橄榄石相变过程原位观测实验研究

橄榄石是地幔中的主要造岩矿物,橄榄石到其高压相的相变对地幔动力学过程有着广泛的影响。人们通常认为地幔成分中橄榄石的α-β相变是产生410km间断面的原因,并认为橄榄石的定向排列对上地幔中地震波的各向异性有一定的影响。橄榄石的α-β相变可能对板块动力学有着影响,而相变时可能导致的流变弱化会强烈地影响到俯冲带的力学特征。本文简述了橄榄石相变研究的一些新进展,内容包括原位X射线衍射实验技术和冷却方法、实验设备、压标对实验结果精确性的影响以及成核生长和剪切引导两个主要的相变机制。本文的实验通过对(Mg_0.9Fe_0.1)₂SiO₄橄榄石α-β相变过程的原位衍射实验研究确定其形核率和长大率参数,据此估算俯冲带中亚稳态橄榄石的存在状态,从而为分析研究俯冲带的动力学过程提供直接的实验依据。共进行了10组不同温压条件下的实验,分别得到了完全相变和部分相变的数据,从而得到了含Fe橄榄石原位X射线衍射相变实验的第一手重要数据,同时根据红外和光学及电子显微观测分析对实验样品的相变机制做了分析研究。     

西藏马攸木地区雅江南带方辉橄榄岩的显微构造特征及其矿物结构水的初步研究

青藏高原地区广泛出露地幔橄榄岩体,但对其显微构造特征和矿物结构水的研究仍很缺乏。本文以马攸木地区雅江南带方辉橄榄岩为研究对象,采用光学显微镜、电子背散射衍射(EBSD)及傅里叶变换红外光谱(FTIR)对其进行系统分析。研究结果表明:(1)马攸木地区雅江南带方辉橄榄岩中橄榄石发育扭折带和波状消光,并具有显著的结晶学优选方位(A型组构),指示其主导变形机制为位错蠕变;(2)红外光谱测试表明,马攸木方辉橄榄岩中橄榄石几乎没有明显的结构水吸收峰,推断其经历了明显的H丢失。斜方辉石含水量处于85wt ppm~209wt ppm之间,代表地幔源区含水量或其下限值;(3)该区橄榄岩中橄榄石含水量低于包体和造山带橄榄岩中橄榄石含水量,斜方辉石结构水含量则与包体和造山带橄榄岩中斜方辉石的可以比较。我们的研究结果为了解青藏高原地幔橄榄岩中橄榄石的结构水和变形机制提供了初步资料。     

Fe–Mg diffusion in olivine I: experimental determination between 700 and 1,200<Emphasis Type="Bold">°</Emphasis>C as a function of composition,crystal orientation and oxygen fugacity

We have determined Fe–Mg diffusion coefficients in olivines from different sources (Nanga Parbat, Pakistan and San Carlos, Arizona, USA) at atmospheric pressure as a function of composition, oxygen fugacity (10⁻⁵–10⁻¹² Pa) and temperature (700–1200°C) using thin films produced by pulsed laser deposition and RBS to analyze the concentration profiles. We have characterized the nano-scale structure and composition of the thin films annealed at various conditions and shown that the nature of the film (e.g. crystallinity, wetting behavior) depends strongly on the annealing conditions. If these variations are not taken into account in the form of boundary conditions for modeling the diffusion profiles, artifacts would result in the diffusion data. The diffusion coefficients obtained from 75 experiments reveal that (i) between fO₂ of 10⁻⁵ and 10⁻¹⁰ Pa, diffusion along all three principal crystallographic directions in olivine, [100], [010] and [001], are described by a constant activation energy of ∼200 kJ/mol, precluding any temperature dependence of diffusion anisotropy and change of mechanism of diffusion at temperatures between 950 and 1200°C, (ii) diffusion coefficients increase with oxygen fugacity at fO₂ > 10⁻¹⁰ Pa, with an fO₂ exponent that lies between 1/4 and 1/7, and (iii) at fO₂ below 10⁻¹⁰ Pa, and consequently at temperatures below ∼900°C, diffusion becomes weakly dependent/independent of fO₂, indicating a change of diffusion mechanism. Activation energy of diffusion at these conditions is slightly higher, ∼220 kJ/mol. The data, including the change of mechanism, are analyzed in terms of point defect chemistry in Part II of this work to derive an equation that allows calculation of diffusivities in olivine over its entire field of stability. Availability of directly measured data at temperatures down to 700°C imply that for the first time diffusion coefficients can be interpolated, rather than extrapolated, for modeling most natural systems.     

Temperature dependence of the polarized electronic absorption spectra of olivines. Part I – fayalite

 Polarized electronic absorption spectra of orthorhombic fayalite, Fe₂SiO₄, [E || a(|| Z),E || b(|| X), E || c(|| Y)], space group Pbnm, have been studied in the temperature range 293 ≤T/K ≤ 1273. The spectra were analysed into component bands originating from spin-allowed dd transitions of iron(II) at the different sites, M1 and M2, in the structure. The assignments of bands, made on the basis of the polarization dependence of the spectra and considerations of transition energies, were confirmed by the analysis of the temperature-dependent spectra. The temperature dependencies of integral intensities, half band widths and energy positions of absorptions bands caused by Fe²⁺ on the different octahedral sites, M1 and M2, were evaluated for the individual transitions. Independent of the site symmetry, absorption bands shift to lower energies and half band widths increase on rising temperature. The temperature dependence of band intensities depends on site symmetry. The integral intensities are found to increase with temperature for the transition metal ion on a centrosymmetric site, or remain constant when the site is missing an inversion centre. This is consistent with the general conclusion of Taran et al. (1994). Received: 11 October 2001 / Accepted: 17 January 2002     

橄榄石晶格优选方位和上地幔地震波速各向异性

根据福建省明溪幔源包体（二辉橄榄岩）中橄榄石晶格优选方位（ＬＰＯ）及其晶体弹性刚度系数，计算了地震波速度及其各向异性．研究结果表明，该区地震波各向异性是由橄榄石塑性流动产生晶格优选方位而引起的．与构造背景有关的ＶＰ，Ｖｓ１，Ｖｓ２和△Ｖｓ分布特征表明，中国东南沿海地区上地幔物质流动方向（由ＮＷＷ向ＳＥＥ）与橄榄石［１００］定向排列方向（ａ轴）和ＶＰ最大方向有一致的趋势．     

Strain and local heterogeneity in the forsterite–fayalite solid solution

Infrared powder-absorption spectra of nine natural and five synthetic olivine samples across the forsterite–fayalite join have been investigated at room temperature in the range 70–1400 cm^–1. Variations of peak positions as a function of Fe content are close to linear for those vibrational bands whose trend could be followed across the solid solution. Line-broadening has been quantified by autocorrelation analysis. Positive deviations from linearity of the line-broadening parameter, _corr, for groups of bands at low energies are consistent with the existence of local elastic strain heterogeneities at intermediate compositions in the solid solution. It also appears that the structure of forsterite is more homogeneous than Fe-rich olivines in relation to local elastic strain effects. Positive deviations from linearity of the line-broadening parameter for the low-energy regions scale linearly with calorimetric data for the enthalpy of mixing. This close correlation between line-broadening in IR spectra and calorimetric enthalpies of mixing has now been observed for four different binary solid solutions, and there is a further, qualitative correlation with bulk modulus.     

甘肃黑山铜镍硫化物含矿岩体的地质特征及橄榄石成因探讨

黑山铜镍硫化物含矿岩体位于中亚造山带南缘北山褶皱带东部,对该岩体的研究有助于正确理解造山带型铜镍硫化物的成矿作用。详细的野外基础地质特征表明黑山矿区仅出露单一的新元古代青白口系地层,无寒武纪地层出露。黑山含矿岩体由早期的方辉橄榄岩、二辉橄榄岩和橄榄辉长苏长岩,以及稍晚期的辉长岩脉组成。黑山岩体位于黑山背斜南翼,其初始产状应为一水平或近水平的岩床状岩体,因后期褶皱作用,岩体发生了倾斜形成现今的产状。黑山岩体中橄榄石Fo值为80.5~87.0,其Ni含量为1070×10^-6~3461×10^-6。借助"MELTS"软件,我们进一步厘定了黑山母岩浆为高镁玄武岩浆 (12.81% MgO, 10.84% FeO, 430×10^-6 Ni)。研究表明,黑山橄榄石的主要控制因素为:1)母岩浆的成分;2)后续新鲜岩浆的补充混合作用;3)硫化物熔离作用;4)晶间硅酸盐熔浆作用;5)橄榄石与硫化物之间发生的Fe-Ni交换。模拟计算表明,硫化物熔离与橄榄石结晶几乎同时发生,橄榄石与硫化物的最小质量比约为20:1。1号矿体及矿化体的橄榄石比4号矿体更富Mg和Ni,并且还呈现非常好的负相关关系,表明这些橄榄石与硫化物发生了不同程度的Fe-Ni交换,而与其发生Fe-Ni交换的硫化物更富Ni以及共生的岩浆更为原始。这很可能是因为黑山岩体形成于开放的岩浆通道系统,早期融离的硫化物与后续的新鲜的硫不饱和岩浆发生反应,使得该类硫化物含量减少但硫化物中的金属元素含量增高从而形成1号矿体及矿化体。     

橄榄石流体包裹体中分子水的发现

利用激光拉曼和红外光谱测定了内蒙古东部喀喇沁地区玻基橄辉岩橄榄石斑晶中的原生流体包裹体的成分,发现了波长分别为３２４５～３５６５ｃｍ＾－１的液态水和波长为３６２７的ｃｍ＾－１气态水的特征峰,而未发现结构水的特征峰,橄榄石的惰性气体同位素测定结果表明包裹休事的水来源于地幔岩浆,而非混染陆壳水。这一发现,揭示了地幔水可以以流体包裹体的形成赋存在火山岩的矿物斑晶中。     

Sheared peridotite xenolith from the V. Grib kimberlite pipe,Arkhangelsk Diamond Province,Russia: Texture,composition, and origin

The petrography and mineral composition of a mantle-derived garnet peridotite xenolith from the V. Grib kimberlite pipe (Arkhangelsk Diamond Province, Russia) was studied. Based on petrographic characteristics, the peridotite xenolith reflects a sheared peridotite. The sheared peridotite experienced a complex evolution with formation of three main mineral assemblages: (1) a relict harzburgite assemblage consist of olivine and orthopyroxene porphyroclasts and cores of garnet grains (Gar1) with sinusoidal rare earth elements (REE) chondrite C1 normalized patterns; (2) a neoblastic olivine and orthopyroxene assemblage; (3) the last assemblage associated with the formation of clinopyroxene and garnet marginal zones (Gar2). Major and trace element compositions of olivine, orthopyroxene, clinopyroxene and garnet indicate that both the neoblast and clinopyroxene-Gar2 mineral assemblages were in equilibrium with a high Fe-Ti carbonate-silicate metasomatic agent. The nature of the metasomatic agent was estimated based on high field strength elements (HFSE) composition of olivine neoblasts, the garnet-clinopyroxene equilibrium condition and calculated by REE-composition of Gar2 and clinopyroxene. All these evidences indicate that the agent was a high temperature carbonate-silicate melt that is geochemically linked to the formation of the protokimberlite melt.     

加载、加热路径上橄榄石的相变及其对相变动力学参数计算的影响

本文研究了橄榄石原位相变实验中加载、加热路径上的相变及其对确定相变动力学参数的影响.利用文献［1］所给出的退火后先加温后加压,且相对低温条件下实验结果确定出的Ni2SiO4橄榄石相变动力学参数,计算了加载、加热路径上所发生的相变对确定成核率、长大率及相变体积分数的影响.结果表明,退火后先加压后加温,且相对高温条件下的实验数据受到加热路径上成核的影响.根据这样的实验数据得到的成核率会明显高于实际温压条件下的成核率.尤其是当多数实验都是高温实验时,根据这些成核率数据所确定的成核率参数会严重偏离其真值,从而严重影响对俯冲带颗粒粒度及俯冲带流变结构的计算.尽管目前有很多关于Mg2SiO4橄榄石长大率的实验数据,也有通过对挤碰物理图像的分析对(Mg0.89Fe0.11)2SiO4橄榄石成核率的估算,但只有文献［2］通过退火后先加压后加温的原位实验得到了Mg2SiO4橄榄石的相变成核率,且属于高温实验.根据本文的研究结果,我们认为亟需补充退火后先加温后加压或相对低温的实验数据以得到正确的地幔橄榄石成核率参数.