轻放工作面坚硬顶板初次放顶矿压研究

针对柴里煤矿374①综放工作面坚硬顶板初次放顶难的问题,采取了强制放顶措施,同时进行矿压观测,了解初次放顶过程中矿压显现规律,采取有效安全措施,减少初次放顶带来的危害。     

碱金属离子及碱溶液对膨润土性能影响的研究进展

基于前人有关膨润土在碱性环境下的室内试验和数值模拟的研究结果 ,重点阐述了碱金属离子及碱溶液对膨润土矿物成分、微观结构、膨胀性和渗透性等方面的影响,讨论了温度、pH值与溶液浓度等对上述过程的影响。碱金属离子及碱性溶液不仅可交换膨润土中蒙脱石层间阳离子,而且可溶解膨润土中的蒙脱石,生成非膨胀性矿物,并随着温度和pH值升高,蒙脱石被溶解程度增加,从而导致了膨润土膨胀力减小,且随着温度、溶液浓度及pH值的增加,膨胀力削弱程度加强;同时,膨润土与碱金属离子及碱溶液接触时孔隙增多,进而渗透性增强,随着温度和溶液浓度增加,渗透性也明显增强。数值模拟可实现膨润土与碱性溶液长期接触时发生的矿物成分及渗透性变化的预测。高温、不同pH值的低碱性溶液及其耦合作用对膨润土的矿物化学成分、微观结构、膨胀力和渗透性的影响及机理研究应该是今后研究的重点。     

新疆东天山花岗岩类岩石形成的物理化学条件

通过对新疆东天山花岗岩类岩石中的角闪石、斜长石、碱性长石、磷灰石、黑云母成分的系统研究,确定花岗岩类岩石在11—17km深处结晶;无矿化、蚀变的二长花岗岩结晶温度约550℃,花岗闪长岩、石英二长岩的结晶温度为552—650℃,钠长石化的含矿二长花岗岩其二长石平衡温度均低于510℃,蚀变愈强烈,平衡温度愈低。二长花岗岩的起源温度为780—840℃,石英二长岩的起源温度为860—880℃,碱长花岗岩的起源温度最低。推算得到二长花岗岩的极限起源深度为28—32km,石英二长岩的极限起源深度为33—34km。HF,HCI逸度计算表明,它们趋向于岩浆晚阶段富集,但无论是早结晶的磷灰石,还是晚结晶的黑云母,总是钠长石化的含矿花岗岩低于正常无蚀变、无交代现象花岗岩的逸度值,正常花岗岩类岩石由黑云母指示的f_(HC(?)),f_(HF)分别为36.60—51.10kPa,1.20—1.60 kPa。花岗岩类岩石形成的fo_2为1.05×10~(-11)—3.11×10~(-11)Pa,而钠长石化的含矿二长花岗岩具最低的氧逸度,为1.48×10~(-17)—2.45×10~(-15)Pa。     

Conditions of pocket formation in the Oktyabrskaya tourmaline-rich gem pegmatite (the Malkhan field, Central Transbaikalia, Russia)

Coexisting melt (MI), fluid-melt (FMI) and fluid (FI) inclusions in quartz from the Oktaybrskaya pegmatite, central Transbaikalia, have been studied and the thermodynamic modeling of PVTX-properties of aqueous orthoboric-acid fluids has been carried out to define the conditions of pocket formation. At room temperature, FMI in early pocket quartz and in quartz from the coarse-grained quartz–oligoclase host pegmatite contain crystalline aggregates and an orthoboric-acid fluid. The portion of FMI in inclusion assemblages decreases and the volume of fluid in inclusions increases from the early to the late growth zones in the pocket quartz. No FMI have been found in the late growth zones. Significant variations of solid/fluid ratios in the neighboring FMI result from heterogeneous entrapment of coexisting melts and fluids by a host mineral. Raman spectroscopy, SEM EDS and EMPA indicate that the crystalline aggregates in FMI are dominated by mica minerals of the boron-rich muscovite–nanpingite CsAl₂[AlSi₃O₁₀](OH,F)₂ series as well as lepidolite. Topaz, quartz, potassium feldspar and several unidentified minerals occur in much lower amounts. Fluid isolations in FMI and FI have similar total salinity (4–8 wt.% NaCl eq.) and H₃BO₃ contents (12–16 wt.%). The melt inclusions in host-pegmatite quartz homogenize at 570–600 °C. The silicate crystalline aggregates in large inclusions in pocket quartz completely melt at 615 °C. However, even after those inclusions were significantly overheated at 650±10 °C and 2.5 kbar during 24 h they remained non-homogeneous and displayed two types: (i) glass+unmelted crystals and (ii) fluid+glass. The FMI glasses contain 1.94–2.73 wt.% F, 2.51 wt.% B₂O₃, 3.64–5.20 wt.% Cs₂O, 0.54 wt.% Li₂O, 0.57 wt.% Ta₂O₅, 0.10 wt.% Nb₂O₅, 0.12 wt.% BeO. The H₂O content of the glass could exceed 12 wt.%. Such compositions suggest that the residual melts of the latest magmatic stage were strongly enriched in H₂O, B, F, Cs and contained elevated concentrations of Li, Be, Ta, and Nb. FMI microthermometry showed that those melts could have crystallized at 615–550 °C.

Crystallization of quartz–feldspar pegmatite matrix leads to the formation of H₂O-, B- and F-enriched residual melts and associated fluids (prototypes of pockets). Fluids of different compositions and residual melts of different liquidus–solidus P–T-conditions would form pockets with various internal fluid pressures. During crystallization, those melts release more aqueous fluids resulting in a further increase of the fluid pressure in pockets. A significant overpressure and a possible pressure gradient between the neighboring pockets would induce fracturing of pockets and “fluid explosions”. The fracturing commonly results in the crushing of pocket walls, formation of new fractures connecting adjacent pockets, heterogenization and mixing of pocket fluids. Such newly formed fluids would interact with a primary pegmatite matrix along the fractures and cause autometasomatic alteration, recrystallization, leaching and formation of “primary–secondary” pockets.     

高温高压下石英砂岩的电导率实验研究

利用交流阻抗谱实验技术,在0.5~2.0 GPa、573~873 K和10-1~106 Hz条件下,借助YJ-3000t紧装式六面顶高压设备和Solartron-1260阻抗/增益-相位分析仪测定了石英砂岩的电导率。实验结果表明:在测定的频率范围,样品的复阻抗的实部、虚部、模和相角对频率有很强的依赖性。随着温度升高,电导率增大,lgσT与1/T之间符合Arrhenius线性关系。通过拟合计算,获得了表征样品电学性质的指前因子、活化焓、活化能、活化体积等物性参数。杂质离子导电机制对高温高压下石英砂岩的导电行为提供了合理的解释。     

The pressure dependence of the zirconium-in-rutile thermometer

The solubility of ZrO₂ in rutile is strongly temperature-dependent and has been identified as a potentially powerful thermometer when the rutile coexists with an appropriate buffer assemblage, e.g. zircon + quartz. In combination with experimental data at 10 kbar, previous consideration of data on natural rutile has not identified a pressure dependence for the thermometer. However, the expected volume change as a result of substitution of the larger Zr⁴⁺ cation for Ti⁴⁺ suggests that the Zr content of rutile should decrease with increasing pressure. To investigate the pressure dependence of the thermometer, piston cylinder (at 10, 20 & 30 kbar) and 1 atm furnace experiments were performed in the system ZrO₂-TiO₂-SiO₂. The solubility of ZrO₂ in rutile, in the presence of zircon and quartz was reversed at each pressure value. From these experiments, the thermodynamics of the end-member reaction ZrSiO₄ = SiO₂ + ZrO₂ (in rutile) have been determined. There is a secondary pressure effect accompanying the primary temperature dependence of the Zr content of rutile. New thermometer equations are, in the α -quartz field: in the β -quartz field and in the coesite field in which φ is ppm Zr, P is in kbar and R is the gas constant, 0.0083144 kJ K⁻¹. Thermometric results using these equations are shown for a range of geological settings.     

An infrared spectroscopic study of lawsonite to 20 GPa

The infrared spectrum of CaAl₂Si₂O₇ · H₂O-lawsonite, has been characterized to pressures of 20 GPa at 300 K. Our results constrain the response to compression of the silicate tetrahedra, hydroxyl units, and water molecules in this material. The asymmetric and symmetric stretching and bending vibrations of the Si₂O₇ groups (at zero pressure frequencies between 600 and 1000 cm⁻¹) increase in frequency with pressure at rates between 3.6 and 5.9 cm⁻¹/GPa. All silicate modes appear to shift continuously with pressure to 20 GPa, although the lowest frequency stretching vibration becomes unresolvable above 18 GPa, and a splitting of the main bending vibration is observed near this pressure. The O-H stretches of the hydroxyl units exhibit a discontinuity in their mode shifts at ∼8–9 GPa, which we interpret to be produced by a pressure-induced change in hydrogen bonding. The stretching and bending vibrations of the water molecule are relatively unaffected by compression to 20 GPa, thus demonstrating that the structural cavities in which water molecules reside are relatively rigid. Significant changes in the amplitude of the O-H stretches of the hydroxyl and water units are observed at this pressure as well; nevertheless, our results demonstrate that the dominant structural units in lawsonite persist metastably at 300 K with only modest structural modifications well beyond the known stability field of this phase. Received: 10 July 1998 / Revised, accepted: 23 October 1998     

辽东早元古代裂谷多金属硫铁矿地质及其成矿规律

辽东早元古代地层内赋存着一系列多金属硫铁矿床。矿床的形成与分布主要受裂谷盆地演化及含矿建造控制。在不同的演化阶段分别形成了含钴黄铁矿 含铜黄铁矿 含硬石膏黄铁矿矿床系列和含硼（镁电气石）磁黄铁矿 含铅锌黄铁矿 重晶石闪锌黄铁矿矿床系列。依据成矿特征可分为海底火山喷气沉积与海底喷气沉积两种成因类型。成矿作用受裂谷、次级盆地、一定含矿层位和特殊容矿岩石相互联系与配套的控矿因素制约。在对成矿规律研究的基础上将该区多金属硫铁矿划分为６个成矿远景区。     

Compressibility and swelling characteristics of Al-Khobar Palygorskite, eastern Saudi Arabia

Expansive soils are found in different locations in eastern Saudi Arabia. The area is arid with high temperatures, highly variable humidity and an excessive rate of evaporation compared to the low precipitation. This resulted in the formation of water sensitive soils. In the present investigation, line valve buildings for a sweet water feeder (1118 mm in diameter) were constructed on a highly expansive material consisting mainly of brown palygorskite and gray palygorskite with thin sheets of gypsum and limestone. Block samples from both palygorskites were brought to the laboratory and cores as well as remolded samples were obtained from the blocks. The two palygorskites were found to be highly plastic and have a very high swelling potential. The liquid limit (LL) and plastic limit (PL) values for the brown palygorskite are 261% and 140%, respectively. The gray palygorskite has a LL of a 285% and a PL of 123%. The oedometer free swell tests for the two palygorskites produced an expansion ranging between 31.8% and 42.5% for the remolded samples. However, the expansion for cores ranges between 8.3% and 19.3%. The constant volume pressure tests produced a stress in excess of 4240 kPa. The swell potential reached a steady state after four days while the swelling pressure reached a steady state in about 3 h. The paper addresses the geology of the area, the characterization of the geomaterial including mineralogical composition using X-ray diffraction and SEM techniques and the swelling characteristics of the material.     

C型采场支承压力分布特征的数值模拟研究

冲击地压的发生与支承压力的分布有重要关系。为研究C型采场支承压力的动态变化规律,采用FLAC3D软件对孤岛工作面推进过程中煤体垂直应力场进行了数值模拟。通过对工作面推进过程中煤体支承压力的平面分布特征、走向支承压力和倾斜支承压力的动态演化特征进行分析,得到以下结论：① 煤体中垂直应力分布呈“C”形;② 孤岛工作面超前支承压力影响距离为正常工作面的3～5倍;③ 双工作面“见方”时,支承压力峰值达到最大值。工程实例验证了结论的可靠性,其结果可为现场冲击地压预测和防治提供依据。