Effective macroscopic transport parameters between parallel plates with constant concentration boundaries

A macroscopic transport model is developed, following the Taylor shear dispersion analysis procedure, for a 2D laminar shear flow between parallel plates possessing a constant specified concentration. This idealized geometry models flow with contaminant dissolution at pore-scale in a contaminant source zone and flow in a rock fracture with dissolving walls. We upscale a macroscopic transient transport model with effective transport coefficients of mean velocity, macroscopic dispersion, and first-order mass transfer rate. To validate the macroscopic model the mean concentration, covariance, and wall concentration gradient are compared to the results of numerical simulations of the advection–diffusion equation and the Graetz solution. Results indicate that in the presence of local-scale variations and constant concentration boundaries, the upscaled mean velocity and macrodispersion coefficient differ from those of the Taylor–Aris dispersion, and the mass transfer flux described by the first-order mass transfer model is larger than the diffusive mass flux from the constant wall. In addition, the upscaled first-order mass transfer coefficient in the macroscopic model depends only on the plate gap and diffusion coefficient. Therefore, the upscaled first-order mass transfer coefficient is independent of the mean velocity and travel distance, leading to a constant pore-scale Sherwood number of 12. By contrast, the effective Sherwood number determined by the diffusive mass flux is a function of the Peclet number for small Peclet number, and approaches a constant of 10.3 for large Peclet number.     

Stochastic assessment of GPS carrier phase measurements for precise static relative positioning

 Global positioning system (GPS) carrier phase measurements are used in all precise static relative positioning applications. The GPS carrier phase measurements are generally processed using the least-squares method, for which both functional and stochastic models need to be carefully defined. Whilst the functional model for precise GPS positioning is well documented in the literature, realistic stochastic modelling for the GPS carrier phase measurements is still both a controversial topic and a difficult task to accomplish in practice. The common practice of assuming that the raw GPS measurements are statistically independent in space and time, and have the same accuracy, is certainly not realistic. Any mis-specification in the stochastic model will inevitably lead to unreliable positioning results. A stochastic assessment procedure has been developed to take into account the heteroscedastic, space- and time-correlated error structure of the GPS measurements. Test results indicate that the reliability of the estimated positioning results is improved by applying the developed stochastic assessment procedure. In addition, the quality of ambiguity resolution can be more realistically evaluated. Received: 13 February 2001 / Accepted: 3 September 2001     

地震面波产生的地震动转动分量研究

本文利用弹性波动理论对地面转动分量，即瑞利（Rayleigh)波和乐夫（Love)波产生的转动分量进行了研究，给出了相应的计算公式和计算方法，特别注意到面波的散射效应对转动分量的影响，并将这一特性引入到转动分量的求取中，使问题的解决更切合于实际，最后选取实际地震记录，利用得到的公式计算出地震面波产生的转动分量。     

Health Risks and Environmental Inequity: A Geographical Analysis of Accidental Releases of Hazardous Materials

This study examines the spatial distribution and impact of nonroutine accidental releases of hazardous materials relative to the demographic composition of residents in nearby communities. First, atmospheric dispersion modeling methods are used to delineate the impact zones of worst‐case accidents in two New York counties over the last ten years. Next, using accidental reports for 1997, GIS and statistical operations are used at the census tract level of the two counties to determine whether these incidents disproportionately affected disadvantaged neighborhoods. The results suggest that the areas of high‐impact from accidental releases of hazardous materials are best characterized by a large proportion of families below the poverty line, Hispanics, and other minorities.     

Normal Point Algorithm For Reduction Of Two Colour Slr Observations

Two colour laser ranging to artificial satellites is an attractivetechnique, which is capable to provide refraction corrected ranges without the need of an atmospheric model by measuring the dispersive delay of laser pulses of different wavelength. Although the required accuracy of the detection scheme is stringent, the technique has matured so far, that routine two colour observationsbecame feasible.The present paper describes a normal point procedure reducing two colour laser range observations with respect to the dispersive delay,exploiting the knowledge of satellite response signatures in conjunction with detector characteristics and the appropriate center of mass correction models.Moreover the dispersion model of the atmosphere is briefly reviewed, paying attention to the wavelength domains provided by modern twocolour ranging lasers, e.g., the Ti:SAP laser.Preliminary data is presented and compared to both, normal point data reduced with a standard procedure and zenith path equivalent meteorological parameters.     

Phosphorus oxynitride PON, a silica analogue: structure and compression of the cristobalite-like phase; P –T phase diagram

 The structure of the cristobalite-like polymorph of phosphorus oxynitride PON has been refined using neutron powder diffraction data. It is tetragonal, space group I&4macr;2d, Z=4. The four P–(O,N) distances are equal but the tetrahedron is compressed along c. In AX₂ or ABX₄ compounds, the tetragonal I&4macr;2d or I&4macr; structure is obtained when the average ratio of the cation to anion radius is below 1.186, whereas the tetragonal P4₁2₁2 or orthorhombic C222₁ structure is obtained at low temperatures for larger ratios. The cell parameters of this PON polymorph have been determined as a function of hydrostatic pressure by in situ angle dispersive X-ray powder diffraction in a diamond-anvil cell. Under truly hydrostatic pressure, a strong anisotropic behavior is observed with the c parameter being nearly incompressible. Very slight anisotropic stress strongly modifies the high-pressure behavior. According to the pressure-temperature conditions of treatment, three phases, cristobalite-, moganite-, and quartz-like, have been obtained by quenching experiments, and the P–T phase diagram of PON was derived. The high-pressure behavior of the α-quartz, moganite, and cristobalite-like polymorphs of PON and SiO₂ is discussed. Received: 7 August 2000 / Accepted: 21 January 2001     

GPS接收机天线相位中心偏差的检测

GPS接收机天线相位中心偏差是指GPS天线接收卫星信号的电气中心与基机械几何中心之差。在高精度测量中，这是不容忽视的。讨论了采用基线测量相对测定法确定天线相位中心在水平和垂直方向上的偏差的原理和方法，并给出了测量结果及建议。     

THE FOUNDATION AND MOVEMENT OF TROPICAL SEMI-GEOSTROPHIC ADAPTATION

The breakdown and foundation of geostrophic balance is one of the important movements inthe mid-and high-latitude atmosphere and oceans.In the tropical area,the value of Coriolis pa-rameter is so small that it is difficult to satisfy the bi-geostrophic equilibrium between the pressureand velocity fields.However,in the tropical area,the zonal velocity of some motions in the atmo-sphere and oceans is large,so the Coriolis force is not small,geostrophic balance can exist in zonaldirection,i.e.semi-geostrophic balance.Furthermore,in the dominant area of Hadley circulationin the atmosphere or the area near the ocean meridional boundary,the meridional velocity is large,so geostrophic balance can also exist in meridional direction.In this paper,the process of the dis-persion of inertial gravity wave and the foundation of semi-geostrophic balance are first discussed.Second,the adjustment process between the velocity and pressure fields after adaptation is alsoviewed,and the scale criterion of the semi-geostrophic adaptation is discussed,i.e.for the motionwith meridional scale greater than the equatorial Rossby radius of deformation,the velocity andpressure fields after adaptation change to fit the initial pressure field;on the contrary,the fieldschange to fit the initial zonal velocity field,and the strength of the fields after adaptation dependson the zonal scale.     

高分辨区域输送模式中不同输送格式的对比试验

本文对两种输送格式在理论试验的基础上，引入19层高分辨区域输送模式EM3，由中尺度模式（MM4)提供实例输送风场，积分至13、18、30、50、70小时，作分析和对比数值试验。采用的两种格式是:二阶动量矩守恒的Prather格式（以下简称为SOM)及通量订正的Smolar格式。数值试验结果表明，高精度的SOM格式使数值扩散减小一个量级， 使输送物质（SO#-[2])中心浓度比Smolar格式增大3～4倍， 采用SOM格式还明显改进了浓度中心水平平均运动轨迹的模拟精度，选择高精度的平流格式是改进模拟结果的重要途径。     

Modifications of the dispersion relations for surface waves in a layer on a half-space

Summary Dispersion relations for Love and Rayleigh waves in a layer on a half-space are modified by introducing quadratic slownesses instead of velocities. The advantages of this approach are demonstrated on analytical formulae for computing the group velocity.