An Investigation of Digestion Methods for Trace Elements in Bauxite and Their Determination in Ten Bauxite Reference Materials Using Inductively Coupled Plasma‐Mass Spectrometry

Trace elements from samples of bauxite deposits can provide useful information relevant to the exploration of the ore‐forming process. Sample digestion is a fundamental and critical stage in the process of geochemical analysis, which enables the acquisition of accurate trace element data by ICP‐MS. However, the conventional bomb digestion method with HF/HNO₃ results in a significant loss of rare earth elements (REEs) due to the formation of insoluble AlF₃ precipitates during the digestion of bauxite samples. In this study, the digestion capability of the following methods was investigated: (a) ‘Mg‐addition’ bomb digestion, (b) NH₄HF₂ open vessel digestion and (c) NH₄F open vessel digestion. ‘Mg‐addition’ bomb digestion can effectively suppress the formation of AlF₃ and simultaneously ensure the complete decomposition of resistant minerals in bauxite samples. The addition of MgO to the bauxite samples resulted in (Mg + Ca)/Al ratios ≥ 1. However, adding a large amount of MgO leads to significant blank contamination for some transition elements (V, Cr, Ni and Zn). The NH₄HF₂ or NH₄F open vessel digestion methods can also completely digest resistant minerals in bauxite samples in a short period of time (5 hr). Unlike conventional bomb digestion with HF/HNO₃, the white precipitates and the semi‐transparent gels present in the NH₄HF₂ and NH₄F digestion methods could be efficiently dissolved by evaporation with HClO₄. Based on these three optimised digestion methods, thirty‐seven trace elements including REEs in ten bauxite reference materials (RMs) were determined by ICP‐MS. The data obtained showed excellent inter‐method reproducibility (agreement within 5% for REEs). The relative standard deviation (% RSD) for most elements was < 6%. The concentrations of trace elements in the ten bauxite RMs showed agreement with the limited certified (Li, V, Cr, Cu, Zn, Ga, Sr, Zr and Pb) and information values (Co, Ba, Ce and Hf) available. New trace element data for the ten RMs are provided, some of which for the first time.     

Production and Certification of Synthetic Selenium Isotopic Reference Materials

Due to intensive research into selenium isotopes in recent years, the increasing requirement for reliable and comparable measurement results has created a strong demand for selenium isotopic certified reference materials (iCRM) that were previously not available. To address this, eleven selenium iCRMs were developed, including ten synthetic iCRMs (GBW 04447–GBW 04456) and one natural iCRM (GBW 04457). The synthetic iCRMs were prepared with ⁷⁶Se, ⁷⁸Se, ⁸⁰Se and ⁸²Se solutions and a natural selenium solution; the natural iCRM was prepared with highly pure selenium material. The property values of isotope ratios in these iCRMs were certified by calibrated mass spectrometry with a collision cell multi‐collector ICP‐MS. The mass discrimination effect of the instrument was corrected with corresponding ⁷⁸Se/⁷⁶Se isotope mixtures and ⁸²Se/⁷⁶Se isotope mixtures, which were gravimetrically prepared with purified, isotopically enriched selenium materials. Homogeneity and stability tests were performed, and no significant influences were found. The uncertainty of the property values of the iCRMs was evaluated according to the Guide to the Expression of Uncertainty in Measurement (GUM) of ISO/BIPM and ISO Guide 35. The δ^82/76Se value of GBW 04457 relative to NIST SRM 3149 was also calculated. These iCRMs are intended for use in calibration of instruments and evaluation of methods for the determination of selenium isotope ratios.     

基于突变级数法的页岩气探采综合环境影响评价研究

为缓解能源紧张,页岩气作为储量丰富的非常规能源在我国正大力开发,而我国页岩气开发起步较晚,受管理与技术限制,页岩气开发造成的综合环境影响问题还得不到有效解决。针对页岩气开发存在的环境问题,本文基于我国页岩气开发现状,借鉴美国页岩气开发的成功经验,从自然环境与人文环境两方面对页岩气开发综合环境影响因素进行分析,建立了页岩气开发综合环境影响评价指标体系;同时为降低评价过程主观因素的影响,简化评估过程,本文引入突变级数法建立了页岩气开发综合环境影响评估模型,运用数值替换方法区分页岩气开发综合环境影响等级。最后将评价体系与评估模型应用到实际案例中,得到的评价结果与实际情况基本符合,为页岩气开发项目的综合环境评价提供了很好的理论依据。     

月表构造与深部构造的关系

地球和月球很可能是通过大撞击形成的。在行星地质学中,研究月球的地质-构造现象,对了解月球、地球乃至太阳系的形成与演化历史都有很大帮助。月球的构造分为深部构造与月表构造,寻找它们在分布或成因上的关系,可以为月球甚至地月系的起源和演化历史提供重要参考。利用LROC的宽视角影像数据以及LOLA数据提取解译月表构造,结合深大断裂进行观察分析,并对月球的撞击盆地进行统计,最后以静海地区为例分析构造分布特征,发现月球的质量瘤盆地中具有环状分布的月岭,外侧具有近环状分布的深大断裂,自前酒海纪至酒海纪,具备上述特征的质量瘤盆地占总撞击盆地的比例突然有一个很大的提升,且静海地区西部具有该构造分布特征。推测该特征与撞击、月海沉降等有关,且在酒海纪与雨海纪期间月球有较多的月海玄武岩分布,由此判断静海西部存在质量瘤,发生过撞击与月海沉降。     

高海拔多年冻土区路基工程行为对低温多年冻土长期影响的监测研究

青藏铁路路基创造性采用了主动冷却路基的设计理念修建而成,目前铁路已经安全运营超过10年。青藏铁路路基修筑在多年冻土之上,路基下部冻土温度变化是衡量路基是否稳定的关键因素。基于长期（2008—2019年）地温观测资料,对昆仑山垭口南坡青藏铁路K980+000低温多年冻土区块石路基坡脚至坡脚外30 m范围内的冻土上限变化、年际地温变化、季节性地温变化进行分析,研究了路基工程行为对低温多年冻土的长期影响机制。结果表明：冻土地温不断升高,冻土上限逐年下移;与天然孔比较,路基坡脚处地温增温幅度反而较小,主要可能受块石路基冷却效应的影响;冷季与暖季呈现出不对称的增温趋势。冻土路基普遍增温的趋势仍然存在,出于对多年冻土的保护与保证工程稳定性的考虑,应尽量采用冷却路基的思想修建路基。同时,应加强对路基的监测,分析长期增温过程后路基稳定性变化,并对路基下部冻土的变化做出定量研究。     

落石冲击混凝土板与缓冲层组合结构的动力响应

钢筋混凝土（RC）板与一定厚度的土颗粒缓冲层组合结构被广泛用于山区高位单体及群发性崩塌落石的防治,为研究此类防护结构在落石作用下的冲击力衰减规律及RC板的破坏模式,开展了室外系列落石冲击试验。结果表明,增大缓冲层厚度能够有效减小最大冲击力,峰值加速度随缓冲层厚度减小而增大,尤其在缓冲层厚度为0.1 m及0.2 m时,最大值急剧增大,峰值加速度与缓冲层厚度的变化满足指数函数关系;根据量纲分析原理得到缓冲层最大冲击深度与动能的平方成正比、与最大入射冲击力成反比的计算公式,且与实测值较吻合;入射冲击力在缓冲层内的衰减率随缓冲层厚度的增加以指数函数递增,在0.6 m缓冲层厚度下可使峰值冲击力衰减70%左右;随累积冲击能级的增大,RC板经历了弯曲起裂及扩展、次级弯曲裂纹和剪裂纹产生及跨中弯曲裂纹贯通的过程,试验结束时RC板整体表现出典型的弯曲破坏特征。     

Hydro-geochemistry of groundwater and surface water in Dschang town(West Cameroon): Alkali and alkaline-earth elements ascertain lithological and anthropogenic constraints

This study focuses on the sources of alkali and alkaline-earth elements based on the geochemistry of groundwater and surface water in Dschang concerning environmental and anthropogenic constraints. A comprehensive set of 50 samples from groundwater and surface water were analyzed by ICPMS and processed by spatial interpolation in a GIS environment. The results highlight a geochemical anomaly at the center of the densely inhabited area subject to a profusion of open dumps discharges. This anomaly with the highest spatial contents of Be(Cs, Rb, Mg) suggests an anthropogenic source that demarcates with the lowest alkali and alkaline-earth elements on the peripheral area of Dschang. Other findings include lithological constraints with volcanic rocks being the main source compared to granitoid.The study points out good correlations between Be, Cs, Rb and Mg spatial distributions and physicochemical parameters of waters(K, EC, TDS), and inversely with the lowest p H. p H is established as the most functioning physico-chemical constraint of alkali and alkaline-earth mobility in Dschang. The p H lowest values within the geochemical anomaly also highlight the impact of human activities on water acidity, which later enhance elements mobility and enrichment. Despite low elements contents relative to WHO standards, our findings point out an example of anthropogenic impact on water geochemistry linked to solid waste pollution; it also demonstrates significant anthropogenic changes of environmental physicochemical parameters of prime importance in the mobility and distribution of elements in the study area.Similar assessments should be extended in major towns in Cameroon.     

Implications of Japan’s long term climate mitigation target and the relevance of uncertain nuclear policy

Achieving long-term climate mitigation goals in Japan faces several challenges, starting with the uncertain nuclear power policy after the 2011 earthquake, the uncertain availability and progress of energy technologies, as well as energy security concerns in light of a high dependency on fuel imports. The combined weight of these challenges needs to be clarified in terms of the energy system and macroeconomic impacts. We applied a general equilibrium energy economic model to assess these impacts on an 80% emission reduction target by 2050 considering several alternative scenarios for nuclear power deployment, technology availability, end use energy efficiency, and the price of fossil fuels. We found that achieving the mitigation target was feasible for all scenarios, with considerable reductions in total energy consumption (39%–50%), higher shares of low-carbon sources (43%–72% compared to 15%), and larger shares of electricity in the final energy supply (51%–58% compared to 42%). The economic impacts of limiting nuclear power by 2050 (3.5% GDP loss) were small compared to the lack of carbon capture and storage (CCS) (6.4% GDP loss). Mitigation scenarios led to an improvement in energy security indicators (trade dependency and diversity of primary energy sources) even in the absence of nuclear power. Moreover, preliminary analysis indicates that expanding the range of renewable energy resources can lower the macroeconomic impacts of the long term target considerably, and thus further in depth analysis is needed on this aspect.

Key policy insights

• For Japan, an emissions reduction target of 80% by 2050 is feasible without nuclear power or CCS.

• The macroeconomic impact of such a 2050 target was largest without CCS, and smallest without nuclear power.

• Energy security indicators improved in mitigation scenarios compared to the baseline.

     

城市居民对乡村旅游影响的感知研究——以上海、南京为例

乡村旅游的发展必然会对乡村经济、社会文化和环境产生影响.以2006年9-11月在上海、南京两城市所作的700份问卷调查资料为基础,利用SPSS和Excel软件,定量分析了城市居民对乡村旅游影响的感知.结果表明:城市居民对乡村旅游影响正面感知强于负面感知;可分为中立者(37.3%)、理性支持者(37.8%)和矛盾支持者(24.9%)3类,支持者多于中立者;人口学特征不同,其感知存在一定差异.     

3S技术在神农架滑雪场生态环境影响评价中的应用

神农架滑雪场位于国家级自然保护区的边缘地带。运用景观生态学原理和方法,采用3S技术,对滑雪场景观生态体系的结构和功能状况进行评价,通过景观多样性指数、景观聚集度指数等指标量化计算及比较分析,预测了项目建成后对所在区域生态完整性的影响程度及将造成的敏感生态问题。结果表明,评价区自然系统的生物量将减少430.26 t,平均净生产力降低为881.55 g/m2.a,项目建设不会改变林地的模地地位,其对生态环境质量仍有较强的调控能力。3S技术结合景观生态学方法将生态环境影响评价由定性评价转向定量预测,为建设项目生态影响评价研究作了有益的探索。