Evaporation of nebular fines during chondrule formation

Studies of matrix in primitive chondrites provide our only detailed information about the fine fraction (diameter <2 μm) of solids in the solar nebula. A minor fraction of the fines, the presolar grains, offers information about the kinds of materials present in the molecular cloud that spawned the Solar System. Although some researchers have argued that chondritic matrix is relatively unaltered presolar matter, meteoritic chondrules bear witness to multiple high-temperature events each of which would have evaporated those fines that were inside the high-temperature fluid. Because heat is mainly transferred into the interior of chondrules by conduction, the surface temperatures of chondrules were probably at or above 2000 K. In contrast, the evaporation of mafic silicates in a canonical solar nebula occurs at around 1300 K and FeO-rich, amorphous, fine matrix evaporates at still lower temperatures, perhaps near 1200 K. Thus, during chondrule formation, the temperature of the placental bath was probably >700 K higher than the evaporation temperatures of nebular fines. The scale of chondrule forming events is not known. The currently popular shock models have typical scales of about ¹⁰⁵ km. The scale of nebular lightning is less well defined, but is certainly much smaller, perhaps in the range 1 to 1000 m. In both cases the temperature pulses were long enough to evaporate submicrometer nebular fines. This interpretation disagrees with common views that meteoritic matrix is largely presolar in character and CI-chondrite-like in composition. It is inevitable that presolar grains (both those recognized by their anomalous isotopic compositions and those having solar-like compositions) that were within the hot fluid would also have evaporated. Chondrule formation appears to have continued down to the temperatures at which planetesimals formed, possibly around 250 K. At temperatures >600 K, the main form of C is gaseous CO. Although the conversion of CO to CH₄ at lower temperatures is kinetically inhibited, radiation associated with chondrule formation would have accelerated the conversion. There is now evidence that an appreciable fraction of the nanodiamonds previously held to be presolar were actually formed in the solar nebula. Industrial condensation of diamonds from mixtures of CH₄ and H₂ implies that high nebular CH₄/CO ratios favored nanodiamond formation. A large fraction of chondritic insoluble organic matter may have formed in related processes. At low nebular temperatures appreciable water should have been incorporated into the smoke that condensed following dust (and some chondrule) evaporation. If chondrule formation continued down to temperatures as low as 250 K this process could account for the water concentration observed in primitive chondrites such as LL3.0 and CO3.0 chondrites. Higher H₂O contents in CM and CI chondrites may reflect asteroidal redistribution. In some chondrite groups (e.g., CR) the Mg/Si ratio of matrix material is appreciably (30%) lower than that of chondrules but the bulk Mg/Si ratio is roughly similar to the CI or solar ratio. This has been interpreted as a kind of closed-system behavior sometimes called “complementarity.” This leads to the conclusion that nebular fines were efficiently agglomerated. Its importance, however is obscured by the observation that bulk Mg/Si ratios in ordinary and enstatite chondrites are much lower than those in carbonaceous chondrites, and thus that complementarity did not hold throughout the solar nebula.     

Size distributions of chondrules and dispersed droplets caused by liquid breakup: An application to shock wave conditions in the solar nebula

We present the results of an aerodynamic liquid dispersion experiment using initially molten silicate samples. We investigate the threshold of breakup and the size distribution of dispersed droplets. The breakup threshold is consistent with the previous experiments using water and a mixture of water and glycerol. Also, we confirm the previous results that the size distributions of dispersed droplets are represented by an exponential form and that the characteristic size of dispersed droplets is related to the dynamic pressure of high-velocity gas flow. The size distribution has a similar form to that of chondrules, though the experiment is not exactly corresponding to the shock heating models for chondrule formation that consider solid precursors which are molten by the shocks. The experimental results indicate that, if liquid chondrule-precursors were dispersed by high-velocity flow, the dynamic pressure of the flow is ∼10 kPa. A chondrule formation condition in a shock-wave heating model suggests that this pressure can be realized at the regions within ∼1 AU in the minimum solar-nebula mass models. However, if the nebula had a larger mass and gravitational instabilities occurred, this pressure may be realized in the spiral arms at 2-3 AU and chondrules may be formed in asteroid belt.     

Determination of rare earth and refractory trace element abundances in early solar system objects by ion microprobe

Experimental and analytical procedures devised for measurement of rare earth element (REE) abundances using a secondary ion mass spectrometer (ion microprobe) are described. This approach is more versatile than the conventional techniques such as neutron activation analysis and isotope dilution mass spectrometry by virtue of its high spatial resolution that allows determination of REE abundances in small domains (10-20 micron) within individual mineral phases. The ion microprobe measurements are performed at a low mass-resolving power adopting the energy-filtering technique (Zinner and Crozaz 1986) for removal and suppression of unresolved complex molecular interferences in the REE masses of interest. Synthetic standards are used for determining various instrument specific parameters needed in the data deconvolution procedure adopted for obtaining REE abundances. Results obtained from analysis of standards show that our ion microprobe may be used for determining REE abundances down to ppm range with uncertainties of ∼ 10 to 15%. Abundances of rare earth and several other refractory trace elements in a set of early solar system objects isolated from two primitive carbonaceous chondrites were determined using the procedures devised by us. The results suggest that some of these objects could be high temperature nebular condensates, while others are products of melting and recrystallization of precursor nebular solids in a high temperature environment.     

太阳原始星云原子团簇的初步研究

选用Ａｌｌｅｎｄｅ和宁强两块ＣＶ３陨石，在分子团簇串级飞行时间质谱装置上。用激光溅射模拟太阳原始星云在高能环境下的Ｓｉ－０，Ｆｅ－０和Ｍｇ－０原子团簇的形成和分布，对模拟过程所产上的原子团簇系列的结构和稳定性，以及可能的天体化学意义进行了初步探讨。     

Mineralogy and petrology of Al-rich objects and amoeboid olivine aggregates in the CH carbonaceous chondrite North West Africa 739

The aluminum-rich (>10 wt% Al₂O₃) objects in the CH carbonaceous chondrite North West Africa (NWA) 739 include Ca,Al-rich inclusions (CAIs), Al-rich chondrules, and isolated mineral grains (spinel, plagioclase, glass). Based on the major mineralogy, 54 refractory inclusions found in about 1 cm² polished section of NWA 739 can be divided into hibonite-rich (16%), grossite-rich (26%), melilite-rich (28%), spinel-pyroxene-rich (16%) CAIs, and amoeboid olivine aggregates, (AOA's, 17%). Most CAIs are rounded, 25–185 μm (average=70 μm) in apparent diameter, contain abundant, tiny perovskite grains, and typically surrounded by a single- or double-layered rim composed of melilite and/or Al-diopside; occasionally, layers of spinel+hibonite and forsterite are observed. The AOAs are irregularly shaped, 100–250 μm (average=175 μm) in size, and consist of forsterite, Fe,Ni-metal, and CAIs composed of Al-diopside, anorthite, and minor spinel. One AOA contains compact, rounded melilite-spinel-perovskite CAIs and low-Ca pyroxene replacing forsterite. The Al-rich (>10 wt% bulk Al₂O₃) chondrules are divided into Al-diopside-rich and plagioclase-rich. The Al-diopside-rich chondrules, 50–310 μm (average=165 μm) in apparent diameter, consist of Al-diopside, skeletal forsterite, spinel, ±Al-rich low-Ca pyroxene, and ±mesostasis. The plagioclase-rich chondrules, 120–455 μm (average=285 μm) in apparent diameter, are composed of low-Ca and high-Ca pyroxenes, forsterite, anorthitic plagioclase, Fe,Ni-metal nodules, and mesostasis. The isolated spinel occurs as coarse, 50–125 μm in size, subhedral grains, which are probably the fragments of Al-diopside chondrules. The isolated plagioclase grains are too coarse (60–120 μm) to have been produced by disintegration of chondrules or CAIs; they range in composition from nearly pure anorthite to nearly pure albite; their origin is unclear. The Al-rich objects show no evidence for Fe-alkali metasomatic or aqueous alteration; the only exception is an Al-rich chondrule fragment with anorthite replaced by nepheline. They are texturally and mineralogically similar to those in other CH chondrites studied (Acfer 182, ALH85085, PAT91467, NWA 770), but are distinct from the Al-rich objects in other chondrite groups (CM, CO, CR, CV). The CH CAIs are dominated by very refractory minerals, such as hibonite, grossite, perovskite and gehlenitic melilite, and appear to have experienced very low degrees of high-temperature alteration reactions. These include replacement of grossite by melilite, of melilite by anorthite, diopside, and spinel, and of forsterite by low-Ca pyroxene. Only a few CAIs show evidence for melting and multilayered Wark-Lovering rims. These observations may suggest that CH CAIs experienced rather simple formation history and escaped extensive recycling. In order to preserve the high-temperature mineral assemblages, they must have been efficiently isolated from the hot nebular region, like some chondrules and the zoned Fe,Ni-metal grains in CH chondrites.     

太阳星云凝聚过程的岩石学模型：（Ⅱ）非球陨石、C1陨石及类C1陨石的凝聚成因和小行星区星云凝聚作用

综述了非球陨石（铁陨石，石铁陨石和无球粒陨石）在成分结构方面的非分异成因证据，推断其成因是：星云盘中心层中的星云发生气－液凝聚作用形成的熔滴，在较高温度下彼此合并形成了较大熔体，熔体固化后形成该类陨石母体。根据Ｃ１陨石不含球粒和其它成分特征，推断它们是星云只发生气－固凝聚作用的产物。对近年来新发现的一些特殊成分的碳质球粒陨石进行了综合分析，暂定名为类Ｃ１陨石。通过类Ｃ１陨石与其它球粒陨石及Ｃ１陨石成分结构特征的对比，推断它们是星云盘边缘层星云发生气－液－固和气－固联合凝聚作用，同时发生水化作用的产物。最后，在对所有陨石凝聚成因进行解释的基础上，建立了小行星区星云凝聚模型。     

Accretion among preplanetary bodies: The many faces of runaway growth

When preplanetary bodies reach proportions of ∼1 km or larger in size, their accretion rate is enhanced due to gravitational focusing (GF). We have developed a new numerical model to calculate the collisional evolution of the gravitationally-enhanced growth stage. The numerical model is novel as it attempts to preserve the individual particle nature of the bodies (like N-body codes); yet it is statistical in nature since it must incorporate the very large number of planetesimals. We validate our approach against existing N-body and statistical codes. Using the numerical model, we explore the characteristics of the runaway growth and the oligarchic growth accretion phases starting from an initial population of single planetesimal radius R₀. In models where the initial random velocity dispersion (as derived from their eccentricity) starts out below the escape speed of the planetesimal bodies, the system experiences runaway growth. We associate the initial runaway growth phase with increasing GF-factors for the largest body. We find that during the runaway growth phase the size distribution remains continuous but evolves into a power-law at the high-mass end, consistent with previous studies. Furthermore, we find that the largest body accretes from all mass bins; a simple two-component approximation is inapplicable during this stage. However, with growth the runaway body stirs up the random motions of the planetesimal population from which it is accreting. Ultimately, this feedback stops the fast growth and the system passes into oligarchy, where competitor bodies from neighboring zones catch up in terms of mass. We identify the peak of GF with the transition between the runaway growth and oligarchy accretion stages. Compared to previous estimates, we find that the system leaves the runaway growth phase at a somewhat larger radius, especially at the outer disk. Furthermore, we assess the relevance of small, single-size fragments on the growth process. In classical models, where the initial velocity dispersion of bodies is small, these do not play a critical role during the runaway growth; however, in models that are characterized by large initial relative velocities due to external stirring of their random motions, a situation can emerge where fragments dominate the accretion, which could lead to a very fast growth.     

On the mean oxygen isotope composition of the Solar System

Since the first discovery of extraordinary oxygen isotope compositions in carbonaceous meteorites by Clayton et al. [Clayton, R.N., Grossman, L., Mayeda, T.K., 1973. Science 182, 485-488], numerous studies have been done to explain the unusual mass-independent isotope fractionation, but the problem is still unresolved to this day. Clayton's latest interpretation [Clayton, R.N., 2002. Nature 415, 860-861] sheds new light on the problem, and possible hypotheses now seem to be fairly well defined. A key issue is to resolve whether the oxygen isotopes in the Solar System represented by the Sun (solar oxygen) are the same as oxygen isotopes in planetary objects such as bulk meteorites, Mars, Earth, and Moon, or whether the solar oxygen is more similar to the lightest oxygen isotopes observed in CAIs (Calcium Aluminum-rich Inclusions) in primitive meteorites. Here, we examined the problem using oxygen isotope analytical data of about 400 bulk meteorite samples of various classes or types (data compiled by K. Lodders). We used in our discussion exclusively the parameter , a direct measure of the degree of mass-independent isotope fractionation of oxygen isotopes. When is arranged according to a characteristic size of their host planetary object, it shows a systematic trend: (1) values scatter around zero; (2) the scatter from the mean () decreases with increasing representative size of the respective host planetary object. This systematic trend is easily understood on the basis of a hierarchical scenario of planetary formation, that is, larger planetary objects have formed by progressive accretion of planetesimals by random sampling over a wide spectrum of proto-solar materials. If this progressive random sampling of planetesimals were the essential process of planetary formation, the isotopic composition of planetary oxygen should approach that of the solar oxygen. To test this random sampling hypothesis, we applied a multiscale, multistep bootstrap statistical method [Shimodaira, H., 2004. Ann. Statist. 32, 2616-2641] to the meteorite oxygen isotope data, and deduced a σ-N relation, where σ is the standard deviation of , and N is the representative size of a host planetary object. If we assign 200 and 500 km as a representative sizes of the chondrite and achondrite parent bodies, the observed σ of agree well with the values predicted by the σ-N relation. A common mean value of for all planetary objects also agrees with the progressive random sampling process. Therefore, we conclude that the solar oxygen is the same as planetary oxygen, but differs from CAI oxygen. The conclusion implies that a massive enrichment in ¹⁷O and ¹⁸O resulting from CO self-shielding, a current influential interpretation of CAI-O, did not occur.     

Origin of three-dimensional shapes of chondrules: I. Hydrodynamics simulations of rotating droplet exposed to high-velocity rarefied gas flow

The origin of three-dimensional shapes of chondrules is an important information to identify their formation mechanism in the early solar nebula. The measurement of their shapes by using X-ray computed topography suggested that they are usually close to perfect spheres, however, some of them have rugby-ball-like (prolate) shapes [Tsuchiyama, A., Shigeyoshi, R., Kawabata, T., Nakano, T., Uesugi, K., Shirono, S., 2003. Lunar Planet. Sci. 34, 1271-1272]. We considered that the prolate shapes reflect the deformations of chondrule precursor dust particles when they are heated and melted in the high velocity gas flow. In order to reveal the origin of chondrule shapes, we carried out the three-dimensional hydrodynamics simulations of a rotating molten chondrule exposed to the gas flow in the framework of the shock-wave heating model for chondrule formation. We adopted the gas ram pressure acting on the chondrule surface of in a typical shock wave. Considering that the chondrule precursor dust particle has an irregular shape before melting, the ram pressure causes a net torque to rotate the particle. The estimated angular velocity is for the precursor radius of r₀=1 mm, though it has a different value depending on the irregularity of the shape. In addition, the rotation axis is likely to be perpendicular to the direction of the gas flow. Our calculations showed that the rotating molten chondrule elongates along the rotation axis, in contrast, shrinks perpendicularly to it. It is a prolate shape. The reason why the molten chondrule is deformed to a prolate shape was clearly discussed. Our study gives a complementary constraint for chondrule formation mechanisms, comparing with conventional chemical analyses and dynamic crystallization experiments that have mainly constrained the thermal evolutions of chondrules.     

Conditions for collisional growth of a grain aggregate

Collisional growth of grain aggregates is a critical process in the early stage of planet formation. A collision between grain aggregates is numerically simulated by means of a smoothed particle hydrodynamic code, treating a grain aggregate as a continuum media. A model for mechanical response of a grain aggregate is developed based on published experimental data. Free parameters of the model are the bulk modulus, compressive, shear, and tensile strengths of a grain aggregate, and impact velocity. I have determined three conditions for the growth of an aggregate within the mechanical response model. (1) Compressive strength is the smallest among the three components of strengths. (2) Impact velocity is as low as 4% of the sound speed of an aggregate. (3) Effective restoration of the strengths is necessary due to reconnection between grains followed by compaction of an aggregate. Possibilities of these conditions in the solar nebula are discussed.