Chemical composition of bottled mineral waters in Estonia

Five commercially available in Estonia brands of bottled water have been analysed for 59 chemical elements by ICP-QMS and ICP-AES techniques to assess the quality of domestic mineral waters in scope of the European Groundwater Geochemistry Project initiated by the Geochemistry Expert Group of EuroGeoSurveys. Contents of 9 cations and anions, pH and electrical conductivity (EC) were measured in the bottled mineral waters by IC, titration and photometric methods. The data showed a significant difference between natural undiluted mineral water (Värska Originaal) characterised by the highest values of pH, EC and majority of trace elements studied, and other domestic waters sold in Estonia.     

月球的化学演化

月球是一个发生了化学分异的星球,它由月壳、月幔±一个小的金属月核组成。大量观察事实显示月球曾经有过岩浆洋,岩浆洋的结晶分异主导了月球的化学演化。目前主流观点认为,月球是在太阳系演化的早期,至少45亿年前,一个火星大小的星球,与即将完成原始吸积的地球胚胎发生偏心撞击,造成地球的熔融,形成岩浆洋,飞溅出来的物质迅速吸积形成绕地球运动的月球,并且在月球上形成了全球规模的岩浆洋,进而发生了结晶分异。,由于月球上没有海洋和板块俯冲,岩浆洋分异是其化学演化的主要途径。月球岩浆洋的80％～85％在大撞击后的100Ma内已经固化,这可能是由于月球体积小、表面没有大气包裹所致。月球极贫水,因此在岩浆结晶过程中斜长石首先结晶。斜长石由于密度小于玄武质岩浆而漂浮在岩浆洋的表层,橄榄石等密度大的矿物则堆积在岩浆洋的底部。随着结晶分异的进行,残余岩浆不断富集不相容元素,包括K、U等放射性元素;与此同时,密度较大的钛铁矿开始结晶,造成高钛堆晶岩密度大于其下的橄榄石堆晶岩的不稳定结构,进而发生月幔翻转,引发一系列岩浆活动,进而形成月球上特有的镁质系列、碱质系列等岩石。由于月球氧逸度较低,Eu主要以＋2价形式存在,因此斜长石高度富集Eu,相应地除高地斜长岩外,其他岩石均表现为Eu高度亏损的特点。与此同时,Re在低氧逸度下表现为强亲铁元素的特点,Re／Os在月球岩浆过程中不发生分异。月球的体积远小于地球,因而其演化时间远远短于地球,很多原始的分异被完整地保留下来。因此月球的化学演化是类地行星早期演化过程的“化石”,尽管与现代的地球存在较大差异,但是对于认识地球早期演化具有借鉴意义。     

遥感影像分辨率分析技术在滑坡研究中的应用

采用定性与定量相结合的方法对滑坡要素进行了深入分析。将滑坡要素划分为空间要素、时间要素和岩土性质要素3个方面,并分别讨论它们与遥感影像空间分辨率、时间分辨率和波谱分辨率的关系。首先对各滑坡要素进行了定性分析,然后提出了判识滑坡空间要素的定量依据;提出了通过遥感影像计算滑动速率的公式,以此作为按照时间分辨率选择遥感数据的依据;最后提出为判识岩土性质要素应采用高波谱分辨率遥感影像的观点。     

基于伪语义相似度模型的中文地址匹配方法

地址匹配中,由于传统相似度模型受字符重叠数影响大,在处理简写、缩写地址要素单元时,错误匹配问题突出;深度学习方法需要大量样本支撑,但庞大的数据量和多样的形式,导致生成样本的成本过高。为解决上述问题,本文首先应用基于条件随机场和双向长短时记忆神经网络的模型,对地址进行分词;然后通过建立一种伪语义相似度,对地址要素进行分级匹配。通过对公安业务中地址数据进行测试,在对缩写、简写等不规范地址描述方面,本文模型能较理想地完成任务,各参考指标均高于0.9。     

Properties of iron alloys under the Earth's core conditions

The Earth's core is constituted of iron and nickel alloyed with lighter elements. In view of their affinity with the metallic phase, their relative high abundance in the solar system and their moderate volatility, a list of potential light elements have been established, including sulfur, silicon and oxygen. We will review the effects of these elements on different aspects of Fe–X high pressure phase diagrams under Earth's core conditions, such as melting temperature depression, solid–liquid partitioning during crystallization, and crystalline structure of the solid phases. Once extrapolated to the inner–outer core boundary, these petrological properties can be used to constrain the Earth's core properties.     

Chemical enrichment in the early galaxy

New, precise abundance data for a large number of elements in a growing sample of extremely metal-poor stars are accumulating from the new 8-m telescopes. Combined with theoretical models, these results advance our understanding of the first generations of stars, whose nucleosynthesis products are fossilised in the oldest stars we see today and thus give clues to the earliest phases of evolution in the Galaxy. In particular, the heaviest elements give us insight into the different neutron capture mechanisms and the stellar sites where such elements could be produced. They also afford an independent way to determine the age of the Galaxy, by radioactive chronology. This revised version was published online in August 2006 with corrections to the Cover Date.     

Improved relativistic transformations in GPS

For GPS satellite clocks, a nominal (hardware) frequency offset and a conventional periodic relativistic correction derived as a dot product of the satellite position and velocity vectors, are used to compensate the relativistic effects. The conventional hardware clock rate offset of 38,575.008 ns/day corresponds to a nominal orbit semi-major axis of about 26,561,400 m. For some of the GPS satellites, the departures from the nominal semi-major axis can cause an apparent clock rate up to 10 ns/day. GPS orbit perturbations, together with the earth gravity field oblateness, which is largely responsible for the orbit perturbations, cause the standard GPS relativistic transformations to depart from the rigorous relativity transformation by up to 0.2 ns/day. In addition, the conventional periodic relativistic correction exhibits periodic errors with amplitudes of about 0.1 and 0.2 ns, with periods of about 6 h and 14 days, respectively. Using an analytical integration of the gravity oblateness term (J₂), a simple analytical approximation was derived for the apparent clock rate and the 6-h periodic errors of the standard GPS gravity correction. For daily linear representations of GPS satellite clocks, the improved relativistic formula was found to agree with the precise numerical integration of the GPS relativistic effects within about 0.015 ns. For most of the Block IIR satellites, the 6-h periodical errors of the GPS conventional relativistic correction are already detectable in the recent IGS final clock combinations.     

局部区域模型重力异常快速算法

地球重力场位系数模型可以用于计算局部重力扰动场元。然而随着地球重力场模型阶次的提高、局域重力场计算范围的增大,其计算速度往往不能满足工程需求。针对这一问题,在对位系数模型泰勒级数展开的基础上提出了采用向量运算、混合编程的方法,同时对连带勒让德函数Belikov递推方法中与经纬度无关的量进行了预先计算,有效提高了计算速度。提出的方法对于利用超高阶次重力场模型快速解算大范围、高分辨率重力场元数据以及累加求和计算具有一定的参考与借鉴意义。     

The impact of accelerometry on CHAMP orbit determination

 The contribution of the STAR accelerometer to the CHAMP orbit precision is evaluated and quantified by means of the following results: orbital fit to the satellite laser ranging (SLR) observations, GPS reduced-dynamic vs SLR dynamic orbit comparisons, and comparison of the measured to the modeled non-gravitational accelerations (atmospheric drag in particular). In each of the four test periods in 2001, five CHAMP arcs of 2 days' length were analyzed. The mean RMS-of-fit of the SLR observations of the orbits computed with STAR data or the non-gravitational force model were 11 and 24 cm, respectively. If the accelerometer calibration parameters are not known at least at the few percent level, the SLR orbit fit deteriorates. This was tested by applying a 10% error to the along-track scale factor of the accelerometer, which increased the SLR RMS-of-fit on average to 17 cm. Reference orbits were computed employing the reduced-dynamic technique with GPS tracking data. This technique yields the most accurate orbit positions thanks to the estimation of a large number of empirical accelerations, which compensate for dynamic modeling errors. Comparison of the SLR orbits, computed with STAR data or the non-gravitational force model, to the GPS-based orbits showed that the SLR orbits employing accelerometer observations are twice as accurate. Finally, comparison of measured to modeled accelerations showed that the level of geomagnetic activity is highly correlated with the atmospheric drag model error, and that the largest errors occur around the geomagnetic poles. Received: 7 May 2002 / Accepted: 18 November 2002 Correspondence to: S. Bruinsma Acknowledgments. The TIGCM results were obtained from the CEDAR database. This study was supported by the Centre National d'Etudes Spatiales (CNES). The referees are thanked for their helpful remarks and suggestions.     

GGR Critical Review of Analytical Developments in 2004–2005

In 2005 Geostandards and Geoanalytical Research embarked upon a new initiative for its readers. Key researchers in various fields of geoanalytical technique development and their application were identified and invited to provide reviews pertinent to their expertise. As noted in the first of these publications "…instead of revisiting the historical context or decades of development in each analytical technique, the goal here has been to capture a snapshot of "hot topics" across a range of fields as represented in the… literature" (Hergt et al . 2005). Rather than prepare an annual review, a decision was taken earlier this year to provide a biennial summary of progress and accomplishments, in this case for the years 2004–2005. The principal techniques employed in Earth and environmental sciences are covered here, and include laser ablation and multicollector ICP-MS, ICP-AES, thermal ionisation and secondary ion mass spectrometry, as well as neutron activation analysis, X-ray fluorescence and atomic absorption spectrometry. A comprehensive review of the development of reference materials, often essential to these techniques, is also provided. The contributions assembled serve both to keep readers informed of advances they may be unfamiliar with, but also as a means of showcasing examples of the breadth and depth of work being conducted in these fields.