
of mound evolution and coral growth versus time. 相似文献
67.
Li Guowu Shi Nicheng Xiong Ming Ma Zhesheng Bai Wenji Fang Qingsong 《Frontiers of Earth Science》2007,1(1):21-25
The origin of native Si-Fe alloy mineral is thought to be related with mantle and aerolite. The native Si-Fe alloy minerals
from podiform chromites of the Luobusha ophiolite in the Yarlong Zangbo suture zone were examined by a new method for powder-like
diffractograms of small single crystals, using an SMART APEX-CCD area-detector X-ray diffractometer. The powder diffraction
pattern shows that the minerals are composed of FeSi, FeSi2, β-FeSi2 and native silicon. The association of these minerals suggests that the crystallization order of the mineral may be from
early to late FeSi→FeSi2→native silicon, accompanied by gradually increasing deoxidization.
Translated from Acta Petrologica et Mineralogica, 2005, 24(5): 453–456 [译自: 岩石矿物学杂志] 相似文献
68.
Three resection–intersection algorithms were applied to simulated projections and clinical data from radiostereometric patients. On simulated data, the more advanced bundle-adjustment-based algorithms outperformed the classical Selvik algorithm, even if the error reductions were small for some parameters. On clinical data, the results were inconclusive.The two different projection geometries had a much larger influence on the error size and distribution. For the biplanar configuration, the position and motion errors were small and almost isotropic. For the uniplanar configuration, the position errors were comparably high and anisotropic, but still resulted in a high accuracy for some motion parameters at the expense of others.The simplified resection–intersection algorithm by Selvik may still be considered a good and robust algorithm for radiostereometry. More studies will have to be performed to find out how the theoretical advantages of the bundle methods can be utilized in clinical radiostereometry. 相似文献
69.
目的旨在提高肺结核开放-菌阴综合征的诊断和鉴别诊断,材料和方法用回顾性分析经病原学或临床确诊的开放型肺结核,而痰菌阴性的42例病人的CT影像表现。结果得到42例均见斑片状高密度灶影,其中41例不规则空洞影,4例与支气管相通;28例卫星灶影,8例纤维索条影,1例仅见小斑片状影伴卫星灶影,10例见斑点状钙化影,2例淋巴结肿大等。结论是CT对肺结核开放-菌阴综合征的诊断和鉴别诊断有较高的价值,特别是对估价空洞的形态结构,心后区,脊柱旁,后肋隔区,与肺门阴影重叠的病及少量胸腔积液等方面更有价值,对诊断和疗效的观察较可靠。 相似文献
70.