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961.
B.E. Leveridge R.K. Shail 《Proceedings of the Geologists' Association. Geologists' Association》2011,122(4):568-615
Deep marine deposits of the Gramscatho Basin of south Cornwall reflect two tectonic regimes; Early to Middle Devonian rifting of continental lithosphere with formation of oceanic lithosphere to the south, and Middle Devonian to earliest Carboniferous convergence along its southern margin. Sediments on thinned continental crust to the north and oceanic lithosphere to the south were juxtaposed in the Late Devonian when nappes of deep water flysch and olistostrome were thrust up on to the northern continental margin of the basin. Basin closure was accommodated by forward propagating thrust nappes, accompanied by penecontemporaneous sedimentation. The stratigraphical sequences of major nappes illustrate the progradation of flysch with climactic sedimentation of olistostrome in late Mid- to Late Devonian times. The Lizard Complex, including the Lizard ophiolite, within that nappe stack, constitutes part of one of the GCR sites which are largely in the allochthonous rocks. Many of those sites feature the olistostrome, Roseland Breccia Formation, with its great variety of sedimentary, igneous and metamorphic clasts (up to 1.5 km), and the association of ocean floor basalt and penecontemporaneous acidic volcanics indicative of the coming together of oceanic and continental plates. A site at the top of the parautochthonous continental margin succession displays the erosion products of the youngest nappe as it emerged and advanced across the sediment surface, marking closure of the oceanised Gramscatho Basin and continental collision. 相似文献
962.
963.
为提高桥墩泥石流防撞墩的抗冲击性能,拟将废旧轮胎堆栈于防撞墩前,与之形成一种刚柔复合结构.并使用显式动力有限元软件LS-DYNA,通过对泥石流大石块的冲击过程进行数值计算,发现当冲击能量在轮胎的吸能范围时,其冲击力能降低80%. 相似文献
964.
潜孔锤的钻进过程是一个高度非线性、大变形、破碎岩石的过程,利用非线性有限元程序ANSYS/LS-DY-NA研究了在凿岩过程中,球齿凿入不同空隙率(塑性体积应变)岩石的冲击力特性。结果表明,岩石空隙率对钻头球齿与岩石之间的凿入冲击力幅值有很大影响,随着空隙率的增大,球齿凿入的冲击力显著减小,而对活塞与钻头间冲击力幅值影响甚微。通过ANSYS/LS-DYNA瞬态冲击数值模拟,形象地再现了潜孔锤钻凿系统冲击岩石发生侵入破坏的物理过程,为冲击碎岩瞬态研究提供了一个有效的分析方法。 相似文献
965.
Yimin Wang Xiaohong Wang Wenjun Qu Yushu Gao Tiexin Gu Xingtao Fan S.I. Andreev Xuefa Shi 《Geostandards and Geoanalytical Research》2011,35(3):341-352
Two Co‐rich seamount crust reference materials, MCPt‐1 and MCPt‐2, were prepared using ultra‐fine particle size milling technique and characterised for the platinum‐group elements (PGEs). The raw material for these two reference materials was collected separately from the Magellan seamounts of the western Pacific Ocean and the seamounts of the central Pacific Ocean by Russian and Chinese scientists. First, they were ground by ball mill to a ?200 mesh powder, then further processed by ultra‐fine jet mill and well‐mixed. The particle size distributions of the samples were tested by a laser particle analyser; the average particle size was 1.8 and 1.5 μm (equal to about 2000 mesh) respectively. The homogeneity of six major and minor elements in these two materials was tested at the milligram level of sampling mass by high‐precision wavelength dispersive X‐ray fluorescence (XRF) spectrometry and at the microgram level of sampling mass by electron probe microanalyser. The homogeneity of more than forty trace elements, including Pt, was tested at the microgram level of sampling mass by LA‐ICP‐MS. Except for Rh, all PGEs were determined by isotope dilution‐ICP‐MS. Platinum in MCPt‐1 and MCPt‐2 was characterised as certified values, whereas the other five PGEs in MCPt‐1 and MCPt‐2 were reported as reference values. In addition, the information values of sixty‐two major, minor and trace elements were obtained by XRF, ICP‐AES and ICP‐MS. The minimum sampling mass for the determination of PGEs was 1 g, while the minimum sampling mass for the determination of the other elements was 2–5 mg. 相似文献
966.
Cornelia Kriete 《Geostandards and Geoanalytical Research》2011,35(3):319-340
Round 23 of the GeoPT international proficiency testing scheme included the ferromanganese nodule powder FeMn‐1 which was distributed as an additional sample (23A). The aim of this initiative was to assess overall analytical performance for such a challenging oxide matrix with a view to the possible certification of such a material in accordance with ISO Guide requirements. To investigate inter‐method discrepancies, precision data and the method means for the most frequently used analytical methods (XRF, ICP‐MS and ICP‐AES) and sample preparation techniques were calculated and then compared using statistical tests of equivalence. For most major elements, XRF and ICP‐AES data dominated and these were found to give equivalent results. In contrast, for most trace elements significant discrepancies were detected between data obtained by different analytical methods. Possible causes are discussed with a view to attributing their origin to calibration strategy, sensitivity or interferences. It is assumed that the unusual oxide matrix generated unexpected interferences and thus method bias. Discrepancies observed between data from different analytical methods provide valuable information for the participating analysts, helping them to avoid systematic errors and thus minimising bias. They also suggest actions necessary to improve results for any future certification of such a material. 相似文献
967.
Mg/Ca and Sr/Ca ratios in calcium carbonate are important components of many palaeoclimate studies. We present an isotope dilution method relying on a single mixed spike containing 25Mg, 43Ca and 87Sr. Dozens of samples per day, as small as 10 μg of carbonate, could be dissolved, spiked and run in an ICP‐MS with a precision of 0.8% (2 RSD). Two instruments types, a sector field and a quadrupole ICP‐MS, were compared. The best long term precision found was 0.4% (2 RSD), although this increased by up to a factor of two when samples of very different Mg or Sr content were run together in the same sequence. Long term averages for the two instruments concurred. No matrix effects were detected for a range of Ca concentrations between 0.2 and 2 mmol l‐1. Accuracy, tested by measuring synthetic standard solutions, was 0.8% with some systematic trends. We demonstrate the strength of this isotope dilution method for (a) obtaining accurate results for sample sets that present a broad Mg and Sr range and (b) testing solid carbonates as candidate reference materials for interlaboratory consistency. Mg/Ca and Sr/Ca results for reference materials were in good agreement with values from the literature. 相似文献
968.
Surendra P. Verma Rosalinda González‐Ramírez Rodolfo Rodríguez‐Ríos 《Geostandards and Geoanalytical Research》2011,35(2):183-192
Pressed powder pellets and fused beads or glass disks are routinely used in X‐ray fluorescence spectrometry for the determination of major and trace elements, respectively, in geological materials. In order to evaluate the performance of these two sample preparation methods, we determined Ni and Cr concentrations of fourteen RMs from Japan, France and South Africa, and eighty‐five igneous and three sedimentary rock samples from Mexico in both powder pellets and glass beads. We also computed new values of statistical parameters for RMs from an outlier‐based multiple‐test method and compared them with the literature mean and confidence limit values. The results showed that the multiple‐test method provided more reliable central tendency and dispersion parameters for RMs than those obtained previously from the two or three standard deviation method, or from robust methods. The powder pellet and fused bead sample preparation methods provided consistent results for Ni and Cr at concentration levels > 50 μg g?1 in this application; for lower concentration levels, however, these methods showed somewhat greater differences. For quantitative comparisons, both ordinary and weighted least‐squares linear regression models were used to show that the two sample preparation methods provided generally unbiased results. 相似文献
969.
Germain Bayon Dominique Birot Claire Bollinger Jean Alix Barrat 《Geostandards and Geoanalytical Research》2011,35(1):145-153
We report on an improved method for determining trace element abundances in seawater and other natural waters. The analytical procedure involves co‐precipitation on iron hydroxides after addition of a Tm spike, and measurement by inductively coupled plasma‐sector field mass spectrometry (ICP‐SFMS). The validity of the method was assessed through a series of co‐precipitation experiments, using ultra‐diluted solutions of a certified rock reference material (BIR‐1). Results obtained for four natural water reference materials (NASS‐5, CASS‐4, SLEW‐3, SLRS‐4) are in agreement with published working values for rare earth elements, yttrium, vanadium and, when available, for hafnium, zirconium, thorium and scandium. A set of proposed values with uncertainties typically better than 8% RSD is proposed for Hf, Zr and Th. 相似文献
970.
A HF‐free sample preparation method was used to purify silicon in twelve geological RMs. Silicon isotope compositions were determined using a Neptune instrument multi‐collector‐ICP‐MS in high‐resolution mode, which allowed separation of the silicon isotope plateaus from their interferences. A 1 μg g‐1 Mg spike was added to each sample and standard solution for online mass bias drift correction. δ30Si and δ29Si values are expressed in per mil (‰), relative to the NIST SRM 8546 (NBS‐28) international isotopic RM. The total variation of δ30Si in the geological reference samples analysed in this study ranged from ‐0.13‰ to ‐0.29‰. Comparison with δ29Si values shows that these isotopic fractionations were mass dependent. IRMM‐17 yielded a δ30Si value of ‐1.41 ± 0.07‰ (2s, n = 12) in agreement with previous data. The long‐term reproducibility for natural samples obtained on BHVO‐2 yielded δ30Si = ‐0.27 ± 0.08‰ (2s, n = 42) on a 12 month time scale. An in‐house Si reference sample was produced to check for the long‐term reproducibility of a mono‐elemental sample solution; this yielded a comparable uncertainty of ± 0.07‰ (2s, n = 24) over 5 months. 相似文献