1993年北半球环流特征及其对我国天气气候的影响

１９９３年北半球主要环流特征表现为：５００ｈＰａ副产持续加强西伸，位置偏南；亚洲中纬度春，夏经向环流发展，东亚太平洋遥相关型稳定；西藏高原５００ｈＰａ位势高度持续偏高，印缅槽持续偏弱；１００ｈＰａ位势高度场低纬持续偏高，中，高纬持续偏低，夏季南亚高压位置异常偏高。热带海洋出现明显异常，一次新的厄尔尼诺现象发生。热带海洋和北半球大气环流的异常对我国天气气候产生明显影响。     

A numerical simulation of gas flow during coal/gas outbursts

Summary A model of the gas flow in airways during an instantaneous outburst of coal and gas is formulated and solved numerically using MacCormack's explicit finite-difference scheme. This model is based on the assumption that geological structures, in-situ stresses and high-gas-pressure gradients play important roles in initiating an outburst, with the gas content and gas-pressure gradients being the most dominant factors. The fluid-dynamic processes that occur after an outburst are computed by the numerical integration of the complete time-dependent Navier-Stokes equations. The mixture velocity, the density and the gas-concentration profiles in both time and space domains (immediately after an outburst) are presented. The global results are useful in gaining an improved understanding of gas-flow patterns during coal/gas outbursts and in determining the range of the disturbance so that effective methods of control can be developed.Nomenclature a speed of sound - C gas concentration (mass) - C _v specific heat at constant volume - C _p specific heat at constant pressure - CFL Courant-Friedrichs-Lewy number - E total energy of the mixture - F the vector defined in Equation 27 - G the vector defined in Equation 28 - h entropy - h _i entropy at inlet - J _xi diffusion flux in the i-direction - k thermal conductivity of a gas - M Mach number - P pressure of a mixture (the partial pressure of gas) - P gas pressure - P _a atmospheric pressure     

电阻率-孔隙度、电阻率-含油（气）饱和度关系的一般形式及其最佳逼近函数类型的确定（Ⅰ）

本文导出了电阻率-孔隙度、电阻率-含油（气）饱和度关系的一般形式--两个对称的表达式,并给予了实验证明。同时,本文指出,Archie公式、Winsauer公式和双水公式都是一般形式在一定条件下的特例。在一般情况下,本文给出了14个能够逼近这两个表达式的函数类型,通过岩芯数据进行选优,可以得到适合不同地区或地层的最优方程。根据本文理论建立的解释方法和研制的软件已经在油田生产中推广应用并取得了良好效果。 由于涉及内容较多,全文分两部分撰写。以下是本文的第（Ⅰ）部分,即一般形式的导出及实验验证;而最佳函数类型的确定及其在生产中的应用将作为本文的第（Ⅱ）部分发表。     

A note on the characteristics and possible origins of desert varnishes from Southeast Morocco. A reply to comments by R. I. Dorn

This reply to Dorn (1989) argues that a biotic origin is not the only way in which desert varnishes may be formed. It is suggested that a variety of initial conditions may result in similar end products. It is agreed that the dissimilar views of the authors may result from their different philosophies concerning the classification of Mn/Fe varnishes.     

Nonequilibrium thermodynamics of pressure solution

This paper is concerned with the thermodynamic theory of solution and precipitation processes in wet crustal rocks and with the mechanism of steady pressure-solution slip in contact zones, such as grain-to-grain contacts, fracture surfaces, and permeable gouge layers, that are infiltrated by a mobile aqueous solution phase. A local dissipation jump condition at the phase boundary is fundamental to identifying the thermodynamic force driving the solution and precipitation process and is used here in setting up linear phenomenological relations to model near-equilibrium phase transformation kinetics. The local thermodynamic equilibrium of a stressed pure solid in contact with its melt or solution phase is governed by Gibbs's relation, which is rederived here, in a manner emphasizing its independence of constitutive assumptions for the solid while neglecting surface tension and diffusion in the solid. Fluid-infiltrated contact zones, such as those formed by rough surfaces, cannot generally be in thermodynamic equilibrium, especially during an ongoing process of pressure-solution slip, and the existing equilibrium formulations are incorrect in overlooking dissipative processes tending to eliminate fluctuations in superficial free energies due to stress concentrations near asperities, defects, or impurities. Steady pressure-solution slip is likely to exhibit a nonlinear dependence of slip rate on shear stress and effective normal stress, due to a dependence of the contact-zone state on the latter. Given that this dependence is negligible within some range, linear relations for pressure-solution slip can be derived for the limiting cases of diffusion-controlled and interface-reaction-controlled rates. A criterion for rate control by one of these mechanisms is set by the magnitude of the dimensionless quantityk/2C _pD, wherek is the interfacial transfer coefficient, is the mean diffusion path length,C _p is the solubility at pressurep, andD is the mass diffusivity.     

莺－琼盆地YA13－1气田热流体活动与有机／无机成岩响应

根据钻井中途测试（ＤＳＴ）、重复地层测试（ＲＦＴ）、镜质体反射率（Ｒ０）、流体包裹体分析和粘土矿物Ｘ射线衍射全定量分析等综合研究发现，莺－琼盆地ＹＡ１３－１气田存在４期热流体活动；南侧的崖南地区和西侧的莺歌海盆地是其两个重要的热流体物质源和动力源；多期热流体活动在ＹＡ１３－１地区不仅造成热异常和物质迁移，而且还引起了不同的有机／无机成岩响应，如骨架颗粒的多期溶蚀作用、至少两期的次生加大作用、粘土矿物转化和有机质热成熟作用异常。第二、第三期热流体因出溶作用形成ＹＡ１３－１气田大规模的天然气聚集。     

Trace analysis of quaternary aminoalcohols as degradation products from softeners in wastewater

The sensitive and selective determination of polyalcohols without chromophores or fluorophores in the lower ppb-level is still an analytical task of high interest, especially in the field of environmental investigations. This paper describes a cation-exchange HPLC procedure for the separation and fluorescence detection of two quaternary ammonium compounds with polyalcoholic groups (degradation products of fabric softener) after derivatization with 9-fluorenylmethyl chloroformate (FMOC). Detailed experiments were carried out to determine optimum reaction conditions (pH, reaction time, temperature), linear range, detection limits, and kinetics of the reaction. The HPLC separation on a cation-exchange column includes a gradient program which provides complete separation from neutral compounds also reacting with FMOC and its hydrolysis products formed during the reaction in alkaline medium. High specificity for both investigated ammonium compounds with detection limits in the range of 1 ppb could be achieved.     

关于地震台站极性校正的问题

国内外的台网中总是一些台站，其极性读取似乎是由大量台站Ｐ波初动的整体分布确定的震源机制相矛盾，这些矛盾通常被作为坏读（ｂａｄ ｒｅａｄｉｎｇ）处理，造成台站的极性问题的复杂原因究竟是什么，利用ＮＥＩＣ的核爆资料，文中给出两种可能推测：台站仪器本身的不可和地震本身的复杂性。     

Characteristics of air flow over Andaman islands including precipitation

The characteristics of simulated air flow over Andaman Islands are studied with a two-dimensional version of the University of Virginia meso scale model (UVMM). Using the observed synoptic data as initial conditions, 24 hr simulations are obtained for a day each in April and November. These days are chosen to study the variations in the simulated flow pattern under different synoptic conditions including precipitation effects. A large scale condensation scheme is employed to consider the effect of latent heat release on the perturbations. The results show that the latent heat released by condensation strengthens the intensity of perturbations and the topography accelerates the arrival of sea breeze by about an hour. The model-simulated results, given in graphical form, are discussed and compared with available observations.