Geochemical diagenetic trends during phosphorite formation – economic implications: The case of the Negev Campanian phosphorites,Southern Israel

Research on the Upper Campanian (Upper Cretaceous) Negev phosphorites (Mishash Formation), based on microprobe analyses, Fourier Transform Infrared spectroscopy, wet chemistry, microtextural (Scanning Electron Microscopy) studies and mineralogical analyses, together with quantified rates of sedimentation and P accumulation, enables the chemistry of these rocks to be better constrained across the Negev area and allows their suitability for the manufacture of P fertilizers to be better determined. Two phosphorite facies are differentiated: (i) a pristine phosphorite facies of low P content, more typical of basinal sections and (ii) a reworked, granular phosphorite facies commonly enriched in P, found predominantly near palaeo‐highs and forming most of the economic phosphates. The distribution of F/P₂O₅, CO₂/F, U(IV), Cd, Zn and other trace metals (Mo, Ni, Cr, Cu, V and Y), rare‐earth elements concentration, Ce and Eu anomalies and heavy rare earth elements enrichment, are controlled by these two facies. F/P₂O₅ in carbonate‐fluorapatite is much lower (0·090 to 0·107) in the pristine than in the reworked facies (0·107 to 0·120); in addition, the lower F/P₂O₅ in the pristine facies is coupled with: (i) higher Cd, Zn, Mo, Ni, Cr, Cu and V concentrations; (ii) a considerably reduced (< 10%) U(IV) fraction of total U; (iii) lower rare earth elements/P₂O₅ and Y/P₂O₅ ratios; (iv) less negative Ce and Eu anomalies and lower heavy rare earth elements (Lu/La) enrichment; (v) an increase in Fe‐rich smectites in the clay fraction; and (vi) presence of OH in the carbonate‐fluorapatite structure. Sedimentary reworking of previously formed pristine phosphate, together with its redeposition near structural highs in more oxic bottom conditions, results in considerable diagenetic changes in the chemistry of the phosphorites, making them more suitable for economic exploitation. The results presented here provide geochemical criteria for identifying pristine phosphate in other phosphorite sequences and may help to better locate phosphate strata chemically suitable for the phosphate industry elsewhere.     

中国边缘海域及其邻区的岩石层结构与构造分析

利用中国边缘海域近年的地震层析成像结果,根据速度异常和各向异性分析东海、黄海和南海北部的岩石层结构和构造,讨论中朝块体和扬子块体在黄海内部的拼合边界(黄海东部断裂带)、东海陆架盆地上地幔异常与岩石层形成演化、南海北部地壳底部高速层的成因及地幔活动等问题。分析表明,黄海东部与朝鲜半岛之间存在一个深部构造界限(大致对应于黄海东部断裂带),分界两侧Pn波速度各向异性存在明显差异,反映不同构造应力和断裂剪切运动作用下的岩石层地幔变形特征。东海陆架下方的低速异常揭示了张裂盆地形成时期的地幔活动痕迹,表明中、新生代期间发生过地幔上涌并造成岩石层减薄,菲律宾海板块向西俯冲引发的地幔活动对东海陆架岩石层的形成、演化产生明显的影响。南海北部岩石层厚度较大并且温度相对偏低,地幔异常仅限于局部地区,估计南海北部大陆边缘的地壳底部高速层形成于张裂发生之前,或者是地壳形成时期壳幔分异时的产物。南海中央海盆的扩张不仅导致地壳拉张,软流层物质上涌,而且也造成岩石层地幔减薄甚至缺失。     

桂林毛村岩溶区和非岩溶区牧草养分动态的对比研究

通过进行岩溶区和非岩溶区牧草田间对比试验,测定植被在生长季内( 6- 8月)的养分动态变化,并结合N / P化学计量学的原理和方法,研究了岩溶区牧草的养分限制状况。结果表明: ( 1)在生长季节的6- 8月,岩溶区4种牧草N、P养分浓度都具有显著的随月份的增长而减少的趋势。从岩溶区和非岩溶区所测定的4种牧草养分结果来看,岩溶区牧草的N素平均值为22. 79 mg /g ,非岩溶区牧草的N素略小于岩溶区,为22. 15 mg /g ;岩溶区的P素平均值为6. 03 mg /g ,非岩溶区牧草的P素小于岩溶区,为5. 35 mg /g。( 2)无论是岩溶区还是非岩溶区,牧草的N /P与N 的相关性最大,相当系数都大于0. 6,与非岩溶区不同的是,岩溶区牧草的N /P与Ca 的相关性也很大,而非岩溶区的则较小。( 3)岩溶区牧草植物体Ca、Mg总含量分别是非岩溶区的2和1. 5倍。不同种类的牧草对Ca、Mg 的吸收和累积能力有较大的差异,本研究中的类玉米其钙含量远远小于其它3种牧草的钙含量。      

河流对0.8 Ma B.P.环境突变事件的地貌响应研究

以兰州盆地0.8 Ma B.P.阶地为例证,运用古地磁测年方法,通过收集相关文献,分析讨论了0.8 Ma B.P.阶地与0.8 Ma B.P.环境突变事件的联系。结果表明：① 0.8 Ma B.P.环境突变事件主要表现在气候转型、构造运动等方面,具有群发性和全球性特点;② 兰州盆地以及其他区域0.8 Ma B.P.阶地存在的证据,表明河流在0.8 Ma B.P. 前后普遍发生过一次下切事件;③ 0.8 Ma B.P.阶地是河流对0.8 Ma B.P.环境突变事件的地貌响应,构造运动为提供了下切驱动力,而气候变化则控制了下切时间。     

Effects of N:P ratio of Artemisia ordosica on growth influenced by soil calcium carbonate

Soil calcium carbonate(CaCO_3) has a strong solid phosphorus effect, and high content of CaCO_3 can significantly reduce the effectiveness of soil phosphorus. To reveal the limiting effect of soil CaCO_3 on the growth of plants on sand land and its mechanism of plant physiology, we performed pot experiments with a two-factor randomized block design and a three-factor orthogonal design for different soil CaCO_3 content treatments using Artemisia ordosica seedlings. In the experiments, we surveyed plant height, aboveground biomass, root length and root weight and analyzed N, P concentrations and RNA content of the seedlings, and discussed the relationships between relative growth rate(RGR) of the seedlings and N:P ratio as well as RNA. Results show that, the RGRs of plant height and above-ground biomass of the seedlings decreased significantly with the increase of soil CaCO_3 content, and those for root length and root weight decreased. The RGRs of plant height and above-ground biomass of the seedlings were significantly negatively correlated with leaf N:P ratios, but significantly positively correlated with leaf RNA content and leaf P concentrations. It can be seen that soil CaCO_3 is a stress factor for the growth of A. ordosica seedlings, and the growth response of the seedlings under the influence of soil CaCO_3 is in line with the Growth Rate Hypothesis.     

华南二叠－三叠系的事件地层与生物地层界线

华南二叠－三叠系界线研究应严格区分事件地层界线与生物地层界线。“界线粘土”层的底界即为事件地层界线。生物地层界线定义不能与“混生层”或“过渡层”的概念连在一起。长兴煤山忠心大队剖面是最好的二叠－三叠系全球界线层型剖面点（ＧＳＳＰ）。二叠－三叠系生物地层界线定义为ＨｉｎｄｅｏｄｕｓｐａｒｖｕｓＭｏｒｐｈｏｔｙｐｅ１的首次出现,其位置就在长兴剖面界线层（混生层）２的内部,比事件地层界线高１５ｃｍ。ＨｉｎｄｅｏｄｕｓｐａｒｖｕｓＭｏｒｐｈｏｔｙｐｅ１的首次出现,即为长兴阶的顶界。     

清溪场地区茅口组裂缝储层预测

茅口组储层以生屑灰岩储层为主,储集空间主要为溶孔、裂缝。这里运用P波振幅方位各向异性分析方法,对清溪场构造茅口组储层开展裂缝预测,搞清了裂缝发育与地层岩性以及构造发育之间的关系,明确了裂缝的走向、强度,以及密度发育部位,预测了裂缝的分布范围。实际资料应用表明,用该套方法识别裂缝—溶隙型储层是有效和可靠的,可以检测出有利的裂缝储层发育带。     

二连盆地与地沥青密切相关的砂岩型铀矿床微观矿物特征及成因分析

内蒙古二连盆地产在下白垩统碎屑岩系中的砂岩型铀矿床,其矿化与地沥青密切相关,有铀矿物存在之处必有地沥青;岩石中也普遍含地沥青。笔者通过蚀刻α径迹示踪,对铀含量在(200~1770)×10~(-6)的碎屑岩进行扫描电镜分析,采用分子量计算方法确定了该地区含铀碎屑岩中的铀是以多种超显微铀矿物形式存在。其中,以赛汉高毕铀矿床为代表,铀主要形成复成分磷钙铀矿。其它铀矿床也普遍有复成分磷钙铀矿产出:巴彦乌拉矿床样品因钙含量低、硅含量高,则铀石多于复成分磷钙铀矿;道尔苏矿床以铀石和磷铀矿为主,有少量沥青铀矿及复成分磷钙铀矿;哈达图矿床主要是沥青铀矿,未见复成分磷钙铀矿。除了地沥青之外,各矿床中与铀矿物共生的主要矿物还有草莓状、鲕粒状黄铁矿。由此推断,铀矿床的可能成因是:来自盆地深部的UH_3、PH_3、CaH_2、SiH_4、FeH_2、H_2S等在伴随油气向上运移过程中,由于温度、压力降低和氧化作用而发生分解及凝聚,形成草莓状、鲕粒状黄铁矿;同时派生出含U、P、Si、Ca等的氧化物的低温热水溶液,并最终结晶析出铀矿物,形成有大量黄铁矿共生的铀矿体;而油气经过长期挥发,最终演变成地沥青,成为铀矿物的载体。     

饱和土半空间中圆柱形孔洞对平面P波的散射

在 Biot饱和多孔介质动力学理论的基础上,首次建立了求解饱和土半空间中圆柱形孔洞对平面 P 波散射问题的波函数展开法。首先。分析了具有圆柱形孔洞的饱和土半空间场地在平面 P 波入射下产生散射波系,并将入射波和散射波的波函数在圆柱坐标下展开。然后,引入边界条件,求出散射波函数的待定系数,从而,得到饱和土半空间中圆柱形孔洞对平面P波的散射问题的解析解。根据所得的波函数的解,可求解区域内的位移、应力的值,同时,分析了入射波频率、入射角对柱面上的应力集中因子的影响。     

硅烷偶联剂改性TiO2/膨胀石墨复合材料的制备及其光催化性能研究

以硅烷偶联剂黏结剂,利用溶胶-凝胶法将TiO2（P25）负载在膨胀石墨上,利用XRD、EDS以及SEM等分析技术对TiO2/膨胀石墨复合材料进行表征;以橙黄Ⅱ为目标降解物,考察了TiO2/膨胀石墨复合材料光催化性能以及重复使用性能。结果表明：随着TiO2含量的增加,TiO2/膨胀石墨复合材料的光催化效率随之增加,对橙黄Ⅱ的光催化降解符合一级反应动力学方程,TiO2负载量为15%时,反应速率常数为0.387 h-1,高于P25的反应速率常数。TiO2/膨胀石墨复合物使用4次仍保持较高的光催化活性。