Adsorption of Au(III) and Au(I) complexes on δ-MnO2

The sorption of AuCl₄ ⁻,AuCl₂ ⁻ and Au(S₂O₃)^3- on δ-MnO₂ was investigated at pH2–11.6, 0.01 mol/L and 0.1 mol/L NaNO₃ solutions. At pH 4 in two electrolyte strength solutions, Au sorption densities on δ-MnO₂ are 0.18–0.21 and 0.28μmoL/m² for AuCl₄ ⁻ and Au(S₂O₃)₂ ^3-, respectively, and the Au surface coverage is approximate to or lower than 1%. This adsorption of the two Au complexes decreases as the solution pH increases, which conforms to the sorption regularity of the anion on δ-MnO₂. The Au sorption decreases in the sequence of Au(S₂O₃)₂ ^3- >AuCl₄ ⁻ >AuC1₂ ⁻. The intrinsic equilibrium constants (logK ^int) of the three Au complexes are 1.17–2.7, much higher than those of Cu and Cd. The hydrolysis products of AuCl₄ ^- are preferentially adsorbed by δ-MnO₂ and the inner-sphere Au-surface complexes are formed on the surface. Project supported by the National Studying-abroad Foundation, the National Natural Science Foundation of China (Grant No. 49573200) and the Australian Mining Industry.     

Extending the known distribution of the Younger Dryas Vedde Ash into northwestern Russia

The known distribution of wind‐blown Vedde Ash (ca. 10.3 ka BP) has been extended to the Karelian Isthmus in northwestern Russia. This has been possible as the result of a density separation technique that separates the rhyolitic Vedde Ash shards from the minerogenic host sediment. The Vedde Ash occurs in the middle of a pollen zone with high percentages of, for example, Artemisia and Chenopodiaceae, suggesting that the Younger Dryas (or GS‐I in the GRIP ice‐core event stratigraphy) was cold and dry throughout its duration. This is in agreement with sites in south Sweden where the Vedde Ash also occurs in the middle of a pollen zone dominated by Artemisia, Chenopodiaceae and Cyperaceae. Copyright © 2000 John Wiley & Sons, Ltd.     

BVRI photometry of possible standard stars in NGC 188

CCD photometry of possible standard stars, in Cousins B, V, R and I, in a field in the region of NGC 188 is presented.     

http://dx.doi.org/10.1016/j.gsf.2016.04.002

Population synthesis studies into planet formation have suggested that distributions consistent with observations can only be reproduced if the actual Type Ⅰ migration timescale is at least an order of magnitude longer than that deduced from linear theories.Although past studies considered the effect of the Type I migration of protoplanetary embryos,in most cases they used a conventional formula based on static torques in isothermal disks,and employed a reduction factor to account for uncertainty in the mechanism details.However,in addition to static torques,a migrating planet experiences dynamic torques that are proportional to the migration rate.These dynamic torques can impact on planet migration and predicted planetary populations.In this study,we derived a new torque formula for Type Ⅰ migration by taking into account dynamic corrections.This formula was used to perform population synthesis simulations with and without the effect of dynamic torques.In many cases,inward migration was slowed significantly by the dynamic effects.For the static torque case,gas giant formation was effectively suppressed by Type I migration;however,when dynamic effects were considered,a substantial fraction of cores survived and grew into gas giants.     

新疆县域农林牧渔业空间差异分析——基于ESDA与GIS方法

应用ESDA并结合标准差指数(S)、变异系数(V)等方法,从空间相关的视角分析新疆各县市农林牧渔业人均产值的空间差异。结果显示:以农林牧渔业人均产值来计算的新疆县域间的农林牧渔业人均产值呈现北疆高于东疆、南疆的空间差异。2003-2012年间:新疆县域农林牧渔业人均产值的空间自相关测度Moran's I呈曲线性增减态势,表明农林牧渔业人均产值的空间集聚性呈曲线性波动,但农林牧渔业人均产值的年增长率逐年上升。从局部自相关分析来看,区域间呈现两个极端化较为明显,说明新疆农林牧渔业人均产值在空间分布上具有不均衡性。     

上海地区不同重现期的风速估算研究

基于上海气象站历史风速观测资料,采用极值I型和皮尔逊III型分布估算了上海市不同重现期最大风速的时间变化以及各区（县）不同重现期最大和极大风速的空间分布。结果表明,1901~2011年,上海市10、30、50和100 a重现期的最大风速分别为21.0、24.9、26.7和29.2 m/s。1974~2011年期间,上海各区（县）10 m高度10、30、50和100 a重现期的最大风速都是以南部沿海地区南汇或金山最大,分别为19.0、21.4、22.6和24.1 m/s;各重现期极大风速也是以南汇或金山最大,分别为32.3、36.4、38.4和41.0 m/s。中心城区各重现期的最大和极大风速都最小。     

iTRAQ-based proteomic profiling of the marine medaka (Oryzias melastigma) gonad exposed to BDE-47

A recent study demonstrated that 2,2′,4,4′-tetrabromodiphenyl ether (BDE-47) may have an adverse effect on the reproduction in marine medaka (Oryzias melastigma), but the molecular mechanisms remain largely unknown. In this study, we investigated the protein expression profiles of male and female gonads of O. melastigma exposed to dietary BDE-47 at two dosages (0.65 and 1.30 μg/g/day, respectively) for 21 days. Extracted proteins were labeled with iTRAQ and analyzed on a MALDI TOF/TOF analyzer, as results, 133 and 144 unique proteins were identified in testis and ovary, respective, and they exerted dose- and sex-dependent expression patterns. In testis, among the 42 differentially expressed proteins; down-regulation of histone variants and parvalbumins implicated BDE-47 may disrupt the spermatogenesis and induce sterility in fishes. In ovary, 38 proteins were differentially expressed; the elevation of vitellogenins and apolipoprotein A–I expression indicated BDE-47 acts as an estrogen-mimicking compound and led to reproductive impairment in O. melastigma.     

珠三角县域城市潜力的时空关联结构演变

基于1990、1994、2000、2005 和2009年公路网数据和经因子分析得到的县域城市综合实力指数,采用扩展的潜力模型测度县域潜力指数,运用时空自相关方法探讨珠三角县域潜力的时空关联格局及其演变,并与空间关联格局对比及与交叉相关函数比较检验其准确性。结果表明：① 珠三角县域潜力总体上具正时空关联性,但关联程度不高,1994-2005年缓慢加强而2005-2009年趋于减弱。大多县域潜力的局部时空关联特征相对稳定,且以正相关为主,但部分县市时空关联类型发生了明显转化。② 县域潜力的局部时空关联类型分布差异及其变化明显,时空HH区分布于中部地带和东部的深圳—东莞地带,2000年后中部的时空HH区范围收缩至广—佛核心都市区;西部时空LL区连片分布格局相对稳定,中南部2005年开始出现新的时空LL区,东部时空LL区范围1994-2000年扩大而后逐步收缩,2009年零星分布于东部边缘;时空异质区变化较剧烈。③ 三大地带县域潜力的局部时空关联特征反差鲜明,东部与中部差异趋于缩小,而西部与中、东部的差异进一步扩大。④ 时空自相关方法能有效挖掘县域潜力的时空关联模式,比仅考虑空间效应的ESDA方法更能准确客观揭示县域潜力间的时空交互关系。     

Genetic diversity and population structure of Eleutheronema rhadinum in the East and South China Seas revealed in mitochondrial COI sequences

Eleutheronema rhadinum is a potential commercial fisheries species and is subject to intense exploitation in China. Knowledge on the population structure of E. rhadinum in Chinese coastal waters, which is important for sustainable exploitation and proper resource management, is lacking. In the present study, the genetic diversity and population structure of E. rhadinum were evaluated using a 564-base pair fragment of the mitochondrial cytochrome c oxidase subunit I （COl） gene. A total of 76 specimens were collected from three localities around the East （Qidong and Zhoushan） and South China Seas （Zhuhai）. Among these individuals, nine polymorphic sites were detected and 1 l distinct haplotypes were defined. High levels ofhaplotype diversity （h=0.759i0.035） and low levels of nucleotide diversity （re=0.001 98i0.003 26） were observed in these populations, Hierarchical analysis of molecular variance （AMOVA） indicated that 96.72% of the genetic variation occurred within the populations, whereas 3.28% occurred among populations. No significant genealogical branches or clusters were recognized on the neighbor-joining tree. Intra-group variation among populations was significant （~0~t=0.032 85, P〈0.01）. These results suggest that E. rhadinum populations in the East and South China Seas have developed divergent genetic structures. Tests of neutral evolution and mismatch distribution suggest that E. rhadinum may have experienced a population expansion. The present study provides basic information for the conservation and sustainable exploitation of this species.     

Sensitive Ion‐Flotation Separation of Ag(I) Traces Using 2‐(2‐Methoxyphenyl)benzimidazole before Flame Atomic Absorption Spectrometric Determination in Water

A sensitive, reliable, and environmentally friendly method for simple separation and preconcentration of Ag(I) traces in aqueous samples is presented prior to their flame atomic absorption spectrometric determinations. At pH 7.0, Ag(I) was separated with 2‐(2‐methoxyphenyl)benzimidazole (MPBI) as a new complexing agent and floated after adding sodium dodecyl sulfate (SDS) as a foaming reagent. The floated layer was then dissolved in proper amount of concentrated nitric acid in methanol and introduced to the flame atomic absorption spectrometer (FAAS). The effects of pH, concentration of MPBI, type and amount of surfactant as the floating agent, type and amount of eluting agent, and influence of foreign ions on the recovery of the analyte ion were investigated. Also, using a nonlinear curve fitting method, the formation constant of 1.62 × 10⁶ was obtained for Ag(I)–MPBI complex. The analytical curve was linear in the range of 1.8 × 10^?7–1.7 × 10^?6 mol/L for determination of Ag(I). The relative standard deviation (RSD; N = 10) corresponding to 0.7 × 10^?6 mol/L of Ag(I), the limit of detection (10 blanks), and the enrichment factor were obtained as 1.7%, 2.9 × 10^?8 mol/L, and 43.0, respectively. The proposed procedure was then applied successfully for determination of silver ions in different water samples.