微波等离子体原子发射光谱法测定偏远矿区海泡石中的主微量元素

海泡石是具有层状结构的含水富镁硅酸盐黏土矿物,其中无机元素含量是揭示其成矿物质来源、成矿流体性质和矿床成因的重要依据,通常采用电感耦合等离子体发射光谱/质谱法(ICP-OES/MS)进行测定,等离子体(ICP)的高温激发会产生成大量谱线干扰,维持ICP稳定工作需使用高纯氩气,持续供气对于偏远矿区海泡石的检测还将面对气体采购和运输不便的问题。本文基于微波等离子体原子发射光谱(MP-AES)的低温激发技术减少光谱干扰,建立了准确测定偏远矿区海泡石中主量元素Mg、Al、Ca、Fe、K、Na和微量元素Cu、Zn、Mn、Pb含量的分析方法。利用硝酸-盐酸-氢氟酸混合酸对海泡石进行微波消解,避免了样品处理过程中分析元素的损失,加快了样品处理速度,同时提高了样品溶液的稳定性。通过选择各元素光谱线的分析波长,并利用快速线性干扰校正(FLIC)技术校正光谱干扰,以Lu为内标元素校正基体效应,提高了灵敏度和准确度。各元素的检出限为0.19～14.6μg/L。海泡石国家标准物质(GBW07138)各元素测定值与认定值的相对误差在-5.0%～6.7%之间。本方法具有检出限低、线性范围宽、结果准确等优点;MP-AES采用自带的氮气发生器为等离子体提供氮气作为工作气,无需引入复杂气体,提高了分析效率,尤其适用于气体采购和运输不便的偏远矿区。     

土壤粒径的光谱响应特性研究

以实验室制备的5个不同粒径水平的土壤样本和室内高光谱数据为基础,通过对光谱数据进行重采样、数学变换等预处理并进行单因素方差分析、相关性分析和回归分析,探讨土壤粒径的高光谱特性,建立了光谱数据预测土壤粒径的校正模型。结果表明,土壤粒径对反射光谱有显著的影响,波长越长影响越大;在全波段范围内土壤粒径和光谱数据都呈负相关关系,对原始光谱数据进行微分变换能增加其与土壤粒径的相关性;以反射率一阶微分建立的回归模型为反演土壤粒径的最佳模型,其建模决定系数■、预测决定系数■、预测相对偏差RPD分别为0.666,0.653,2.043,预测均方根误差RMSE为0.175。     

Retrieving volume FeO and TiO_2 abundances of lunar regolith with CE-2 CELMS data using BPNN method

The volume FeO and TiO_2 abundances(FTAs) of lunar regolith can be more important for understanding the geological evolution of the Moon compared to the optical and gamma-ray results. In this paper, the volume FTAs are retrieved with microwave sounder(CELMS) data from the Chang'E-2 satellite using the back propagation neural network(BPNN) method. Firstly, a three-layered BPNN network with five-dimensional input is constructed by taking nonlinearity into account. Then, the brightness temperature(TB) and surface slope are set as the inputs and the volume FTAs are set as the outputs of the BPNN network.Thereafter, the BPNN network is trained with the corresponding parameters collected from Apollo, Luna,and Surveyor missions. Finally, the volume FTAs are retrieved with the trained BPNN network using the four-channel TBderived from the CELMS data and the surface slope estimated from Lunar Orbiter Laser Altimeter(LOLA) data. The rationality of the retrieved FTAs is verified by comparing with the Clementine UV-VIS results and Lunar Prospector(LP) GRS results. The retrieved volume FTAs enable us to re-evaluate the geological features of the lunar surface. Several important results are as follows. Firstly, very-low-Ti(<1.5 wt.%) basalts are the most spatially abundant, and the surfaces with TiO_2> 5 wt.% constitute less than 10% of the maria. Also, two linear relationships occur between the FeO abundance(FA) and the TiO_2 abundance before and after the threshold, 16 wt.% for FA. Secondly, a new perspective on mare volcanism is derived with the volume FTAs in several important mare basins, although this conclusion should be verified with more sources of data. Thirdly, FTAs in the lunar regolith change with depth to the uppermost surface,and the change is complex over the lunar surface. Finally, the distribution of volume FTAs hints that the highlands crust is probably homogeneous, at least in terms of the microwave thermophysical parameters.     

东昆仑造山带海德乌拉铀矿床成矿流体特征研究

东昆仑造山带海德乌拉铀矿床是近些年西北地区最新探明的与火山岩有关的独立铀矿床,该矿床的发现为东昆仑造山带探寻热液型铀矿床提供了指示意义。本文选择与海德乌拉铀矿成矿期相关的透明矿物（粉红色方解石、紫黑色萤石及石英）作为研究对象,系统地开展C- H- O同位素和流体包裹体研究,查明该矿床成矿流体的来源与性质,并探讨矿床成因。研究结果表明,海德乌拉铀矿床成矿期石英中主要为H2O气液两相包裹体,少见CO2- H2O两相包裹体;在粉红色方解石脉、紫黑色萤石脉中流体包裹体均含H2O气液两相包裹体,在粉红色方解石脉中偶见纯液相包裹体,均未见到纯气相及含固相包裹体。成矿期粉红色方解石、紫黑色萤石及石英中包裹体均一温度范围分别为133~187℃（均值163℃）、127~204℃（均值169℃）、183~287℃（均值219℃）,盐度范围分别为1. 40%~7. 02%NaCleq（均值3. 65%NaCleq）、0. 53%~3. 06%NaCleq（均值1. 26%NaCleq）、7. 17%~17. 26%NaCleq（均值为11. 46%NaCleq）。流体包裹体气相成分以H2O为主,另含少量CO2等。C- H- O同位素实验数据表明,流体中δ13CFluid- V- PDB、δDFluid- V- SMOW、δ18OFluid- V- SMOW值的变化范围分别为1. 59‰~1. 00‰、71‰~63‰、0. 03‰~3. 72‰,表明成矿流体并非单一来源,可能为大气降水与岩浆水混合来源。此外,沥青铀矿的沉淀主要是由于流体与围岩的相互反应所引起的物理化学条件变化加上流体沸腾/CO2去气,最终导致了沥青铀矿等成矿物质发生大规模的卸载与沉淀。     

河南产宝石级高温高压合成钻石的谱学特征及电磁性研究

为快速鉴定高温高压(HPHT)合成钻石,前人已开展了系统的发光特征和谱学特征研究,但对比性分析较少,且对电学性质和磁学性质关注不多.本文结合常规宝石学观察、高精度谱学测试以及导电性和磁性测试,对49粒无色、黄色样品进行了深入研究和对比分析.结果表明:①铁、钴、镍等金属元素的触媒残余是HPHT合成钻石的磁性来源,测试样品...     

双因素判别分析胃癌组织与正常组织自体荧光光谱

通过对手术切除的37例胃癌患者的离体标本的自体荧光光谱检测,显示308nm,337nm激发光谱均呈双主峰结构,双主峰的比值均能区分胃癌与正常胃壁(P<0.001).分别用308nm,337nm激发荧光光谱单因素分析诊断胃癌的灵敏度、特异度、阳性预测值分别为88.8%,86.8%,86.4%和80.1%,72.1%,67.5%.对308nm及337nm激发荧光光谱双因素分析,癌诊断的灵敏度、特异度、阳性预测值分别为94.4%,92.1%,91.9%,其诊断正确符合率明显高于单因素分析的结果.研究表明,以308nm及337nm双波长激发检测胃壁浆膜,双因素判别算法可较好地区分胃癌,这种方法有望成为手术中快速识别胃癌在胃壁的浸润范围的有效方法.     

高浓度气体共振光声光谱信号饱和特性研究

采用恒流驱动耦合机械斩波技术在激光光声光谱装置上系统测量了5%—100%宽浓度范围甲烷气体的共振光声信号,发现在高浓度区共振光声信号呈现异常的饱和特征.基于气体吸收和光声光谱原理定量分析了光声信号饱和的主要原因及影响因素,研究表明,气体样本对入射光强吸收而导致的声源与本征共振模式的耦合系数改变是异常饱和的主要原因,并导出判定光声信号饱和深度的准则以用于判定高浓度气体饱和深度.     

基于阈值光电子-光离子符合技术的分子离子光谱和解离动力学研究

对电子和离子同时采用速度聚焦电场收集的阈值光电子-光离子符合成像谱仪能够有效提高电子的收集效率和能量分辨率.利用该符合成像谱仪,开展了Xe/Ar/Ne 惰性混合气体及NO 分子的阈值光电子谱、阈值光电子-光离子符合质谱和质量选择的符合光谱等实验研究,精确测量了NO 分子的电离势,并且获得了NO⁺离子振动态分辨的X¹Σ⁺,c³Π和B¹Π态光谱.还进一步研究了NO^{+ 相似文献}   

Coherent spectroscopy of a strongly driven triple quantum dot molecule

Based on a calculation model, we study the interference phenomena of serially coupled V-type and Λ-type triple quantum dots (CTQDs) driven simultaneously by a strong driving field and a weak probe field. Strongly depending on the configuration of the three-level CTQD, the probe absorption spectra, which are shown in the tunneling current, exhibit various quantum coherence properties. In the case where the two pairs of transitions of the CTQD have a small eigenfrequency difference Δω, the double-coupling effect of the driving field results in two Autler-Townes doublets and one weak Mollow triplet in one spectrum. With the value of Δω increasing, only one Autler-Townes splitting remains due to the single-coupling of the field. We also find that the effect of spontaneous emission of phonons may lead to an obvious background current, which can be used to distinguish which transition is driven by the driving field in experiment. The interesting quantum property of a CTQD revealed in our results suggests its potential applications in quantum modulators and quantum logic devices.     

Multivariate analysis of fluorescence and source identification of dissolved organic matter in Jiaozhou Bay, China

Hierarchical clustering analysis and principal component analysis (PCA) methods were used to assess the similarities and dissimilarities of the entire Excitation-emission matrix spectroscopy (EEMs) data sets of samples collected from Jiaozhou Bay, China. The results demonstrate that multivariate analysis facilitates the complex data treatment and spectral sorting processes, and also enhances the probability to reveal otherwise hidden information concerning the chemical characteristics of the dissolved organic matter (DOM). The distribution of different water samples as revealed by multivariate results has been used to track the movement of DOM material in the study area, and the interpretation is supported by the results obtained from the numerical simulation model of substance tracing technique, which show that the substance discharged by Haibo River can be distributed in Jiaozhou Bay.