Precise and Accurate In Situ Determination of Lead Isotope Ratios in NIST,USGS, MPI‐DING and CGSG Glass Reference Materials using Femtosecond Laser Ablation MC‐ICP‐MS

Lead isotope ratio data were obtained with good precision and accuracy using a 266 nm femtosecond laser ablation (fLA) system connected to a multi‐collector ICP‐MS (MC‐ICP‐MS) and through careful control of analytical procedures. The mass fractionation coefficient induced by 266 nm femtosecond laser ablation was approximately 28% lower than that by 193 nm excimer laser ablation (eLA) with helium carrier gas. The exponential law correction method for Tl normalisation with optimum adjusted Tl ratio was utilised to obtain Pb isotopic data with good precision and accuracy. The Pb isotopic ratios of the glass reference materials NIST SRM 610, 612, 614; USGS BHVO‐2G, BCR‐2G, GSD‐1G, BIR‐1G; and MPI‐DING GOR132‐G, KL2‐G, T1‐G, StHs60/80‐G, ATHO‐G and ML3B‐G were determined using fLA‐MC‐ICP‐MS. The measured Pb isotopic ratios were in good agreement with the reference or published values within 2s measurement uncertainties. We also present the first high‐precision Pb isotopic data for GSE‐1G, GSC‐1G, GSA‐1G and CGSG‐1, CGSG‐2, CGSG‐4 and CGSG‐5 glass reference materials obtained using the femtosecond laser ablation MC‐ICP‐MS analysis technique.     

Sub-Alfvénic flows in the quiet and recurrent solar winds

Observed instances are given in this paper to show that sub-Alfvénic flow can be formed in the quiet and recurrent low-speed solar wind streams. This kind of flow appears in regions with abnormal enhancement of Alfvénic speed and is associated with a specific type of magnetic configuration.     

基于GIS的油田井位自动成图系统研究

针对油田生产中油水井数据的特点和管理需求,设计并开发了油田井位自动成图系统:基于Oracle9i与ArcSDE9.0创建空间数据库;基于ASP.NET技术开发浏览器端更新与维护属性数据;基于C与MapObjects2.3开发客户端实现成图及应用功能;对自动成图原理、远程数据访问、图属互查等功能提供了实现方法。     

复合面状对象拓扑关系的表达模型

为表达复合面状对象间的细节拓扑关系,对经典9-交集模型进行了改进,给出两种基于分解思想的9-交集模型,其中分解成简单区域的9-交集模型方法相对简单,但表现形式繁琐;分解成点集的9-交集模型的表现形式符合经典9-交集模型,但计算较为复杂。通过示例比较了两种扩展9-交集模型及经典9-交集模型的表达能力。结果表明,两种扩展交集模型均能准确地表达出复合面状对象各子部分之间的拓扑关系的细节,扩充了9-交集模型的表达能力。     

一种基于实践九号卫星的快速系统误差补偿技术

直接利用光学遥感卫星的严格成像模型对地面点进行定位,定位误差与卫星姿态测量误差有关,其中包括地球自转引起的偏流角误差和姿态角常差。偏流角误差可以根据星历数据予以有效消除,而姿态角常差一般要利用少量控制点进行消除。基于此,在消除偏流角的影响下,这里采用了一种改进的四元数算法——P-H算法用于快速计算姿态角常差,并对系统误差进行补偿。该技术较常用的欧拉角解算,具有原理简单,计算速度快和结果稳定的特点。通过实践九号卫星影像的实验表明,运用该技术能快速和大幅度提高卫星在稀少控制点情况下的定位精度。     

The Reliability of Assigned Values from the GeoPT Proficiency Testing Programme from an Evaluation of Data for Six Test Materials that have been Characterised as Certified Reference Materials

Assigned values derived from the GeoPT proficiency testing programme were compared with certified values for six certified reference materials that have been used as test materials in the GeoPT programme. Statistical analysis showed that there were few significant differences between these sets of data and that these differences had no significant impact on the GeoPT assessment when fitness‐for‐purpose criteria were taken into account.     

Mass Fractions of S,Cu, Se,Mo, Ag,Cd, In,Te, Ba,Sm, W,Tl and Bi in Geological Reference Materials and Selected Carbonaceous Chondrites Determined by Isotope Dilution ICP‐MS

Mass fractions of S, Cu, Se, Mo, Ag, Cd, In, Te, Ba, Sm, W and Tl were determined by isotope dilution sector field ICP‐MS in the same sample aliquot of reference materials using HF‐HNO₃ digestion in PFA beakers in pressure bombs and glassy carbon vessels in a high‐pressure asher (HPA‐S) for comparison. Additionally, Bi was determined by internal standardisation relative to Tl. Because isobaric and oxide interferences pose problems for many of these elements, efficient chromatographic separation methods in combination with an Aridus desolvator were employed to minimise interference effects. Repeated digestion and measurement of geological reference materials (BHVO‐1, BHVO‐2, SCo‐1, MAG‐1, MRG‐1 and UB‐N) gave results with < 5% relative intermediate precision (1s) for most elements, except Bi. Replicates of NIST SRM 612 glass digested on a hot plate were analysed by the same methods, and the results agree with reference values mostly within 2% relative deviation. Data for the carbonaceous chondrites Allende, Murchison, Orgueil and Ivuna are also reported. Digestion in a HPA‐S was as efficient as in pressure bombs, but some elements displayed higher blank levels following HPA‐S treatment. Pressure bomb digestion yielded precise data for volatile S, Se and Te, but may result in high blanks for W.     

世界各国静止气象卫星发展综述

首先阐述了美国、欧洲气象卫星组织(EUMETSAT)、日本静止气象卫星的发展历史,从自旋稳定到三轴稳定,从单一载荷到多载荷并行工作,新一代的静止气象卫星的时间、空间和光谱分辨率都大幅提高,然后重点介绍了我国静止气象卫星风云二号和风云四号,相比于自旋稳定的风云二号气象卫星,风云四号卫星的功能和性能实现了跨越式的发展,接着简单介绍了俄罗斯、印度和韩国等其他国家静止气象卫星的发展状况,最后总结了不同时期各国静止气象卫星的发展特点,这对我国后续静止气象卫星的规划和研制有重要参考意义。     

Calculation of partial melting equilibria in the system Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O (NCKFMASH)

A thermodynamic model for haplogranitic melts in the system Na₂O–CaO–K₂O–Al₂O₃–SiO₂–H₂O (NCKASH) is extended by the addition of FeO and MgO, with the data for the additional end‐members of the liquid incorporated in the Holland & Powell (1998) internally consistent thermodynamic dataset. The resulting dataset, with the software thermocalc , is then used to calculate melting relationships for metapelitic rock compositions. The main forms for this are P–T and T–X pseudosections calculated for particular rock compositions and composition ranges. The relationships in these full‐system pseudosections are controlled by the low‐variance equilibria in subsystems of NCKFMASH. In particular, the solidus relationships are controlled by the solidus relationships in NKASH, and the ferromagnesian mineral relationships are controlled by those in KFMASH. However, calculations in NCKFMASH allow the relationships between the common metapelitic minerals and silicate melt to be determined. In particular, the production of silicate melt and melt loss from such rocks allow observations to be made about the processes involved in producing granulite facies rocks, particularly relating to open‐system behaviour of rocks under high‐grade conditions.     

The impact of fragment “L” of comet SL-9 on Jupiter

Filtergrams of high spatial and temporal resolution were obtained in the methane band centred at 892 nm during the impact of fragment L of comet Shoemaker-Levy 9 on Jupiter. The light curve shows two maxima of an emission ball observed above the limb shortly after the impact. The second maximum was the brightest and had a short life time of about 90 seconds. During it's life, the apparent height of the emission ball declined towards the surface of Jupiter; the amount of displacement is larger than the expected effect caused by Jupiter's rotation. About half an hour after the impact, a domelike feature became visible when the location of the impact rotated into the illuminated hemisphere of Jupiter.