Untersuchung der Sorptionseigenschaften des Kationenaustauschers KB-2M mit Makronetzstruktur zur Abtrennung von Zinkionen aus Ab- und Spülwässern

Study of Sorptional Properties of the Cation Exchanger KB-2M with Macroreticular Structure for Recovery of Zinc Ions from Sewage and Rinsing Water Although a number of ion-exchange methods have been employed for the recovery of some transition metals from industrial effluents, knowledge about ion-exchange resins with macroreticular structure is poor. The present paper describes the mechanism of sorption on such exchangers and their application for recovery of zinc from sewage rinsing water. Ion exchanger of macroreticular structure are polymers with long-chained cross-linking agents. We have synthesized carboxylic ion-exchange resins by hydrolysis of copolymerisates of methyl acrylate with different cross-linking agents: divinylbenzene, divinyl sulfide, divinyl ester of ethylene glycol and divinyl ester of di- or triethylene glycol. The sorption process on modifications of the carboxylic resins KB-2 of various structure was studied with different methods: potentiometric titration, infrared spectroscopy, electron microscopy, X-ray structural analysis. The initial zinc concentration in rinsing water was 0.05 mol/L at pH from 3 to 6. For the sorption, 0.2…1.0 g of resin were equilibrated with 100 mL of zinc solution. After equilibrium (12 h), the resin was separated from solution. The zinc ions were determined by atomic absorption spectrometry after stripping with 100 mL of 10% sulfuric acid. The distribution ratio D was calculated (D: mmole of Zn sorbed per gram of resin divided by mmole of Zn per millilitre of solution). By means of infrared spectroscopy, the mechanism of sorption of zinc ions from rinsing water was determined. There may be a possibility of the formation of complexes in the cation-exchange resin phase. It was found out in this paper that the cation-exchanger KB-2M of macroreticular structure is the most effective for the sorption of the Zn²⁺-ions from sewage and rinsing water.     

Current states of stress in the northern Andes as indicated by focal mechanisms of earthquakes

Systematic inversion of double couple focal mechanisms of shallow earthquakes in the northern Andes reveals relatively homogeneous patterns of crustal stress in three main regions. The first region, presently under the influence of the Caribbean plate, includes the northern segment of the Eastern Cordillera of Colombia and the western flank of the Central Cordillera (north of 4°N). It is characterized by WNW–ESE compression of dominantly reverse type that deflects to NW–SE in the Merida Andes of Venezuela, where it becomes mainly strike–slip in type. A major bend of the Eastern thrust front of the Eastern Cordillera, near its junction with the Merida Andes, coincides with a local deflection of the stress regime (SW–NE compression), suggesting local accommodation of the thrust belt to a rigid indenter in this area. The second region includes the SW Pacific coast of Colombia and Ecuador, currently under the influence of the Nazca plate. In this area, approximately E–W compression is mainly reverse in type. It deflects to WSW–ENE in the northern Andes south of 4°N, where it is accommodated by right-lateral displacement of the Romeral fault complex and the Eastern front of the northern Andes. The third, and most complex, region is the area of the triple junction between the South American, Nazca and Caribbean plates. It reveals two major stress regimes, both mainly strike–slip in type. The first regime involves SW–NE compression related to the interaction between the Nazca and Caribbean plates and the Panama micro-plate, typically accommodated in an E–W left-lateral shear zone. The second regime involves NW–SE compression, mainly related to the interaction between the Caribbean plate and the North Andes block which induces left-lateral displacement on the Uramita and Romeral faults north of 4°N.Deep seismicity (about 150–170 km) concentrates in the Bucaramanga nest and Cauca Valley areas. The inversion reveals a rather homogeneous attitude of the minimum stress axis, which dips towards the E. This extension is consistent with the present plunge of the Nazca and Caribbean slabs, suggesting that a broken slab may be torn under gravitational stresses in the Bucaramanga nest. This model is compatible with current blocking of the subduction in the western northern Andes, inhibiting the eastward displacement of slabs, which are forced to break and sink in to the asthenosphere under their own weight.     

The Okavango giant mafic dyke swarm (NE Botswana): its structural significance within the Karoo Large Igneous Province

The structural organization of a giant mafic dyke swarm, the Okavango complex, in the northern Karoo Large Igneous Province (LIP) of NE Botswana is detailed. This N110°E-oriented dyke swarm extends for 1500 km with a maximum width of 100 km through Archaean basement terranes and Permo-Jurassic sedimentary sequences. The cornerstone of the study is the quantitative analysis of N>170 (exposed) and N>420 (detected by ground magnetics) dykes evidenced on a ca. 80-km-long section lying in crystalline host-rocks, at high-angle to the densest zone of the swarm (Shashe area). Individual dykes are generally sub-vertical and parallel to the entire swarm. Statistical analysis of width data indicates anomalous dyke frequency (few data <5.0 m) and mean dyke thickness (high value of 17 m) with respect to values classically obtained from other giant swarms. Variations of mean dyke thicknesses from 17 (N110°E swarm) to 27 m (adjoining and coeval N70°E giant swarm) are assigned to the conditions hosting fracture networks dilated as either shear or pure extensional structures, respectively, in response to an inferred NNW–SSE extension. Both fracture patterns are regarded as inherited brittle basement fabrics associated with a previous (Proterozoic) dyking event. The Okavango N110°E dyke swarm is thus a polyphase intrusive system in which total dilation caused by Karoo dykes (estimated frequency of 87%) is 12.2% (6315 m of cumulative dyke width) throughout the 52-km-long projected Shashe section. Assuming that Karoo mafic dyke swarms in NE Botswana follow inherited Proterozoic fractures, as similarly applied for most of the nearly synchronous giant dyke complexes converging towards the Nuanetsi area, leads us to consider that the resulting triple junction-like dyke/fracture pattern is not a definitive proof for a deep mantle plume in the Karoo LIP.     

Extraction of Lithium from Salt Lake Brine using N523-TBP Mixture System

In this work,problems encountered by tri-butyl phosphate( TBP) in the industrialization of lithium extraction from salt lake brine were discussed in detail. The behavior of N,N-bi-( 2-ethylhexyl) acetamide( N523) during lithium extraction was investigated,and its disadvantages were analyzed in the view of practical application. An N523-TBP mixture extraction system was proposed to alleviate or avoid the defects that N523 and TBP met when they were used separately. The optimal composition of this mixture extraction system was determined to be 20% N523-30% TBP-50% kerosene.The effects of brine acidity,Fe/Li molarity ratio,phase ratio and chloride ion concentration on lithium extraction efficiency were discussed. The operation conditions in single-stage extraction were optimized as brine acidity = 0. 05 mol/L,Fe/Li molarity ratio = 1. 3,and phase ratio = 2. The high concentration of chloride ions in brine was beneficial for the extraction of lithium. The structure of the extracted complex was proposed as( LiFeCl_4·n N523·m TBP)·( 2-n) N523·( 2-m) TBP( m + n = 2) by chemical analysis and slope-fitting methods. The extraction thermodynamic functions were calculated preliminarily,and the results suggested that the extraction process was an exothermic( ΔH 0) and spontaneous( ΔG 0) reaction,and the degree of disorder increased( ΔS 0) during the extraction process. This work will give some guidance to the lithium industry of Qinghai in both the fundamental theory and practical application.     

辽宁西部TM图像逆冲断层解译及找煤研究

辽西坳陷中的断陷盆地边缘逆冲断层发育。本文描述了逆冲断层的TM影像特征,解译划分了逆冲断裂带,并指出逆冲断层对找煤远景解译推断的意义。具体分析了南票、北票矿区外围的找煤远景,还应用影像特征探索性地对逆冲断层倾角进行了解译分类。     

台湾地形对台风Meranti(1010)经过海峡地区时迅速增强的影响研究

台风在趋近大陆过程中强度一般衰减, 但Meranti(1010)北上进入台湾海峡过程中却迅速加强, 且在登陆福建时达到最强。采用中国气象局台风资料、NCEP GFS 0.5°×0.5°再分析资料及台湾雷达资料, 结合中尺度数值模式WRF(The Weather Research and Forecasting Model)开展台湾地形敏感性试验, 研究Meranti进入台湾海峡过程中的结构变化及迅速加强机理。结果表明:台湾地形是Meranti迅速加强的一个重要影响因子。Meranti北上过程中, 一方面通过台湾岛地形分流作用及其背风坡效应在台湾海峡内诱生中尺度涡旋, 形成正负相间的涡度分布, 激发出与台风相关的扰动波列。地形强迫抬升及扰动波列可加强垂直运动和积云对流, 有利于台风对流发展。另一方面, 台湾地形还通过改变环境气流使台风高空辐散场加强, 环境风垂直切变减小, 形成有利于台风发展的环流背景。比较不同高度台湾地形试验中台风动能收支发现, 台湾地形激发的扰动波列和积云对流增强了次网格尺度系统与台风间能量的交换, 成为Meranti登陆前迅速加强的主要动能源。     

云南保山从干树金矿控矿条件及矿床成因讨论

从干树金矿赋存于怒江构造带高黎贡山岩群变质岩系中,有两个明显的次级矿化带,具多期次成矿作用特点:前期可能为沉积变质赋矿,后期为剪切(构造热液)成矿。晚期在浅部风化淋滤富集。剪切作用形成的金矿是主体。     

南羌塘盆地中-新生代逆冲推覆构造样式及构造应力场特征

新生代印度板块与欧亚板块的持续碰撞挤压,造成南羌塘地块向南逆冲于拉萨地块之上,并在南羌塘地块内部形成了一系列的由北往南的逆冲推覆构造。然而,到目前为止,我们对这些逆冲推覆构造及夹持其间的褶皱变形的结构组成、构造样式、形成时代以及缩短量分布等问题仍存在很大的争议。本文在详细的野外调查基础上,对赛布错-扎加藏布断裂（SZT）,多玛-其香错断裂（DQT）,隆鄂尼褶断带（LF）及南羌塘与中央隆起带分界的肖查卡-双湖断裂（XST）进行了几何学、运动学分析,建立了精细的构造框架。我们认为这些断裂为始新世以来形成的同时期的叠瓦状逆冲推覆;并通过野外褶皱形态,结合层面、节理面、断层面滑动矢量的分析,识别出南羌塘盆地4期构造应力场：1） 代表中特提斯俯冲碰撞阶段的近S-N 向的挤压;2） 中特提斯碰撞后,随着班公湖-怒江缝合带的形成,南羌塘地区构造应力场转为S-N 向的伸展;3） 新生代印度板块向欧亚板块俯冲碰撞,青藏高原进入陆内变形阶段,南羌塘盆地内表现为NE-SW 向的挤压,形成本文提及的一系列逆冲推覆构造;4） 随着高原的持续隆升,约14 Ma南北向裂谷开始活动,应力场转为NWW-SEE 向伸展,形成双湖裂谷系。     

综合物探法在西邑铅锌矿外围预测靶区运用

西邑铅锌矿取得深部隐伏矿找矿的重大突破,为扩大找矿成果,在其外围有利成矿地段开展地质勘查工作.应用激电中梯、激电测深和EH4等综合物探方法预测找矿靶区,在深部隐伏矿勘查中能取得较好效果.     

云南双江白水河金矿成矿地质特征

白水河金矿属断裂构造控制的热液蚀变型金矿床,金矿体产于新元古界澜沧群变质岩区多期断裂的次级分支断裂破碎带内。沿构造带有辉绿岩脉、石英斑岩脉、煌斑岩脉侵入,首次在临沧地区新元古界澜沧群变质岩区找到金矿。