内蒙古区域数值预报对探空和地面观测资料的敏感性试验研究

基于内蒙古睿图预报系统的低分辨率版本和WRFDA-FSO诊断工具,评估2021年7月现有探空和地面观测对内蒙古睿图预报系统预报的影响。该方法计算代价相对低廉,并允许根据观测变量、观测类型、气压层次、地理区域等观测的子集对观测影响进行划分。代价函数为以干总能量为度量的背景场和分析场的预报误差之间的差异。结果表明:观测影响的总体总和为负,观测对预报起正贡献作用。对12 h预报误差减小贡献最大的观测来自探空观测的动力变量(U、V风分量)。而单时次单位数量平均观测影响,探空观测的贡献约为地面观测的1/2。探空观测对12 h预报误差减小从近地面层至模式层顶均保持正贡献作用,并在对流层中低层和对流层高空急流层存在两个极大值区域;地面观测在850 hPa以下低层正贡献占比明显。探空观测在被同化系统同化时均总体具有有利的影响,也反映出探空观测数据稳定、质量较高的特征;地面观测对12 h预报误差减小起正贡献作用次数最多的区域在河套地区尤为显著。同时,探讨了需进一步提高地面观测资料同化率的问题。     

Matt Wilson structure: record of an impact event of possible Early Mesoproterozoic age,Northern Territory

The Matt Wilson structure is a circular 5.5 km-diameter structure in Early Mesoproterozoic or Neoproterozoic rocks of the Victoria Basin, Northern Territory. It lies in regionally horizontal to gently dipping Wondoan Hill and Stubb Formations (Tijunna Group) and Jasper Gorge Sandstone (Auvergne Group). An outer circumferential syncline with dips of 5?–?40° in the limbs surrounds an intermediate zone with faulted sandstone displaying horizontal to low dips, and a central steeply dipping zone about 1.5 km across. Several thrust faults in the outer syncline appear to indicate outward-directed forces. The central zone, marked by steeply dipping to overturned Tijunna Group and possibly Bullita Group sandstone and mudstone, indicates uplift of at least 300 m. The rocks are intensely fractured with some brecciation, and contain numerous planar to subtly undulating surfaces displaying striae which resemble shatter cleavage. Thin-sections of sandstone from the central area show zones of intense microbrecciation and irregular and planar fractures in quartz, but no melt-rocks have been identified. The planar fractures occur in multiple intersecting parallel sets typical of relatively low-level (5?–?10 GPa) shock-pressure effects. Alternative mechanisms, i.e. igneous intrusion, carbonate collapse, diapirism and regional deformation processes, have been discounted. The circular nature, central uplift, faulting, shatter features and planar fractures are all consistent with an impact origin. The Matt Wilson structure is most likely a deeply eroded impact structure in which the more highly shocked rocks of the original crater floor have been removed by erosion. Estimates of the age of the Auvergne and Tijunna Groups range from Early Mesoproterozoic (which we favour) to Late Neoproterozoic. Early Cambrian Antrim Plateau Volcanics near the impact structure show no signs of impact effects, allowing the age of impact to be constrained between Early Mesoproterozoic and Early Cambrian. The presence of widespread soft-sediment deformation features, apparently confined to a single horizon in the Saddle Creek Formation some 700?–?1000 m stratigraphically higher in the Auvergne Group than the rocks at the impact site, and apparently increasing in thickness towards the Matt Wilson structure, lead us to speculate that this probable event horizon is related to the impact event: if correct the impact occurred during deposition of the Saddle Creek Formation.     

Raindrop‐impact‐induced erosion processes and prediction: a review

Raindrop‐impact‐induced erosion is initiated when detachment of soil particles from the surface of the soil results from an expenditure of raindrop energy. Once detachment by raindrop impact has taken place, particles are transported away from the site of the impact by one or more of the following transport processes: drop splash, raindrop‐induced flow transport, or transport by flow without stimulation by drop impact. These transport processes exhibit varying efficiencies. Particles that fall back to the surface as a result of gravity produce a layer of pre‐detached particles that provides a degree of protection against the detachment of particles from the underlying soil. This, in turn, influences the erodibility of the eroding surface. Good understanding of rainfall erosion processes is necessary if the results of erosion experiments are to be properly interpreted. Current process‐based erosion prediction models do not deal with the issue of temporal variations in erodibility during a rainfall event or variabilities in erodibility associated with spatial changes in dominance of the transport processes that follow detachment by drop impact. Although more complex erosion models may deal with issues like this, their complexity and high data requirement may make them unsuitable for use as general prediction tools. Copyright © 2005 John Wiley & Sons, Ltd.     

混合表面活性剂存在下镓与O—Cl—PF显色反应的研究

本文研究了在pH 6.5-7.8的(CH_2)_6N_4-HCl缓冲介质中,CDMAA和TritonX-100对Ga与o-Cl-PF和F~-显色反应的增敏作用。结果表明,Ga-o-Cl-PF-F-CDMAA-TritonX-100多元配合物λ_(max)为565nm,表观摩尔吸光系数ε=1.74×10~5L·mol~(-1)·Cm~(-1),Ga含量在0～6.0μg/25ml范围内符合比尔定律,用合成样和标样进行本方法考验,结果满意。     

钛-氨三乙酸-对氯苯基荧光酮-CTMAB四元配合物的分光光度法研究

本文研究Ti(Ⅳ)-氨三乙酸(NTA)-对氯苯基荧光酮(p-ClPF)-CTMAB四元配合物的显色条件。结果表明,在pH5.8—6.6形成了摩尔比为Ti(Ⅳ):NTA:p-ClPF:CTMAB=1:1:3:3的四元配合物,借此反应测定钛,灵敏度高,其ε_(573nm)=2.1×10~5L·mol~(-1)·cm~(-1)。Ti(Ⅳ)浓度在0—1.4μg/10ml范围服从比耳定律。已用本法直接测定了岩矿和铝合金中的Ti,结果满意。     

核爆炸玻璃、撞击玻璃和玻璃陨石源岩

本文根据核爆炸岩石熔融玻璃的地球化学研究结果,与超速陨石撞击坑的熔岩进行比较,获得在远离热力学平衡条件下,各种玻璃和熔岩在化学成分上分布十分均匀的重要结论。岩石玻璃和熔岩是由基岩各组成岩石按一定比例混合熔融形成的。它们的主量元素和痕量元素丰度受基岩元素背景值制约。文中根据熔体和靶岩的化学成分,计算了熔岩各组成岩石的百分比。玻璃陨石是地壳岩石受撞击熔融形成的。同一撒布区的玻璃陨石化学成分相近,说明起源于同一源坑;而玻璃陨石化学成分的不同,则说明母岩组成分量的差异。因此,文中通过模拟计算,得出各玻璃陨石的组成源岩。澳大利亚撒布区的玻璃陨石,Al₂O₃,K₂O 和Na₂O 与 SiO₂及 K₂O/Na₂O 比值不完全相同,说明澳大利亚撒布区存在着几个不同的源岩和源坑,至少有印支、爪哇、菲律宾和澳大利亚四个相应撞击坑。     

Trace analysis of quaternary aminoalcohols as degradation products from softeners in wastewater

The sensitive and selective determination of polyalcohols without chromophores or fluorophores in the lower ppb-level is still an analytical task of high interest, especially in the field of environmental investigations. This paper describes a cation-exchange HPLC procedure for the separation and fluorescence detection of two quaternary ammonium compounds with polyalcoholic groups (degradation products of fabric softener) after derivatization with 9-fluorenylmethyl chloroformate (FMOC). Detailed experiments were carried out to determine optimum reaction conditions (pH, reaction time, temperature), linear range, detection limits, and kinetics of the reaction. The HPLC separation on a cation-exchange column includes a gradient program which provides complete separation from neutral compounds also reacting with FMOC and its hydrolysis products formed during the reaction in alkaline medium. High specificity for both investigated ammonium compounds with detection limits in the range of 1 ppb could be achieved.     

甘肃西部地区高放废物处置库场址预选调查

本文根据高放废物处置库场址选择的基本要求，对区域地质及深部构造特征、新构造运动及地震分布规律进行了调查，确定北山南带地区为稳定区。在稳定区内根据处置库有利围岩的出露情况，结合岩体工程地质特征分析，初步选出了４个以花岗岩为主体的场址预选区。经综合分析，认为在４个场址预选区中，以Ｉ号预选区的条件最优，其次是Ⅱ号预选区，再次是Ⅲ号和Ⅳ号预选区。场址区的最后确定尚待进一步调查和论证。     

River channel adjustments downstream from channelization works in England and Wales

Relatively little attention has been given to river channel adjustments that occur downstream from channelization works. This study is concerned with the nature of channel adjustments downstream from a total of 46 channelization works located in low and high energy environments in England and Wales. Channel changes are identified principally by the method of field survey and by reconstructing the original positions of eroded beds and banks. Use is also made of maps, aerial photographs, and engineering drawings of different dates and the technique of space-for-time substitution is applied. Enlargement of channel cross-sections through erosion had occurred downstream from a variety of types, sizes, and dates of channelization works. The maximum increase of channel size was 153 per cent. Out of a total of 14 sites with enlarged channel cross-sections, seven had undergone a change of width only, at a further three width increased rather than depth, and at the remaining four sites depth increases were dominant. These sites all have relatively high stream powers. Factors causing spatial variation of erosion included tree roots locally binding bank sediments and the occurrence of bends. Planform change had taken place at only one site. A further three high stream power sites had downstream reaches incised into bedrock and therefore did not exhibit adjustment. Channel enlargement is explained in terms of increased flood flows downstream from channelization works causing higher stream velocities, which in turn cause erosion, thereby increasing channel width and/or depth. Examination of flow records for 35 stations revealed flood events which would formerly have spread overbank but are now confined by the channelization works and are therefore likely to alter downstream flows. At sites with downstream change it is proposed that the energy of increased flows was sufficient to exceed a threshold required for erosion of perimeter sediments. By contrast the absence of change at a majority of sites in low energy lowland areas could be a reflection of both the incompetence of increased flows to erode and resistance provided by perimeter sediments. Sites with erosion features appear not to have yet attained new equilibrium conditions.