The C1XS X-ray Spectrometer on Chandrayaan-1

The Chandrayaan-1 X-ray Spectrometer (C1XS) is a compact X-ray spectrometer for the Indian Space Research Organisation (ISRO) Chandrayaan-1 lunar mission. It exploits heritage from the D-CIXS instrument on ESA's SMART-1 mission. As a result of detailed developments to all aspects of the design, its performance as measured in the laboratory greatly surpasses that of D-CIXS. In comparison with SMART-1, Chandrayaan-1 is a science-oriented rather than a technology mission, leading to far more favourable conditions for science measurements. C1XS is designed to measure absolute and relative abundances of major rock-forming elements (principally Mg, Al, Si, Ca and Fe) in the lunar crust with spatial resolution ?25 FWHM km, and to achieve relative elemental abundances of better than 10%.     

Diamonds from placers in western and central Africa: A problem of primary sources

This paper discusses diamonds and their accessory minerals from the Koidu kimberlites, placers on the Bafit River in Sierra Leone, and Chikapa placers in the Democratic Republic of Congo. Minerals from the placers are characterized by fine preservation and bear no evidence of long-term transportation. In placers, garnet, ilmenite and zircon have been found, but the specific features of their chemical composition do not coincide with those of minerals from kimberlites. Diamonds from the placers are of a mantle origin, but they have no direct analogs in the known kimberlite and lamproite pipes.     

Confocal laser scanning microscopy and Raman imagery of ancient microscopic fossils

Among all problems confronting the study of ancient permineralized (petrified) microscopic fossils, two stand out, the need for (1) accurate documentation of their three-dimensional morphology, and (2) direct analysis of their chemical composition and that of their surrounding mineral matrices. To address these problems we demonstrate the use of two techniques that we have recently introduced to Precambrian paleobiology: confocal laser scanning microscopy and Raman imagery. These techniques, both of which are non-intrusive and non-destructive, can provide data by which to characterize, in situ and at micron-scale resolution, the cellular and organismal morphology of thin section-embedded organic-walled fossils. In addition, Raman imagery provides direct analyses of the molecular–structural composition of the kerogenous components of such fossils and of their surrounding matrices, and a means to assess quantitatively the geochemical maturity of the preserved organics. Use of these techniques for studies of ancient microscopic fossils can provide information in three dimensions at high spatial resolution about their morphology and cellular anatomy, taphonomy and fidelity of preservation, composition and mode of preservation, and their biogenicity and syngenetic origin with the rocks in which they occur.     

Breakdown of hydrous ringwoodite to pyroxene and spinelloid at high P and T and oxidizing conditions

To get deeper insight into the phase relations in the end-member system Fe₂SiO₄ and in the system (Fe, Mg)₂SiO₄ experiments were performed in a multi-anvil apparatus at 7 and 13 GPa and 1,000–1,200°C as a function of oxygen fugacity. The oxygen fugacity was varied using the solid oxygen buffer systems Fe/FeO, quartz–fayalite–magnetite, MtW and Ni/NiO. The run products were characterized by electron microprobe, Raman- and FTIR-spectroscopy, X-ray powder diffraction and transmission electron microscopy. At fO₂ corresponding to Ni/NiO Fe-ringwoodite transforms to ferrosilite and spinelloid according to the reaction: 9 Fe₂SiO₄ + O₂ = 6 FeSiO₃ + 5 Fe_2.40Si_0.60O₄. Refinement of site occupancies in combination with stoichiometric Fe³⁺ calculations show that 32% of the total Fe is incorporated as Fe³⁺ according to From the Rietveld refinement we identified spl as spinelloid III (isostructural with wadsleyite) and/or spinelloid V. As we used water in excess in the experiments the run products were also analyzed for structural water incorporation. Adding Mg to the system increases the stability field of ringwoodite to higher oxygen fugacity and the spinel structure seems to accept higher Fe³⁺ but also water concentrations that may be linked. At oxygen fugacity corresponding to MtW conditions similar phase relations in respect to the breakdown reaction in the Fe-end-member system were observed but with a strong fractionation of Fe into spl and Mg into coexisting cpx. Thus, through this strong fractionation it is possible to stabilize very Fe-rich wadsleyite with considerable Fe³⁺ concentrations even at an intermediate Fe–Mg bulk composition: assuming constant K _D independent on composition and a bulk composition of x _Fe = 0.44 this fractionation would stabilize spl with x _Fe = 0.72. Thus, spl could be a potential Fe³⁺ bearing phase at P–T conditions of the transition zone but because of the oxidizing conditions and the Fe-rich bulk composition needed one would expect it more in subduction zone environments than in the transition zone in senso stricto.

The Atacama Large Millimeter/Submillimeter Array: overview & status

The Atacama Large Millimeter/Submillimeter Array (ALMA) is an international millimeter-wavelength radio telescope under construction in the Atacama Desert of northern Chile. ALMA will be situated on a high-altitude site at 5000 m elevation which provides excellent atmospheric transmission over the instrument wavelength range of 0.3 to 3 mm. ALMA will be comprised of two key observing components—a main array of up to sixty-four 12-m diameter antennas arranged in a multiple configurations ranging in size from 0.15 to ∼18 km, and a set of four 12-m and twelve 7-m antennas operating in a compact array ∼50 m in diameter (known as the Atacama Compact Array, or ACA), providing both interferometric and total-power astronomical information. High-sensitivity dual-polarization 8 GHz-bandwidth spectral-line and continuum measurements between all antennas will be available from two flexible digital correlators. At the shortest planned wavelength and largest configuration, the angular resolution of ALMA will be 0.005″. The instrument will use superconducting (SIS) mixers to provide the lowest possible receiver noise contribution, and special-purpose water vapor radiometers to assist in calibration of atmospheric phase distortions. A complex optical fiber network will transmit the digitized astronomical signals from the antennas to the correlators in the Array Operations Site Technical Building, and post-correlation to the lower-altitude Operations Support Facility where the array will be controlled, and initial construction and maintenance of the instrument will occur. ALMA Regional Centers in the US, Europe, Japan and Chile will provide the scientific portals for the use of ALMA; early science observations are expected in 2010, with full operations in 2012.     

High-mass star forming regions: An ALMA view

The advent of ALMA is bound to improve our knowledge of OB star formation dramatically. Here, we present an overview of this topic outlining how high angular resolution and sensitivity may contribute to shed light on the structure of high-mass star forming regions and hence on the process itself of massive star formation. The impact of this new generation instrument will range from establishing the mass function of pre-stellar cores inside IR-dark clouds, to investigating the kinematics of the gas from which OB stars are built up, to assessing or ruling out the existence of circumstellar accretion disks in these objects.     

Ultraviolet observations of Phoebe from the Cassini UVIS

Observations of Saturn's distant moon Phoebe were made at far-ultraviolet (FUV) (1100-1900 Å) and extreme-ultraviolet (EUV) (600-1100 Å) wavelengths by the Cassini Ultraviolet Imaging Spectrograph (UVIS) during the Cassini spacecraft flyby on June 11, 2004. These are the first UV spectra of Phoebe and the first detection of water ice on a Solar System surface using FUV wavelengths. The characteristics of water ice in the FUV are presented, and Hapke models are used to interpret the spectra in terms of composition and grain size; the use of both areal and intimate mixing models is explored. Non-ice species used in these models include carbon, ice tholin, Triton tholin, poly-HCN and kerogen. Satisfactory disk-integrated fits are obtained for intimate mixtures of ∼10% H₂O plus a non-ice species. Spatially resolved regions of higher (∼20%) and lower (∼5%) H₂O ice concentrations are also detected. Phoebe does not display any evidence of volatile activity. Upper limits on atomic oxygen and carbon are 5×¹⁰¹¹ and 2×¹⁰¹² atoms/cm², respectively, for solar photon scattering. The UVIS detection of water ice on Phoebe, and the ice amounts detected, are consistent with IR measurements and contribute to the evidence for a Phoebe origin in the outer Solar System rather than in the main asteroid belt.     

The albedo dichotomy of Iapetus measured at UV wavelengths

The dramatic hemispheric dichotomy in albedo displayed by Saturn's moon Iapetus has intrigued astronomers for centuries. Here we report on far-ultraviolet observations of Iapetus' bright and dark terrains from Cassini. We compare the reflectance spectra of Iapetus's dark terrain, Hyperion and Phoebe and find that both Phoebe and Hyperion are richer in water ice than Iapetus' dark terrain. Spectra of the lowest latitudes of the dark terrain display the diagnostic water ice absorption feature; water ice amounts increase within the dark material away from the apex (at 90° W longitude, the center of the dark leading hemisphere), consistent with thermal segregation of water ice. The water ice in the darkest, warmest low latitude regions is not expected to be stable and may be a sign of ongoing or recent emplacement of the dark material from an exogenic source.     

Carbon dioxide segregation in 1:4 and 1:9 CO2:H2O ices

The mid-infrared spectra of mixed vapor deposited ices of CO₂ and H₂O were studied as a function of both deposition temperature and warming from 15 to 100 K. The spectra of ices deposited at 15 K show marked changes on warming beginning at 60 K. These changes are consistent with CO₂ segregating within the ice matrix into pure CO₂ domains. Ices deposited at 60 and 70 K show a greater degree of segregation, as high as 90% for 1:4 CO₂:H₂O ice mixtures deposited at 70 K. As the ice is warmed above 80 K, preferential sublimation of the segregated CO₂ is observed. The kinetics of the segregation process is also examined. The segregation of the CO₂ as the ice is warmed corresponds to temperatures at which the structure of the water ice matrix changes from the high density amorphous phase to the low density amorphous phase. We show how these microstructural changes in the ice have a profound effect on the photochemistry induced by ultraviolet irradiation. These experimental results provide a framework in which observations of CO₂ on the icy bodies of the outer Solar System can be considered.