应用综合勘查方法分析平朔安太堡三号井工矿突水原因

平朔公司安太堡三号井工矿2007年3月在首采工作面辅运顺槽掘进时,迎头冒顶突水,初期突水量达6000～8000m^3/d,将1289．16m标高以下淹没。在分析研究区地层、构造及水文地质条件的基础上,对沙沟河道进行了渗漏观测,对地表排污水、沟水和井下突水点的水质进行了分析化验,有针对性的布置了6条物探线,最后进行了钻孔验证,综合分析认为突水水源主要为大沙沟河道的侧向补给,突水通道为NW向的强风化带。提出了加大井下排水,地表对大沙沟河进行土工膜防渗处理的综合治理措施。     

努力提高三维地震勘探精度，为西部煤炭工业做出新贡献

以国家重大产业技术开发专项“西部煤炭资源高精度三维地震勘探技术”项目的由来、意义和总体研究目标为引,概括的介绍了项目依托工程中各个专项技术研究完成情况,并对非均匀介质成像技术、高精度三维地震静校正技术、高密度采集技术、特观技术、岩性反演技术、属性体解释技术等六项重大关键技术取得的突破性进展进行了重点说明。指出随着我国煤炭生产重点的逐步西移,应加强诸如叠前、叠后深度偏移技术的研究,以解决复杂山区三维地震面元内地震反射波散射问题,提高其三维地震勘探精度,为西部煤炭工业做出新贡献!     

临港新城地质特征及其对新城规划与建设的影响分析

结合临港新城三维地质调查所取得的成果,分析了该城区地质特征及对新城建设的影响,为新城规划建设提供科学依据和服务。     

三维地震小面元采集技术在晋城矿区的应用

依托“西部煤炭资源高精度三维地震勘探技术”工程,对晋城矿区进行了旨在提高小断层,小陷落柱探测能力的高密度三维地震勘探。根据面元选择因素及该区地质任务,采用5m×5m网格进行野外数据采集;考虑炮检距、方位角、覆盖次数、排列片横纵比及煤层埋深（350～500m）等因素,采用中点放炮、60道接收,24次覆盖（横向4次,纵向6次）的8线16炮束状观测系统,基岩中激发。原始资料经同一处理流程后,获得5m×5m×1ms、5m×10m×1ms、10m×10m×1ms及2.5m×2.5m×1ms不同单元的三维数据体多个,通过对比可以发现小断层,小陷落柱在其小面元叠加时间剖面、顺层切片及相干切片都有清晰的反映。实例说明,小面元采集技术可以提高对小构造的纵、横向分辨能力,满足山区对三维地震精确勘探的要求。     

小面元三维地震勘探技术在西山屯兰矿南五采区的应用

屯兰矿南五采区地形复杂,最大高差达271m,地表大面积为第四系黄土覆盖,激发困难。为探索研究小面元三维地震勘探技术的应用效果。在常规三维地震勘区域内划出1km^2,采用5m×5m小面元进行采集。在地震数据采集过程中,采取了加大激发井深、提高覆盖次数、减小CMP面元网格和加大接收排列等技术措施,做到“四小三高、二中一深、两个等高面”。通过插值、抽线及扩大面元处理。获得2．5m×2．5m×1ms、5m×5m×1ms、5m×10m×1ms、10m×10m×1ms以及不同叠加次数的三维数据体。资料解释工作主要是在5m×5m×1ms、2．5m×2．5m×1ms两个数据体上进行,解释落差大于或等于5m的断层6条,落差3～5m的断层8条;查明长轴直径20～30m的陷落柱4个。30～100m的陷落柱1个,大于100m的陷落柱3个。与相邻区常规三维地震比较,小面元三维地震勘探有利于对小陷落柱、小断层的控制和解释。     

Rate constants for the reactions of the NO3 radical with HCOOH/HCOO− and CH3COOH/CH3COO− in aqueous solution between 278 and 328 K

The kinetics of the aqueous phase reactions of NO₃ radicals with HCOOH/HCOO^– and CH₃COOH/CH₃COO^– have been investigated using a laser photolysis/long-path laser absorption technique. NO₃ was produced via excimer laser photolysis of peroxodisulfate anions (S₂O ₈ ^2– ) at 351 nm followed by the reactions of sulfate radicals (SO ₄ ^– ) with excess nitrate. The time-resolved detection of NO₃ was achieved by long-path laser absorption at 632.8 nm. For the reactions of NO₃ with formic acid (1) and formate (2) rate coefficients ofk ₁=(3.3±1.0)×10⁵ l mol^–1 s^–1 andk ₂=(5.0±0.4)×10⁷ l mol^–1 s^–1 were found atT=298 K andI=0.19 mol/l. The following Arrhenius expressions were derived:k ₁(T)=(3.4±0.3)×10¹⁰ exp[–(3400±600)/T] l mol^–1 s^–1 andk ₂(T)=(8.2±0.8)×10¹⁰ exp[–(2200±700)/T] l mol^–1 s^–1. The rate coefficients for the reactions of NO₃ with acetic acid (3) and acetate (4) atT=298 K andI=0.19 mol/l were determined as:k ₃=(1.3±0.3)×10⁴ l mol^–1 s^–1 andk ₄=(2.3±0.4)×10⁶ l mol^–1 s^–1. The temperature dependences for these reactions are described by:k ₃(T)=(4.9±0.5)×10⁹ exp[–(3800±700)/T] l mol^–1 s^–1 andk ₄(T)=(1.0±0.2)×10¹² exp[–(3800±1200)/T] l mol^–1 s^–1. The differences in reactivity of the anions HCOO^– and CH₃COO^– compared to their corresponding acids HCOOH and CH₃COOH are explained by the higher reactivity of NO₃ in charge transfer processes compared to H atom abstraction. From a comparison of NO₃ reactions with various droplets constituents it is concluded that the reaction of NO₃ with HCOO^– may present a dominant loss reaction of NO₃ in atmospheric droplets.     

LonGSp: A near infra-red spectrometer

We present a new cooled grating near infra-red spectrometer designed to acquire spectra at the TIRGO telescope in the 0.9÷2.5m region with a resolving power of 300÷4000, equipped with a Rockwell NICMOS 3 detector.     

Latitudinal variation of measured O3 photolysis frequencies J(O1D) and primary OH production rates over the Atlantic Ocean between 50° N and 30° S

The latitudinal variation of the photolysis frequency of ozone to O(¹D) atoms, J(O¹D), was measured using a filter radiometer during the cruise ANT VII/1 of the research vessel Polarstern in September/October 1988. The J(O¹D) noon values exhibited a maximum of 3.6×10^-5 s^-1 (2 sr) at the equator and decreased strongly towards higher latitudes. J(O¹D) reached highest values for clean marine background air with low aerosol load and almost cloudless sky. The J(O¹D) data, measured under these conditions and a temperature of 295 K, can be expressed by: % MathType!MTEF!2!1!+-% feaafiart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaamOsaiaacI% cacaqGpbWaaWbaaSqabeaaiiaacqWF8baFaaGccaqGebGaaeykaiaa% bccacqWF9aqpcaqGGaGaaeyzaiaabIhacaqGWbGaaeiiaiaabUhacq% GHsislcaaI4aGaaiOlaiaaicdacaaIYaGaeyOeI0IaaGioaiaac6ca% caaI4aGaaiiEaiaaigdacaaIWaWaaWbaaSqabeaacqGHsislcaaIZa% aaaOGaaeiiaiaabIhacaqGGaGaam4uaiabgUcaRiaaiodacaGGUaGa% aGinaiaacIhacaaIXaGaaGimamaaCaaaleqabaGaeyOeI0IaaGOnaa% aakiaadofadaahaaWcbeqaaiaaikdaaaGccaGG9bGaaeikaiaaboha% daahaaWcbeqaaiabgkHiTiaaigdaaaGccaGGPaaaaa!5EE9!\[J({\text{O}}^| {\text{D) }} = {\text{ exp \{ }} - 8.02 - 8.8x10^{ - 3} {\text{ x }}S + 3.4x10^{ - 6} S^2 \} {\text{(s}}^{ - 1} )\] where S represents the product of the overhead ozone column (DU) and the secant of the solar zenith angle. The meridional profile of the primary OH radical production rate P(OH) was calculated from the J(O¹D) measurements and simultaneously recorded O₃ and H₂O mixing ratios. While the latitudinal distribution of J(O¹D) and water vapour was nearly symmetric to the equator, high tropospheric ozone levels up to 40 ppb were observed in the Southern Hemisphere, SH, resulting in higher P(OH) in the SH.     

Trace gas exchange at the air/water interface: Measurements of mass accommodation coefficients

A liquid jet of 90 m diameter and variable length has been utilized to determine absorption rates and, hence, mass accommodation coefficients , of atmospheric trace gases. The compounds investigated are HCl (0.01), HNO₃ (0.01), N₂O₅ (0.005), peroxyacetyl nitrate (>0.001), and HONO (0.005). It is concluded that the absorption of these trace gases by liquid atmospheric water is not significantly retarded by interfacial mass transport. The strengths and limitations of the liquid jet technique for measuring mass accommodation coefficients are explored.